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Toughened polyphenyl ether and nylon alloy and preparation method for toughened polyphenyl ether and nylon alloy

A polyphenylene ether and toughening technology, applied in the field of polyphenylene ether and nylon alloy materials and their preparation, can solve the problems of poor processing formability, intolerance, easy water absorption, etc., and achieve the effect of maintaining the external size

Active Publication Date: 2015-04-15
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It has good mechanical properties, electrical properties, heat resistance, flame retardancy, and low hygroscopicity, but pure PPO has high melt viscosity, poor processability, and is not resistant to corrosion by organic solvents
PA has good mechanical properties and is resistant to various organic solvents, but has the disadvantages of easy water absorption and unstable dimensions

Method used

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  • Toughened polyphenyl ether and nylon alloy and preparation method for toughened polyphenyl ether and nylon alloy
  • Toughened polyphenyl ether and nylon alloy and preparation method for toughened polyphenyl ether and nylon alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Weigh PPO 30%, PA6660%, compatibilizer PPO-g-MAH 5%, toughening agent SEBS-g-MAH 5%, antioxidant 1098 / 168 (1:1) 0.4%, lubricant A-C540A 0.6%;

[0038] (2) After mixing the above materials in a high-speed mixer for 3-5 minutes;

[0039] (3) Finally, the mixed material is added into the hopper of the twin-screw extruder, melted and blended, extruded and granulated into an alloy material;

[0040] Among them, the temperature settings of each section of the twin-screw are: the temperature of the first zone is 240-260°C, the temperature of the second zone is 250-270°C, the temperature of the third zone is 265-285°C, the temperature of the fourth zone is 275-295°C, and the temperature of the fifth zone is 275-295°C , the temperature in the six zones is 270-290°C, the temperature of the machine head is 275-295°C, and the speed of the main engine is 15-35HZ.

Embodiment 2

[0042] (1) Weigh PPO 60%, PA6630%, compatibilizer MPPO 5%, toughening agent SEBS-g-MAH 5%, antioxidant 1098 / 168 (1:1) 0.4%, lubricant A-C540A 0.6 %;

[0043] (2) After mixing the above materials in a high-speed mixer for 3-5 minutes;

[0044] (3) Finally, the mixed material is added into the hopper of the twin-screw extruder, melted and blended, extruded and granulated into an alloy material;

[0045] Among them, the temperature settings of each section of the twin-screw are: the temperature of the first zone is 240-260°C, the temperature of the second zone is 250-270°C, the temperature of the third zone is 265-285°C, the temperature of the fourth zone is 275-295°C, and the temperature of the fifth zone is 275-295°C , the temperature in the six zones is 270-290°C, the temperature of the machine head is 275-295°C, and the speed of the main engine is 15-35HZ.

[0046] The preparation method of compatibilizer MPPO is as follows:

[0047] PPO 90%, PS 10%, antioxidant 1098 / 168 (...

Embodiment 3

[0049] (1) Weigh PPO 40%, PA6645%, compatibilizer MPPO 5%, toughening agent SEBS-g-MAH 10%, antioxidant 1098 / 168 (1:1) 0.4%, lubricant A-C540A 0.6 %;

[0050] (2) After mixing the above materials in a high-speed mixer for 3-5 minutes;

[0051] (3) Finally, the mixed material is added into the hopper of the twin-screw extruder, melted and blended, extruded and granulated into an alloy material;

[0052] Among them, the temperature settings of each section of the twin-screw are: the temperature of the first zone is 240-260°C, the temperature of the second zone is 250-270°C, the temperature of the third zone is 265-285°C, the temperature of the fourth zone is 275-295°C, and the temperature of the fifth zone is 275-295°C , the temperature in the six zones is 270-290°C, the temperature of the machine head is 275-295°C, and the speed of the main engine is 15-35HZ.

[0053] The preparation method of compatibilizer MPPO is as follows:

[0054] PPO 70%, PS 30%, antioxidant 1098 / 168 ...

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Abstract

The invention discloses a toughened polyphenyl ether and nylon alloy and a preparation method for the toughened polyphenyl ether and nylon alloy. The toughened polyphenyl ether and nylon alloy comprises the following components in weight percentage: 20-60 percent of polyphenyl ether, 20-60 percent of polyamide, 5-20 percent of compatilizer, 5-20 percent of toughening agent and 1-2 percent of other additives. The incompatibility of the polyphenyl ether and nylon comprised by the invention is improved through the added compatilizer. Through changing the content of the toughening agent in the alloy material, the alloy material with different impact strength is obtained. A product prepared from the toughened polyphenyl ether and nylon alloy is capable of resisting the high temperature of at least 160 DEG C of a production line and the corrosion of dimethylbenzene and methylbenzene as solvents in spray paint; the contour dimension is kept unchanged; and the phenomena, such as stress cracking and the like, do not occur.

Description

technical field [0001] The invention belongs to the field of polymer composite materials, and relates to a polyphenylene ether and nylon alloy material and a preparation method thereof. Background technique [0002] Polyphenylene ether resin (referred to as PPE or PPO) is a thermoplastic general-purpose engineering plastic and is one of the five major engineering plastics. It has good mechanical properties, electrical properties, heat resistance, flame retardancy, and low hygroscopicity, but pure PPO has high melt viscosity, poor processability, and is not resistant to corrosion by organic solvents. PA has good mechanical properties and is resistant to various organic solvents, but has the disadvantages of easy water absorption and unstable dimensions. The two form an alloy, which can complement each other. The PPO / PA alloy not only maintains the advantages of good heat resistance and dimensional stability of PPO, but also combines the wear resistance and organic solvent re...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L71/12C08L77/06C08L51/08C08L25/06C08L51/00B29C47/92B29C48/92
CPCB29C47/92B29C48/04B29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895B29C2948/92904
Inventor 吴安琪
Owner HEFEI GENIUS NEW MATERIALS
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