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Fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas

A catalytic deoxidation and coalbed methane technology, applied in the direction of gas fuel, petroleum industry, fuel, etc., can solve the problems of reducing relative heat release, high energy consumption, low production intensity, etc., achieve good gas-solid contact effect, simple equipment structure, Strong ability to resist load fluctuations

Active Publication Date: 2012-06-27
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patents CN101139239A and CN101613627A disclose an adiabatic fixed bed coalbed methane deoxygenation reactor, which adopts the method of circulating partially deoxygenated methane-rich gas to reduce the relative oxygen content in coalbed methane, thereby reducing the relative heat release, so as to control the reaction temperature of the catalyst bed at Within an appropriate range, prevent local overheating and overheating, causing catalyst deactivation and sintering, but this also results in high energy consumption and low production intensity of the process

Method used

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  • Fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas
  • Fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas
  • Fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas

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Experimental program
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Effect test

Embodiment 1

[0034] The fluidized bed deoxygenation reactor consists of a shell 19, an oxygen-containing coalbed methane inlet nozzle, a tube heat exchanger 2, a deoxygenated coalbed methane outlet 16, a deoxidizing catalyst particle inlet 17, a catalyst particle discharge port 18, a cooling water inlet 15 and The steam outlet 14 is composed of a vertical tube heat exchanger 2 arranged in the shell 19, and the tube diameter is 25mm. The lower end of the tube is connected in parallel with the cooling water inlet 15, and the upper end of the tube is connected in parallel with the steam outlet 14. The cooling water inlet 15 and the steam outlet 14 are connected to the steam drum 3. The lower part of the shell 1 is a cone with a cone angle of 60 °There are two rows of oxygen-containing coalbed methane upper intake nozzles 12 and oxygenated coalbed methane lower intake nozzles 13 on the cone. Oxygenated coalbed methane upper intake nozzles 12 and oxygenated coalbed methane lower intake nozzles 13...

Embodiment 2

[0039] The structure of the fluidized bed deoxygenation reactor is as described in Example 1, the tube diameter of the tube heat exchanger is 38mm, and the cone angle of the bottom of the fluidized bed reactor is 90°.

[0040] The composition of oxygen-containing coalbed methane (volume percentage): CH 4 Content 52.40%, O 2 Content 9.93%, N 2 The content is 37.36%, and the content of other gases is 0.23%. The deoxidizing catalyst is a spherical cobalt-based catalyst (cobalt oxide content 30%, alumina content 67%, other metal additives content 3%), particle size 40-200μm, bulk density 0.65g / cm 3 . The fluidized bed deoxygenation reactor has an operating temperature of 480-500°C, a pressure of 0.1 MPa, an operating gas velocity of 0.4-0.6 m / s, and a steam drum pressure of 1.2-1.5 MPa. The rest is the same as in Example 1. After the oxygen-containing coalbed methane is catalytically deoxidized in a fluidized bed, the oxygen content in the deoxidized coalbed methane is 0.35%. The r...

Embodiment 3

[0044] The structure of the fluidized bed deoxygenation reactor is as described in Example 1. The composition of oxygen-containing coalbed methane (volume percentage): CH 4 Content 68.27%, O 2 Content 6.58%, N 2 The content is 24.80%, and the content of other gases is 0.35%. The deoxidizing catalyst is a spherical copper-based catalyst (copper oxide content 8%, alumina content 87%, other metal additives content 5%), particle size is 60-240μm, bulk density 0.68g / cm 3 . The fluidized bed deoxygenation reactor has an operating temperature of 500-520°C, a pressure of normal pressure, an operating gas velocity of 0.7-0.8m / s, and a steam drum pressure of 1.0-1.2MPa. The rest is the same as in Example 1. After oxygen-containing coalbed methane is catalytically deoxidized in a fluidized bed, the oxygen content in the deoxidized coalbed methane is 0.32%. The raw material gas (oxygen-containing coalbed methane) and deoxygenated gas composition of this embodiment are shown in Table 3.

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Abstract

The invention relates to a fluidized bed catalytic deoxidation method for oxygen-containing coal bed gas. The fluidized bed catalytic deoxidation method comprises the following steps that: a fluidized bed deoxidation reactor is preheated to the temperature of 300-400 DEG C; the oxygen-containing coal bed gas is fed into the fluidized bed deoxidation reactor; deoxidation catalyst granules are loaded into a feed hopper and are added into the fluidized bed deoxidation reactor under the action of air blowing and supplying; methane and oxygen in the coal bed gas are subjected to low-temperature catalytic combustion reaction in the fluidized bed deoxidation reactor; the gas moves upwards with the carrying of part of solid catalyst granules and enters a one-stage cyclone separator and a two-stage cyclone separator from the top outlet of the fluidized bed deoxidation reactor, and the collected solid catalyst granules circularly enter the fluidized bed deoxidation reactor under the control of a feed back control valve and air blowing and supplying; and the deoxidated coal bed gas which is subjected to coarse dust removal by the cyclone separators is subjected to fine catalyst dust removal by a high-temperature filter, and then, is transferred to a follow-up system for use. The fluidized bed catalytic deoxidation method for the oxygen-containing coal bed gas has the advantages of good safety, low energy consumption, high deoxidation efficiency, long service life of catalyst and large processing capacity.

Description

Technical field [0001] The invention relates to a fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas. Background technique [0002] my country is a big coal consuming country. In the process of coal mining, in order to ensure the safe production of mines, a large amount of low-concentration mixed-air CBM is pumped, and its main component is methane (CH 4 ) And air. According to statistics, billions of cubic meters of coal-bed methane are emitted every year from coal mining in my country, most of which are directly vented and burned. This not only wastes resources, but also increases the greenhouse effect of the atmosphere and causes environmental pollution. [0003] Low-concentration oxygen-containing coalbed methane has a methane content of 30-70% and an oxygen content of 5-15%. It is flammable and explosive. The current main utilization method is direct combustion and power generation, and its economic value has not been fully reflected. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L3/10
Inventor 房倚天赵建涛王洋黄戒介方惠斌董立波王建国
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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