Fluidized bed catalytic deoxidation method and equipment for oxygen-containing coal bed gas
A catalytic deoxidation and coalbed methane technology, applied in the direction of gas fuel, petroleum industry, fuel, etc., can solve the problems of reducing relative heat release, high energy consumption, low production intensity, etc., achieve good gas-solid contact effect, simple equipment structure, Strong ability to resist load fluctuations
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Embodiment 1
[0034] The fluidized bed deoxygenation reactor consists of a shell 19, an oxygen-containing coalbed methane inlet nozzle, a tube heat exchanger 2, a deoxygenated coalbed methane outlet 16, a deoxidizing catalyst particle inlet 17, a catalyst particle discharge port 18, a cooling water inlet 15 and The steam outlet 14 is composed of a vertical tube heat exchanger 2 arranged in the shell 19, and the tube diameter is 25mm. The lower end of the tube is connected in parallel with the cooling water inlet 15, and the upper end of the tube is connected in parallel with the steam outlet 14. The cooling water inlet 15 and the steam outlet 14 are connected to the steam drum 3. The lower part of the shell 1 is a cone with a cone angle of 60 °There are two rows of oxygen-containing coalbed methane upper intake nozzles 12 and oxygenated coalbed methane lower intake nozzles 13 on the cone. Oxygenated coalbed methane upper intake nozzles 12 and oxygenated coalbed methane lower intake nozzles 13...
Embodiment 2
[0039] The structure of the fluidized bed deoxygenation reactor is as described in Example 1, the tube diameter of the tube heat exchanger is 38mm, and the cone angle of the bottom of the fluidized bed reactor is 90°.
[0040] The composition of oxygen-containing coalbed methane (volume percentage): CH 4 Content 52.40%, O 2 Content 9.93%, N 2 The content is 37.36%, and the content of other gases is 0.23%. The deoxidizing catalyst is a spherical cobalt-based catalyst (cobalt oxide content 30%, alumina content 67%, other metal additives content 3%), particle size 40-200μm, bulk density 0.65g / cm 3 . The fluidized bed deoxygenation reactor has an operating temperature of 480-500°C, a pressure of 0.1 MPa, an operating gas velocity of 0.4-0.6 m / s, and a steam drum pressure of 1.2-1.5 MPa. The rest is the same as in Example 1. After the oxygen-containing coalbed methane is catalytically deoxidized in a fluidized bed, the oxygen content in the deoxidized coalbed methane is 0.35%. The r...
Embodiment 3
[0044] The structure of the fluidized bed deoxygenation reactor is as described in Example 1. The composition of oxygen-containing coalbed methane (volume percentage): CH 4 Content 68.27%, O 2 Content 6.58%, N 2 The content is 24.80%, and the content of other gases is 0.35%. The deoxidizing catalyst is a spherical copper-based catalyst (copper oxide content 8%, alumina content 87%, other metal additives content 5%), particle size is 60-240μm, bulk density 0.68g / cm 3 . The fluidized bed deoxygenation reactor has an operating temperature of 500-520°C, a pressure of normal pressure, an operating gas velocity of 0.7-0.8m / s, and a steam drum pressure of 1.0-1.2MPa. The rest is the same as in Example 1. After oxygen-containing coalbed methane is catalytically deoxidized in a fluidized bed, the oxygen content in the deoxidized coalbed methane is 0.32%. The raw material gas (oxygen-containing coalbed methane) and deoxygenated gas composition of this embodiment are shown in Table 3.
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