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A kind of preparation method of humic acid coated urea

The technology of humic acid urea and coating urea is applied in the field of preparation of humic acid-coated urea, and can solve problems such as difficulty in large-scale industrial production and popularization and application, failure to improve urea fertilizer efficiency and utilization rate, and increase in production cost, etc. Achieve the effect of short production process, smooth and beautiful appearance, and reduce physical labor.

Active Publication Date: 2011-11-30
谭钧
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are following defects in the preparation of the above three kinds of humic acid urea products: 1. During the preparation process, weathered coal is only wrapped on the surface of urea by physical methods, or urea is wrapped on the surface of weathered coal or ammonium humate particles, basically no or only a small amount Humic urea formation
Therefore, the urease inhibitory effect of this type of product is bound to be very small, and the effect of improving urea fertilizer efficiency and utilization rate cannot be achieved; 2. The preparation method disclosed in CN 1283600A and CN 200810080040.6 is to directly use weathered coal or peat without extracting humic acid, and the product Low humic acid content in medium, poor water solubility, difficult to be absorbed by crops, and poor use effect; 3. The preparation methods disclosed in CN 1376652A and CN 200810080040.6 all add binders, which increases production costs
[0007] In a word, the above-mentioned disclosed humic acid urea product has high production cost, troublesome operation, slow production speed, and is difficult for large-scale industrial production and popularization and application.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1: Take 200 parts of water into the reactor, add 40 parts of urea, stir and dissolve at about 55°C, add 80 parts of Inner Mongolia Wuchuan weathered lignite (30 mesh) containing 44% humic acid (dry basis) and 26.5% water , The temperature is raised to about 95°C for 10 minutes, 8 parts of diammonium phosphate are added, and the reaction is continued for 50 minutes with stirring. The solid-liquid separation is performed. The clear liquid contains 14.3% of water-soluble humic acid and 9.2% of N. The clear liquid is concentrated, and the concentrated liquid contains 20.4% of water-soluble humic acid and 12.6% of N. Then the concentrated liquid is dried to obtain a solid humic acid urea complex. The solid product contains 38% water-soluble humic acid and 28% N.

Embodiment 2

[0025] Example 2: Take 200 parts of water into the reactor, add 48 parts of urea, stir and dissolve at about 55°C, add 80 parts of Inner Mongolia Wuchuan weathered lignite (30 mesh) containing 69% humic acid (dry basis) and 28% water , The temperature is raised to about 95°C for 10 minutes, 8 parts of diammonium phosphate are added, the reaction is continued for 45 minutes, cooling, solid-liquid separation, the supernatant is concentrated and dried to obtain 71 parts of solid humic acid urea, containing 28 parts of humic acid, The extraction rate of humic acid is 70%, containing 47% of water-soluble humic acid and 30% of N.

Embodiment 3

[0026] Example 3: Add 91 parts of urea to the coating machine (or turntable or drum granulation equipment), and pump 25 parts of the humic acid urea complex concentrate prepared in the above example 1 into the coating machine (or Rotary table, rotary drum granulation equipment), dried at the inlet temperature of 120°C and outlet temperature of 80°C to obtain humic acid-coated urea. The product has been tested by NY 1106-2006 and GB 2441 methods. The product composition is: moisture 4.2%, Total nitrogen 44.1%, water-soluble humic acid 5.2%, pH value (1:250 times aqueous solution): 7.6.

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PUM

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Abstract

The invention provides a method for preparing humic acid coated urea, which comprises the following steps of: dissolving 20 to 400 parts of urea in 40 to 200 parts of water at the temperature of between 20 and 60 DEG C, reacting with 40 to 200 parts of humic acid feed coal at the temperature of between 40 and 100 DEG C for 5 to 30 minutes, adding 10 to 100 parts of phosphate, continuously stirring for reacting for 30 to 120 minutes, performing solid-liquid separation, and evaporating and concentrating to obtain a humic acid-urea complex concentrated liquor, or drying to obtain a solid humic acid-urea complex; and spraying, infiltrating and drying by using coat drying equipment to obtain the humic acid coated urea. The humic acid feed coal has rich resources, and is cheap and readily available; a process flow is short, equipment is easy and convenient to operate, reaction conditions are mild, and the method is easy for production control; the production process is environment-friendly,pollution emission is avoided, and the method is suitable for large-scale industrial production and promotion and application; and the product has good water solubility and attractive appearance, caneffectively inhibit urease from decomposing the urea and improve the fertilizer efficiency of the urea and the utilization rate of nitrogen.

Description

Technical field [0001] The invention belongs to the technical field of slow-release fertilizers, and particularly relates to a preparation method of slow-release urea for agriculture or humic acid-coated urea used as a slow-release special fertilizer substrate. Background technique [0002] At present, mankind is facing serious challenges such as population growth, reduction of arable land, desertification, environmental pollution and water shortage. In order to meet the ever-increasing demand for human survival, agricultural production must provide adequate, high-quality, pollution-free, green organic food and agricultural by-products, and protect the environment on which mankind depends. This has become a worldwide urgent task. [0003] my country is a developing country with more people and less land. At present, both the total production and consumption of chemical fertilizers rank first in the world. In the past two years, the annual consumption of chemical fertilizers in my ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/08C05G3/90
Inventor 谭钧王丽霞白凤华邢文军董钰赵世军张鸿云乌日娜
Owner 谭钧
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