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Production process of waterborne positive lithium ion battery

A lithium-ion battery and production process technology, which is applied in the manufacture of non-aqueous electrolyte batteries, battery electrodes, electrolyte batteries, etc., can solve the problems of low pass rate, low specific energy, low oiliness, and restrictions on raw materials, etc., and achieve coating speed The effect of fast, low temperature and cost reduction

Active Publication Date: 2011-09-14
安徽风驰新能源科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the production process of the existing water-based positive electrode lithium-ion battery is consistent with the oily system, and the production process of the oily system is as follows: figure 1 As shown, there is no production process specifically for aqueous cathode lithium-ion batteries
[0004] At present, the lithium-ion battery of the oily system is widely used because of its perfect process and relatively stable battery performance. However, the disadvantage is that the production cost is too high, and it is often limited by the raw materials. The control of water in the process control also needs to be controlled from the front to the back. Many enterprises are restricted by energy consumption quotas; although there are several manufacturers of water-based lithium-ion batteries, the production process still adopts the oil-based production process. Although the prepared products can be used, there are three main problems: 1. Coating only Aluminum foil with a thickness of 0.02mm or more can be used. If the product uses aluminum foil with a thickness of 0.016mm, it will be difficult to coat due to excessive surface tension. ;2. The water removal of the product is not thorough, and there is an air swelling problem after the battery is formed, so the performance of the product is much worse than that of the oily system, which makes it difficult to control the consistency of the product performance, and can only be applied to the shell On thicker and harder large batteries; 3. After the slurry is used, the waste on the barrel wall is not properly disposed of, causing waste and polluting the environment
[0005] It can be seen from the above that the cost of lithium-ion batteries in the oily system needs to be reduced urgently. Only by reducing the cost can we occupy a larger market; but the cost cannot be reduced without reducing the product performance.
Although the cost of lithium-ion batteries in the aqueous system has advantages and can solve the problem to a certain extent, there is still a lack of a production process that specifically guarantees product performance and performance consistency

Method used

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  • Production process of waterborne positive lithium ion battery
  • Production process of waterborne positive lithium ion battery
  • Production process of waterborne positive lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Here is an example of lithium iron phosphate steel shell cylindrical 18650 battery, and cooperate with figure 2 The process flow chart is described in detail.

[0059] (one).

[0060] 1. Cathode material and its weight ratio:

[0061] Lithium iron phosphate: 100 parts;

[0062] Super conductive carbon black (super-p): 3 parts;

[0063] Conductive graphite (ks-15): 2 parts;

[0064] Water-based adhesive: LA132, Chengdu Yindile Power Technology Co., Ltd., 3.5 parts;

[0065] NMP: 2.5 parts;

[0066] 80 parts of deionized water.

[0067] 2. Anode material and its weight ratio:

[0068] Artificial graphite: 100 parts;

[0069] CMC (Carboxymethylcellulose Sodium): 1 part;

[0070] 2 parts of SBR latex (SBR styrene-butadiene latex 50%):

[0071] Deionized water: 140 parts.

[0072] (2). The production process of the water-based cathode lithium-ion battery is as follows (see figure 2 ):

[0073] 1 Positive and negative ingredients: the equipment is Guangzhou Hon...

Embodiment 2

[0109] Here is an example of lithium iron phosphate steel shell cylindrical 18650 battery, and cooperate with figure 2 The process flow chart is described in detail.

[0110] (one).

[0111] 1. Cathode material and its weight ratio:

[0112] Lithium iron phosphate: 100 parts;

[0113] Super conductive carbon black (super-p): 4 parts;

[0114] Conductive graphite (ks-15): 3 parts;

[0115] Water-based adhesive: Chengdu Yindile adhesive LA132, 4 parts;

[0116] NMP: 3 parts;

[0117] 85 parts of deionized water.

[0118] 2. Anode material and its weight ratio:

[0119] Artificial graphite: 100 parts;

[0120] CMC (carboxymethyl cellulose sodium): 2 parts;

[0121] 3 parts of SBR latex (SBR styrene-butadiene latex 50%):

[0122] Deionized water: 143 parts.

[0123] (2). The production process of the water-based cathode lithium-ion battery is as follows (see figure 2 ):

[0124] 1 Positive and negative ingredients: the equipment is Guangzhou Hongyun 200L double plan...

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PUM

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Abstract

The invention belongs to the field of production of lithium ion batteries, in particular to a production process of a waterborne positive lithium ion battery. The production process comprises the following steps of: preparing an anode and a cathode, coating on the anode and the cathode, flaking, baking, preparing an electric core, testing short circuit, baking, putting a lower spacer into a shell, welding a bottom, putting an upper spacer and folding a positive lug, rolling a slot and testing short circuit; and injecting liquid, wiping the positive lug, welding the positive lug with a cover plate, folding the cover plate for covering, sealing, cleaning, standing, performing formation, standing and performing capacity grading. The anode comprises the following components in parts by weight: 100 parts of lithium iron phosphate, 3-4 parts of super conductive carbon black, 2-3 parts of conductive graphite, 3.5-4 parts of waterborne adhesive, 2.5-3 parts of NMP (N-methylpyrrolidone) and 80-85 parts of deionized water and is prepared by the following steps of: mixing the waterborne adhesive, the NMP and the deionized water; adding other raw materials; and stirring to obtain anode slurry. Compared with the conventional oily process of the lithium ion battery, the production process has the advantages of low energy consumption, high production efficiency, low product cost and the like.

Description

technical field [0001] The invention belongs to the field of lithium ion battery production, and in particular relates to a production process of an aqueous positive electrode lithium ion battery. Background technique [0002] The existing lithium-ion battery production process is mainly an oily system using NMP as a solvent. A large amount of NMP (N-methylpyrrolidone) is used in the production of batteries in this system. NMP is a chemical substance synthesized from petroleum and has a small amount of toxicity. , a large amount of emissions will cause air pollution; even if it is recycled, it can only reach 70%-80% of the recycling amount, and it is necessary to purchase professional recycling equipment when recycling, and the power consumption of the equipment is extremely high; and the price of NMP is extremely high, the lowest price in 2010 The price of NMP is 22,000 yuan / ton. With the increase of oil price, the price of NMP is also rising all the way. When the oil is ti...

Claims

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Application Information

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IPC IPC(8): H01M10/058H01M4/139
CPCY02E60/122Y02E60/10Y02P70/50
Inventor 胡泽军胡振宁官彬
Owner 安徽风驰新能源科技股份有限公司
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