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Polishing solution for hard disk magnetic head and preparation method thereof

A polishing liquid, magnetic head technology, applied in polishing compositions containing abrasives, chemical instruments and methods, other chemical processes, etc., can solve the problems of ineffective particle dispersion, reduced cutting rate, inconsistent size, etc. Achieve good suspension stability, good surface quality and good dispersion uniformity

Active Publication Date: 2011-09-07
CHANGSHA RES INST OF MINING & METALLURGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the existing preparation method of magnetic head polishing liquid, it generally uses 3nm to 18nm nano-diamond as abrasive grains, which can cause particles to be on the surface of the blank when the abrasive grains are used for magnetic head polishing (especially for compact compact abrasive polishing). Defects in the holding force cause the abrasive grains to fall off easily during the polishing process, and the cutting rate drops sharply. At the same time, the fallen abrasive grains tend to form black spot defects on the surface of the magnetic head, resulting in a significant increase in the defective product rate
In addition, in the preparation process of the existing magnetic head polishing liquid, the process of crushing and then drying is often adopted. Due to the high surface energy of the nano-powder particles, it is very easy to form hard agglomerates during the drying process, making the particle size of the diamond powder in the actual system and morphology cannot be effectively controlled, and the problem of particle dispersion cannot be effectively solved accordingly.
Since the dispersion and stability of existing nano-diamond powders in the system have not been effectively solved, the powders often exist in the form of agglomerates, and the actual abrasive grains have irregular shapes, inconsistent sizes, and poor bonding between crystallites. Strong, prone to chipping under loading conditions, resulting in easy scratches and black spots during polishing, so the quality of head polishing will be unavoidable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of polishing liquid of hard disk magnetic head of the present invention, this polishing liquid is mainly formulated by the component of following quality:

[0033] Polycrystalline diamond abrasive grains: 2g (the average particle size is 60±5 nm, the particle size distribution range is 30nm to 150nm, and the particle aspect ratio is 1.0 to 2.0.);

[0034] Dispersant: 0.5g of oleic acid and 0.5g of octadecylamine,

[0035] Corrosion inhibitor: methyl benzotriazole 0.1g,

[0036] Phase transfer solvent: acetone 8g,

[0037] Oil phase medium conditioner: n-octane 0.5g and

[0038] Hydrocarbon solvent: 188.4 g of No. 3 white oil.

[0039] The polishing liquid of the hard disk magnetic head of above-mentioned present embodiment is prepared through the following steps:

[0040] (1) Diamond powder pretreatment: mix 20g of polycrystalline diamond powder (polycrystalline diamond and its aggregates, the average particle size of which is 30nm to 180nm, and the particle si...

Embodiment 2

[0046] A kind of polishing liquid of hard disk magnetic head of the present invention, this polishing liquid is mainly formulated by the component of following quality:

[0047] Static pressure diamond abrasive grains: 5g (average particle size 80±5 nm, particle size distribution range 30nm-200nm, grain aspect ratio 1.0-2.0);

[0048] Dispersant: oleic acid 0.5g; octadecylamine 0.5g,

[0049] Corrosion inhibitor: methyl benzotriazole 0.1g,

[0050] Phase transfer solvent: acetone 7.5g,

[0051] Oil phase medium conditioner: petroleum ether 2g and

[0052] Hydrocarbon solvent: 184.4 g of No. 5 white oil.

[0053] The polishing liquid of the hard disk magnetic head of above-mentioned present embodiment is prepared through the following steps:

[0054] (1) Diamond powder pretreatment: Mix 50g of static pressure diamond powder (static pressure diamond and its aggregates, the average particle size of which is 40nm to 200nm, and the particle size distribution range is 20nm to 40...

Embodiment 3

[0060] A kind of polishing liquid of hard disk magnetic head of the present invention, this polishing liquid is mainly formulated by the component of following quality:

[0061] Static pressure diamond abrasive grains: 6g (the average particle size of the particles is 100±10 nm, the particle size distribution range is 40nm-300nm, and the aspect ratio of the particles is 1.0-2.0),

[0062] Dispersant: Hypersol hyperdispersant 1.2g,

[0063] Corrosion inhibitor: benzotriazole 0.2g,

[0064] Phase transfer solvent: petroleum ether 4g,

[0065] Oil phase medium conditioner: n-octane 2g and

[0066] Hydrocarbon solvent: 186.6 g of No. 2 white oil.

[0067] The polishing liquid of the hard disk magnetic head of above-mentioned present embodiment is prepared through the following steps:

[0068] (1) Pretreatment of diamond powder: Mix 50g of static pressure diamond powder with 10g of sodium dodecylsulfonate, and then place it in deionized water medium for stirring and grinding, a...

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Abstract

The invention discloses polishing solution for a hard disk magnetic head and a preparation method thereof. The polishing solution is mainly prepared from diamond abrasive particles, a dispersing agent, a corrosion inhibitor, a phase transfer solvent, an oil phase medium regulator and a hydrocarbon solvent, wherein the average particle size of the diamond abrasive particles is 30 to 150nm, the particle size distribution of the particles is 20 to 300nm, and the length-diameter ratio of the particles is 1.0 to 2.0. The preparation method comprises the following steps of: mixing diamond powder and a surface modifier, grinding, removing impurities, and grading to obtain suspension slurry; adding the phase transfer solvent into the suspension slurry, and stirring and dispersing the system; removing fine particles and coarse particles in the phase transfer solvent system by grading to ensure that the particle size distribution and concentration of the diamond abrasive particles meet the requirements; and transferring to the hydrocarbon solvent, adding the oil phase medium regulator, the dispersing agent and the corrosion inhibitor, and uniformly stirring to obtain the polishing solution for the hard disk magnetic head. The polishing solution prepared by the method has high suspension stability and dispersion uniformity, and high polishing efficiency during polishing, and a machined surface has high quality.

Description

technical field [0001] The invention belongs to the technical field of ultra-precision grinding and polishing treatment, and in particular relates to a magnetic head polishing liquid and a preparation method thereof. Background technique [0002] With the increase of hard disk storage density, the recorded magnetic signal line width has reached the nanoscale, the actual flying height of the magnetic head is less than 4nm, the surface roughness of the magnetic head must be less than 0.2nm, and the surface processing accuracy of the components must reach the sub-nanometer level. In order to improve the processing efficiency, reduce the roughness of the magnetic head, and eliminate the fatal damage caused by scratches and impurities embedded in the magnetic disk, it is necessary to develop a high-quality polishing fluid suitable for ultra-precision processing of the magnetic head of a high-storage-density hard disk. [0003] As an excellent abrasive, diamond has always been one...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/02C09K3/14
Inventor 许向阳翟海军刘学璋谢圣中王绍斌段兴无
Owner CHANGSHA RES INST OF MINING & METALLURGY
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