Preparation method of graphene-supported nano MnOOH composite material
A composite material and graphene technology, applied in chemical instruments and methods, catalyst activation/preparation, physical/chemical process catalysts, etc., can solve problems such as prone to agglomeration and affect the excellent performance of nano-effects, and achieve convenient and excellent post-processing Catalytic performance, effect of low reaction temperature
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[0018] to combine figure 1 , the preparation method of graphene-loaded nano-MnOOH composite material of the present invention, comprises the following steps:
[0019] Step 1: MnCl 2 4H 2 O. Graphite oxide and isopropanol are mixed to make a solution, and dispersed evenly by ultrasonic;
[0020] Step 2: KMnO 4 Add water and water to the solution prepared in step 1, stir evenly, the concentration of graphite oxide in isopropanol is 0.00111~0.0222g / mL, MnCl 2 4H 2 The concentration of O in isopropanol is 0.0018~0.054g / mL, MnCl 2 4H 2 O and KMnO 4 The mass ratio of KMnO is 1.42~2.50:1, KMnO 4 The concentration in water is 0.0127~0.15g / mL;
[0021] Step 3: React the mixed solution in step 2 at a constant temperature under sealed conditions for a period of time to obtain a black precipitate. The reaction equation is: 2KMnO 4 +3MnCl 2 +2H 2 O→5MnO 2 +2KCl+4HCl, the reaction time is 30min~24h, and the reaction temperature is 90~150℃;
[0022] Step 4: Centrifuge and wash...
Embodiment 1
[0027] Step 1: 0.36g MnCl 2 4H 2 O. Mix 0.0665g graphite oxide with 30mL isopropanol to form a solution, and disperse evenly by ultrasonic;
[0028] Step 2: Add 0.20g KMnO 4 Add 5mL of water to the solution prepared in step 1, and stir evenly;
[0029] Step 3: React the mixture in step 2 at 120°C for 12 hours under sealed conditions to obtain a black precipitate. The reaction equation is: 2KMnO 4 +3MnCl 2 +2H 2 O→5MnO 2 +2KCl+4HCl;
[0030] Step 4: centrifuge and wash the black precipitate obtained from the reaction, add it to 30mL ethylene glycol, and stir evenly;
[0031] Step 5: React the mixture in step 4 at 120°C for 16 hours under sealed condition, the reaction equation is: 2MnO 2 +HOCH 2 -CH 2 OH→2MnOOH+HOCH 2 -CHO;
[0032] Step 6: Centrifuge, wash, dry, and grind the product obtained from the reaction in step 5 to obtain a graphene-loaded nano-MnOOH composite material. Its XRD test result is as follows figure 2 As shown in (a), the transmission electron...
Embodiment 2
[0035] Step 1: 0.054g MnCl 2 4H 2 O. 0.0399g of graphite oxide was mixed with 30mL of isopropanol to form a solution, which was uniformly dispersed by ultrasonic;
[0036] Step 2: Add 0.038g KMnO 4 Add 3mL water to the solution prepared in step 1, and stir evenly;
[0037] Step 3: React the mixture in step 2 at 120°C for 12 hours under sealed conditions to obtain a black precipitate. The reaction equation is: 2KMnO 4 +3MnCl 2 +2H 2 O→5MnO 2 +2KCl+4HCl;
[0038] Step 4: Centrifuge and wash the black precipitate obtained from the reaction, add it to 12 mL of ethylene glycol, and stir evenly;
[0039] Step 5: React the mixture in step 4 at 120°C for 16 hours under sealed condition, the reaction equation is: 2MnO 2 +HOCH 2 -CH 2 OH→2MnOOH+HOCH 2 -CHO;
[0040] Step 6: Centrifuge, wash, dry, and grind the product obtained from the reaction in step 5 to obtain a graphene-loaded nano-MnOOH composite material.
[0041] After adding 2wt% of the obtained graphene-MnOOH comp...
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