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Ice-covering-proof coating containing electrolyte

An anti-icing and polyelectrolyte technology, applied in the field of materials, can solve the problems of ineffective prevention of icing and limited application effect of superhydrophobic materials, and achieve the effects of low cost, reduced adhesion, and anti-icing

Active Publication Date: 2011-08-03
张家港楚人新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, recently some scholars, such as Stefan Jung, have studied various fluorine-containing low surface energy materials in detail and found that although superhydrophobic materials can prolong the freezing time, they generally freeze in about half an hour [JungS, Dorrestijn M, Raps D, et al.Are Superhydrophobic Surfaces Best for Ice-phobicity[J].Langmuir.2011, 27(6):3059-3066.], indicating that superhydrophobic materials have limited application effects in anti-icing
In particular, it is worth noting that a large number of on-site practices of many power grid companies show that in harsh weather conditions, super-hydrophobic coatings cannot effectively prevent icing

Method used

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  • Ice-covering-proof coating containing electrolyte
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  • Ice-covering-proof coating containing electrolyte

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Add 200mL of ethanol, 1g of vinyltrimethoxysilane, and 20g of acrylic acid into a 500mL three-necked flask, stir, and when the temperature rises to 70°C, add 0.15g of azobisisobutyronitrile, react for 5 hours, add 12g of NaOH into the flask, and continue stirring 3h, that is, silicone modified sodium acrylate resin.

[0031] In a 500mL three-neck flask, add 120g of water and 0.4g of sodium lauryl sulfate in sequence, and stir. Then 1.2g vinyltriethoxysilane, 15.0g dodecafluoroheptyl methacrylate, 10.0g butyl methacrylate, 0.3g benzoyl peroxide were mixed together, ultrasonicated for 10min, and then added to the three-necked bottle Medium, N 2 Protect, raise the temperature to 75°C, and react for 6 hours to obtain a colorless and transparent granular polymer, that is, a fluorosilicon-modified acrylic resin.

[0032] The coating formulation is shown in Table 1.

[0033] Table 1

[0034]

[0035]

[0036] Apply the prepared anti-icing coating to the steel core al...

Embodiment 2

[0040] In ensuring that other conditions remain unchanged in Example 1, vinyl trimethylethoxysilane is followed by vinyl triethoxysilane, propenyl trimethoxysilane, propenyl triethoxysilane, gamma-methacryloxy Propyltrimethoxysilane, γ-methacryloxypropyltrimethoxysilane or methacryloxypropyltri(isopropoxy)silane, trifluoropropyltrimethoxysilane, trifluoropropyl Methyldichlorosilane, Trifluoropropylmethylcyclotrisiloxane, Tridecafluorooctyltrimethoxysilane, Trifluoromethyltrimethylsilane, 1H, 1H, 2H, 2H-Perfluorooctyltrimethylsilane (B) oxysilane is replaced to obtain the corresponding organosilicon-modified sodium polyacrylate resin.

[0041] In a 500mL three-neck flask, add 120g of water and 0.4g of sodium lauryl sulfate in sequence, and stir.

[0042] Then 1.2g vinyltriethoxysilane, 15.0g dodecafluoroheptyl methacrylate, 10.0g butyl methacrylate, 0.3g benzoyl peroxide were mixed together, ultrasonicated for 10min, and then added to the three-necked bottle Medium, N 2 Prot...

Embodiment 3

[0047] Add 200mL ethanol, 1.0g vinyltrimethoxysilane, 0.1g trifluoropropylmethyldichlorosilane, 22g acrylic acid into a 500mL three-necked flask, stir, and when the temperature rises to 75°C, add 0.18g azobisisobutyronitrile , reacted for 5 hours, added 13.6g NaOH to the flask, and continued to stir for 3h to obtain silicone-modified sodium acrylate resin.

[0048] In a 500mL three-neck flask, add 120g of water and 0.4g of sodium lauryl sulfate in sequence, and stir. Then 1.2g vinyltriethoxysilane, 15.0g dodecafluoroheptyl methacrylate, 10.0g butyl methacrylate, 0.3g benzoyl peroxide were mixed together, ultrasonicated for 10min, and then added to the three-necked bottle Medium, N 2 Protect, raise the temperature to 75°C, and react for 6 hours to obtain a colorless and transparent granular polymer, that is, a fluorosilicon-modified acrylic resin.

[0049] The paint formulations are shown in Table 4.

[0050] Table 4

[0051]

[0052] *The size of nano-silica sol is betw...

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Abstract

The invention discloses an ice-covering-proof coating containing electrolyte, which consists of organic silicon modified polyelectrolyte, silicon fluoride modified acrylic ester, nanometer material, dissolvent, pigment, aleveling agent, a fire retardant and preservatives and bactericides. All the materials are as follows according to mass percents: 5 to 90% of organic silicon modified polyelectrolyte, 0 to 80% of silicon fluoride modified acrylic ester, 0.1 to 20% of nanometer material, 0 to 60% of dissolvent, 0 to 30% of pigment, 0 to 5% of leveling agent, 0 to 10% of fire retardant and 0 to 3% of preservatives and bactericides. The ice-covering-proof coating is obtained by uniformly grinding all the materials according to the amount. The ice-covering-proof coating is coated on the surfaces of parts such as high-voltage cables, iron towers, telecommunication lines, aircrafts and the like and can effectively prevent the parts from being covered by ice. The method is simple and practical in the engineering, is convenient to control and has lower cost and good using effect.

Description

technical field [0001] The invention relates to an anti-icing coating, which belongs to the technical field of materials. Background technique [0002] With the rapid development of modern industry, the reliability requirements for grid power supply are getting higher and higher. Icing and snowing are natural phenomena, but icing is a natural disaster for power systems, and icing lines seriously threaten the safe operation of power systems. The hazards caused by icing on transmission lines to the power system include mechanical and electrical accidents such as conductor galloping, disconnection, tower collapse, and flashover. Ice and snow on transmission lines seriously threaten the safe and reliable operation of power and communication networks. [0003] Generally speaking, the icing phenomenon of conductors is formed due to various meteorological reasons, which mainly include factors such as temperature, humidity, cold and warm air convection, circulation and wind speed....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F230/08C09D5/14C08F220/06C08F220/22C09D133/02C09D7/12
Inventor 黄驰刘兴海胡铭杰张方方黄艳芬罗运柏
Owner 张家港楚人新材料科技有限公司
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