Surface glaze, white enamel and preparation method thereof
A surface glaze and enamel technology, applied in the field of enamel, can solve the problems of unstable color of the porcelain surface, heat resistance of organic antibacterial agents, influence on human health, etc., and achieve the effect of good antibacterial and antifungal effect and stable color.
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[0018] The invention provides a method for preparing white surface glaze, which uses Na 2 O-B 2 O 3 -SiO 2 -F is glass substrate, TiO 2 As an opacifier, it includes the following steps:
[0019] a) Will contain 10%~20% Na by weight 2 O, 8%~25%B 2 O 3 , 35%~55% SiO 2 , 15%~25%TiO 2 , 1%~5%CaF 2 , 0%~3%MgO, 0.05%~2%CuO, 0.5%~4%P 2 O 5 , 0%~5%CaO, 1%~6%Al 2 O 3 The raw materials are mixed and melted at 1200℃~1300℃, and water quenched into a frit with a diameter of 1mm~3mm. Among them, CuO can be antibacterial and mildew proof, but Cu is a non-ferrous metal. Adding 1 / 1000 will make the white porcelain layer appear blue. Blue, while TiO 2 During firing, white anatase will be generated, and yellow rutile will inevitably be generated. Cyan and yellow are complementary colors. Therefore, when the amount of CuO is added, the generated cyan and yellow will be complementary. Weaken or disappear, so that the whole porcelain layer is still white, and after firing into the porcelain layer, Cu 2...
Embodiment 1
[0024] Will contain 16.5% Na by weight 2 O, 10% B 2 O 3 , 40% SiO 2 , 25%TiO 2 , 3%CaF 2 , 1% MgO, 0.5% CuO, 1% P 2 O 5 , 3% Al 2 O 3 After mixing, the raw materials are melted at 1200°C, and water quenched into a frit with a diameter of 1mm to 3mm.
[0025] The mass ratio is 100:3:6:0.4:48 frit, nano-ZnO, clay, K 2 CO 3 It is ground with water to form a surface glaze slurry, and then the surface glaze slurry is sprayed on a metal blank with a base glaze, and fired at 800°C to obtain an enamel with a white porcelain layer.
Embodiment 2
[0027] Will contain 20% Na by weight 2 O, 15% B 2 O 3 , 34% SiO 2 , 20% TiO 2 , 4%CaF 2 , 1% CuO, 1% P 2 O 5 , 5% Al 2 O 3 After mixing, the raw materials are melted at 1250°C, and water quenched into a frit with a diameter of 1mm to 3mm.
[0028] Grind the frit with a mass ratio of 98:1.5:5:0.4:43, nano-ZnO, bentonite, KCl and water into a top glaze slurry, and then spray the top glaze slurry on the metal billet with a base glaze at 820℃ Fire down to obtain an enamel with a white porcelain layer.
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