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Porous phosphorus removing ceramic granules with function of slowly releasing alkali and preparation method thereof

A slow-release, functional technology, applied in the direction of inorganic chemistry, non-metallic elements, adsorption water/sewage treatment, etc., can solve the problems of lack of large-scale engineering applications, achieve good phosphorus removal effect, increase plasticity, and improve labor production efficiency Effect

Active Publication Date: 2011-01-05
郑俊 +1
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AI Technical Summary

Problems solved by technology

At present, chemical adsorption phosphorus removal technology mainly focuses on the development of adsorbents, but there are many problems in anti-interference, adsorption capacity and operation replacement cost of phosphorus removal adsorbents, and large-scale engineering applications are still lacking.

Method used

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Examples

Experimental program
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Embodiment Construction

[0012] The application process of the present invention will be further described below in conjunction with examples.

[0013] First use quartz powder (silicon dioxide content greater than 98%, particle size is 400 mesh) and slaked lime, according to CaO and SiO 2 The molar ratio of the mixture is 0.98, mixed and stirred evenly, and placed in a dynamic high-pressure reactor for gelation reaction according to the water-solid ratio of 25:1 to generate xonotlite slurry. The reaction temperature is controlled at 200-220°C, and the holding time is 6 hours; After cooling, filter, dehydrate and dry for later use. Then ordinary Portland cement (grade 42.5), bentonite, fly ash, calcium oxide, nitrocellulose, and xonotlite fiber particles were ground into powders with a particle size above 100 mesh, and the ordinary silicate Cement (grade 42.5): bentonite: fly ash: calcium oxide: nitrocellulose: xonotlite fiber particles: pore-forming agent=25:12:16:11.7:15:20:0.3 mass percentage is mi...

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PUM

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Abstract

The invention discloses porous phosphorus removing ceramic granules with a function of slowly releasing an alkali and a preparation method thereof. The prepared ceramic granules are an environmental material for efficiently removing phosphorus from municipal sewage and industrial wastewater. Based on the basic chemical properties of the phosphorus in water and a phosphorus removing mechanism by chemical absorption, the preparation method of the ceramic granules comprises the following steps of: mixing 20 to 40 mass percent of ordinary portland cement (42.5 level), 10 to 20 mass percent of bentonite, 10 to 20 mass percent of fly ash, 10 to 15 mass percent of calcium oxide, 15 to 25 mass percent of nitrocellulose, 14 to 30 mass percent of xonotlite fiber particle and 0.1 to 0.5 mass percent of pore-creating agent; adding water for stirring the mixture according to a water-solid ratio of 0.35 to 0.45; granulating the mixture into granules with required grain sizes; and after the granules are foamed and solidified, curing the granules by using high-temperature steam to obtain the ceramic granules. The method has the advantages of simple preparation process, readily available raw materials, low cost and wide application prospect in the field of the removing of the phosphorus in water bodies. The prepared ceramic granules have the characteristics of capacity of slowly releasing the alkalis, silicic and calcareous textures, porosity, capacity of continuously and efficiently absorbing and removing the phosphorus and suitability for phosphorus removing systems of the municipal sewage and the industrial wastewater.

Description

technical field [0001] The invention relates to a porous ceramsite filter material capable of chemisorbing phosphate in water bodies and a manufacturing method thereof, more specifically, a porous ceramsite filter material capable of chemically adsorbing and degrading phosphate in water bodies and its preparation method. The preparation method is suitable for phosphorus removal systems of municipal sewage and industrial wastewater, and belongs to the technical field of environmental engineering water treatment. technical background [0002] With the eutrophication of water body highlighted, the discharge of phosphorus in sewage has received more and more attention. At present, the sewage treatment system is still unable to eliminate and compensate for the strong disturbance of nitrogen and phosphorus in the natural process by human activities, and the existing sewage system will still cause some nitrogen and phosphorus to eventually be lost in the water environment. To effe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04B01J20/10C02F1/28
Inventor 郑俊刘宝河孟冠华
Owner 郑俊
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