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Recycle method of pulping effluent of wheat straw chemi-mechanical pulp

A technology for pulping waste liquid and recycling, applied in chemical instruments and methods, non-fibrous pulp addition, water/sludge/sewage treatment, etc., can solve the problems of high application cost and poor operability, and achieve strong pertinence , the effect of less investment and broad development prospects

Inactive Publication Date: 2011-12-28
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In recent years, researchers at home and abroad have isolated hemicellulose from plant fiber raw materials or pulping waste liquid to modify it for surface sizing, beating process, and papermaking wet end addition, etc., and have achieved good expected results. Relatively important theoretical value, but in practical application, there are problems of poor operability and high application cost

Method used

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  • Recycle method of pulping effluent of wheat straw chemi-mechanical pulp

Examples

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Effect test

Embodiment 1

[0019] (1) pre-concentrating the waste liquid of wheat straw chemical pulping, after concentration, the mass concentration is 10%, and standing for several days until the upper and lower layers;

[0020] (2) Take the clarified liquid from the upper layer, adjust the pH to 9, then, stir it electrically in a water bath at 25°C for 5 minutes, then raise the temperature of the water bath to 60°C, and add the mixture of formaldehyde and potassium persulfate within 1 hour , stirring and reacting for 7 hours, and finally, adding hydrochloric acid to adjust the pH to be neutral, wherein the clarified liquid in the upper layer: formaldehyde: the mass ratio of potassium persulfate is 100:20:8;

[0021] (3) Add aluminum chloride to OCC (Old Corrugated Containers) waste paper pulp to decompose for 3 minutes, then add the modified waste liquid obtained in step (2) to decompose for 5 minutes, and finally make corrugated base paper, wherein aluminum chloride The addition amount accounts for ...

Embodiment 2

[0024] (1) Pre-concentrating the pulping waste liquid of wheat straw chemical pulping, the mass concentration is 15%, and standing for several days until the upper and lower layers;

[0025] (2) Take the clarified liquid from the upper layer, adjust the pH to 13, then, stir it electrically in a water bath at 45°C for 10 minutes, then increase the temperature of the water bath to 70°C, and add glyceryl trimethyl chloride within 1 hour The mixed solution of ammonium chloride and sodium hydroxide was stirred and reacted for 4 hours, and finally, adding acetic acid solution to adjust the pH to be neutral, wherein, the clarified liquid of the upper layer: the mass ratio of glyceryl trimethylammonium chloride: sodium hydroxide 100:25:5;

[0026] (5) Add aluminum sulfate to OCC (Old Corrugated Containers) waste paper pulp to decompose for 5 minutes, then add the modified waste liquid obtained in step (2) to decompose for 5 minutes, and make corrugated base paper, wherein the amount o...

Embodiment 3

[0029] (1) Carry out pre-concentration treatment on the pulping waste liquor of wheat straw chemical pulping, the mass concentration is 30%, and let it stand for several days until it is layered up and down;

[0030] (2) Take the clarified liquid of the upper layer, adjust the pH to 10, then, stir electrically in a water bath at 30°C for 20 minutes, then raise the temperature of the water bath to 80°C, and add maleic anhydride and ammonium persulfate within 1 hour. The mixed solution was stirred and reacted for 5 hours, and finally, a sulfuric acid solution was added to adjust the pH to be neutral, wherein the clarified liquid of the upper layer: maleic anhydride: the mass ratio of ammonium persulfate was 100:40:10;

[0031] (7) Add cationic starch to OCC (Old Corrugated Containers) waste paper pulp to decompose for 5 minutes, then add the modified waste liquid obtained in step (2) to decompose for 3 minutes, and make corrugated base paper. It accounts for 1.2% of the mass of ...

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Abstract

The invention provides a recycle method of pulping effluent of wheat straw chemi-mechanical pulp, which comprises the following steps of (1) concentrating the pulping effluent of the wheat straw chemi-mechanical pulp to the mass concentration of 10 to 30% and standing until delamination; (2) regulating supernatant liquid to be alkalinity, and then stirring for 5 to 20 minutes in a water bath of 25 to 55 DEG C; (3) adding the mixture of functional monomers and catalysts in an hour after increasing the temperature of the water bath to 60 to 85 DEG C, uniformly stirring, and then regulating the pH value to neutrality to prepare a wet end additives of semi-chemical corrugated paper, wherein the mass ratio of the supernatant liquid to the functional monomers to the catalysts is 100: (20 to 45): (5 to 10); and (4) taking away lower sediments, mixing with an adhesive X at the temperature of 25 to 45 DEG and adding functional additives to prepare a laminating agent of the semi-chemical corrugated paper. The invention can ensure that the effluent is processed and then used as the wet end additive and the laminating agent of the semi-chemical corrugated paper, thereofre the effluent is fully utilized and resources are saved; and moreover the operation is simple and the cost is low.

Description

【Technical field】 [0001] The invention belongs to the field of energy saving and comprehensive resource utilization in the pulp and paper industry, in particular to a method for resource utilization of wheat straw chemical pulping waste liquid. 【Background technique】 [0002] The chemical-mechanical pulping process is a pulping method that uses light chemical treatment and mechanical refining to produce pulp. Compared with the traditional chemical pulp production process, the chemical treatment conditions for fiber raw materials in the chemical-mechanical pulp production process are relatively mild, such as the amount of chemicals used is less, the treatment temperature is lower and the treatment time is shorter, resulting in the remaining in the pulp. There are more components such as carbohydrates and lignin, and correspondingly less organic matter and residual chemicals dissolved in the pulping wastewater, so the pulping yield is higher, and the content of harmful substan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04D21H21/14
Inventor 韩卿刘冉
Owner SHAANXI UNIV OF SCI & TECH
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