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Method for making rare earth elements uniformly distributed on surface of aluminum-silicon alloy

An aluminum-silicon alloy, surface uniform technology, applied in the field of materials, can solve problems such as the influence of alloy properties, limit the expected metamorphic effect of the alloy, etc., and achieve the effects of uniform surface composition, uniform distribution of rare earth composition, and convenient operation.

Inactive Publication Date: 2012-06-06
无锡东大工业研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Gao Bo et al. conducted a preliminary study on the structure changes of eutectic silicon and primary silicon with Nd added, and found that the addition of Nd can refine the silicon phase, but the rare earth element Nd is enriched, and the addition of high content Nd (> 1%) in the casting The resulting alloy microstructure presents a coarse needle-like distribution. This phenomenon will not only limit the expected modification effect of the rare earth element Nd on the alloy, but also the segregation of the Nd element will also affect the properties of the alloy.

Method used

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  • Method for making rare earth elements uniformly distributed on surface of aluminum-silicon alloy
  • Method for making rare earth elements uniformly distributed on surface of aluminum-silicon alloy
  • Method for making rare earth elements uniformly distributed on surface of aluminum-silicon alloy

Examples

Experimental program
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Effect test

Embodiment 1

[0023] The aluminum-silicon alloy composition used is Al-12.6Si-1Nd.

[0024] The above-mentioned aluminum-silicon alloy is cut out by wire cutting, and the surface of the section of the aluminum-silicon alloy ingot is ground and polished; then the surface of the ingot is cleaned with an organic solvent, and the organic solvent on the surface of the ingot is removed.

[0025] Place the aluminum-silicon alloy ingot after surface pretreatment in the Nadezhda-2 high-current pulsed electron beam equipment, in a vacuum degree ≤ 10 -3 Under the condition of Pa, the high-current pulsed electron beam is applied to modify the surface of the cross-section. The working parameters of the high-current pulsed electron beam are: the acceleration voltage is 23kV, the number of pulses is 15 times, and the processing time is 15μs. The specific heating and cooling process is completed in the alloy surface modification layer, and the heating rate is 10 7 ~10 8 K / s, the solidification rate reach...

Embodiment 2

[0031] The aluminum silicon alloy that adopts is the same as embodiment 1.

[0032] The surface pretreatment method that adopts is with embodiment 1.

[0033] The electron beam heat treatment method adopted is the same as that in Embodiment 1, except that the number of pulses is 25 and the treatment time is 25 μs. The wear resistance of the treated aluminum-silicon alloy section is increased by 2 to 3 times. Compared with the number of pulses in Example 1, which was 15 times, the distribution of the rare earth element Nd on the surface of the aluminum-silicon alloy after treatment is more uniform.

Embodiment 3

[0035] The composition of the aluminum-silicon alloy is Al-17.5Si-0.3Nd.

[0036] The surface pretreatment method that adopts is with embodiment 1.

[0037] The electron beam heat treatment method that adopts is the same as embodiment 1.

[0038] The surface morphology of the alloy after electron beam treatment was observed by means of SEM, and the microstructure and surface composition changes were as follows: Figure 5As shown, it can be seen from the figure that the rare earth element Nd, which presents a dotted distribution on the surface of the untreated sample (due to the reduction in the amount of Nd added), still presents a "cloud" distribution due to diffusion after the electron beam bombards the alloy surface. The problem of Nd element segregation in cast alloy microstructure is solved. In addition, the modification of the electron beam can refine the surface structure of the alloy and redistribute the chemical elements, all of which are conducive to the realizatio...

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Abstract

The invention relates to a method for making rare earth elements uniformly distributed on the surface of an aluminum-silicon alloy, and belongs to the technical field of materials. The method comprises the following steps of: (1) selecting aluminum-silicon alloy cast ingots which comprise the following components in percentage by weight: 12.6 to 25 percent of Si, 0.1 to 2 percent of RE and the balance of Al; cutting cross sections on the aluminum-silicon alloy cast ingots by using a linear cutting method, and grinding and polishing the surfaces of the cross sections; and then cleaning the surfaces with an organic solvent, and removing the organic solvent; and (2) placing the aluminum-silicon alloy cast ingots under the condition of less than or equal to 10<-3>Pa of vacuum degree, and applying high current pulse electron beams to modify the surfaces of the cross sections, wherein the working parameters comprises 23 to 27kV of accelerating voltage and 5 to 25 times of pulse frequency. The method has the advantages of simple process, convenient operation and high energy utilization rate. Tissues quickly fused on the surface of the aluminum-silicon alloy are refined; all the chemical elements are alternatively reallocated; components on the surface are homogenized; and the hardness and toughness can be better matched.

Description

technical field [0001] The invention belongs to the technical field of materials, in particular to a method for uniformly distributing rare earth elements on the surface of an aluminum-silicon alloy. Background technique [0002] Silicon is the main alloying element of aluminum-silicon alloy, which makes the alloy have high fluidity and low shrinkage, so the alloy has excellent casting performance, making aluminum-silicon alloy suitable for manufacturing cylinder heads, pistons, transmission housings, transmissions, Parts such as exhaust pipes have a wide range of application prospects. At present, the aluminum-silicon alloy piston material used in China is mainly eutectic aluminum-silicon alloy. The existence of acicular eutectic silicon, the mechanical properties of the alloy are not high, the tensile strength does not exceed 140MPa, and the elongation δ is less than 3%, which limits the application range of the eutectic aluminum-silicon alloy to a certain extent. In add...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22F1/04
Inventor 高波郝仪涂赣峰郝胜智董闯
Owner 无锡东大工业研究院有限公司
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