Low-refractive index film, method for forming the low-refractive index film, and antireflection film
A low-refractive-index film and deposition method technology, applied in the field of anti-reflection films, can solve the problems of difficult deposition of anti-reflection films and low-refractive-index films, and achieve the effects of uniform anti-reflection function and good anti-reflection function
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Embodiment 1
[0040] will be used for figure 1 The reactive sputtering apparatus SE shown, an example of depositing a low-refractive-index film by the method for depositing a low-refractive-index film of the present invention will be described. It should be noted that regarding sputtering conditions, targets 4A and 4B were used: MgF 2 -SiO 2 Sintered body (MgF 2 : SiO 2 =70:30 atomic percent); sputtering gas: Ar; and reaction gas: O 2 As a common condition, and with vacuum chamber 1 inside 5 x 10 -4 Ar gas is introduced at a back pressure below Pa, and pre-sputtering is performed. Subsequently, a low-refractive-index film was prepared under the following deposition conditions. It should be noted that (O 2 Gas flow ratio) = (O 2 gas flow) / {(O 2 Gas flow)+(Ar gas flow)}×100(%).
[0041] (deposition condition)
[0042] Substrate 11: transparent glass substrate
[0043] ·O 2 Gas flow ratio: 0%, 20%, 40%, 50% and 100%
[0044] · Frequency of AC power supply: 90kHz
[0045] ·Suppli...
Embodiment 2
[0097] will be used for figure 1 An example of the deposition of an anti-reflection film is described using the reactive sputtering apparatus SE shown.
[0098] Here, based on the following respective deposition conditions, a film having Figure 4 Anti-reflective coating of the structure shown.
[0099] (1) Substrate: glass substrate
[0100] (2) Adhesive layer: SiO x
[0101] Sputtering target: Boron-doped polysilicon
[0102] · Sputtering gas: Ar
[0103] Reactive gas: O 2
[0104] (3) High refractive index layer a: Nb 2 o 5
[0105] Sputtering target: metal Nb
[0106] · Sputtering gas: Ar
[0107] Reactive gas: CO 2
[0108] ·Film thickness: 25nm
[0109] (4) Low refractive index layer a: MgF 2 -SiO 2
[0110] · Sputtering targets 4A and 4B: MgF 2 -SiO 2 Sintered body (MgF 2 : SiO 2 =70:30 atomic percent)
[0111] · Sputtering gas: Ar
[0112] Reactive gas: O 2
[0113] Deposition conditions: same as those used in the fourth sample of Example 1
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