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60% high solid content pressure-sensitive adhesive and preparation method thereof

A high-solid content, pressure-sensitive adhesive technology, applied in adhesive types, ester copolymer adhesives, etc., can solve the problems that pressure-sensitive adhesives are difficult to achieve satisfactory results, difficult, and toxic

Inactive Publication Date: 2010-03-24
成都航天明江科技实业有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] For a long time, most glues used in the manufacture of protective films are solvent-based pressure-sensitive adhesives. Because most of the commonly used solvents are toxic and harmful organic compounds, the existing solvent-based pressure-sensitive adhesives pollute the environment and cause harm to the human body. high
Although there are a few environmentally friendly pressure-sensitive adhesives in the market, their solid content is far lower than 60%, which is not conducive to low-cost production. Some have high viscosity and poor leveling, and some are compatible with certain substrates Poor capacitance, causing difficulties
In short, the existing pressure-sensitive adhesives are difficult to achieve satisfactory results.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0021] The present invention will be further described below in conjunction with the examples: set to produce 200 kg of pressure-sensitive adhesive with a solid content of 60%.

[0022] 1. Raw materials and their dosage:

[0023] (1) Monomer

[0024] Butyl acrylate 101.5kg

[0025] Methyl methacrylate 6.0kg

[0026] Hydroxyethyl Acrylate 3.5kg

[0027] Acrylic 2.5kg

[0028] (2) Mixed emulsifier 2.7kg

[0029] in:

[0030] Sodium Lauryl Sulfate 1.8kg

[0031] Octylphenol ethoxylate 0.9kg

[0032] (3) Initiator

[0033] Ammonium persulfate 4.9kg

[0034] (4) Deionized water 79.0kg

[0035] 2. Production process

[0036] (1) Take 15kg of deionized water, 0.6kg of emulsifier, 10.15kg of butyl acrylate, 0.6kg of methyl methacrylate, 0.35kg of hydroxyethyl acrylate, and 0.25kg of acrylic acid into the reactor;

[0037] (2) be warming up to 77 ℃, add the ammonium persulfate solution that is made into 10% weight percentage concentration by 2.4kg ammonium persulfate;

[0...

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PUM

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Abstract

The invention relates to a 60% high solid content pressure-sensitive adhesive and a preparation method thereof, and discloses a way for obtaining environment-friendly pressure-sensitive adhesive whichis applicable to manufacturing a surface protective film of building materials, electrical and electronic products, machines, furniture and the like. The pressure-sensitive adhesive is prepared by adopting a semi-continuous seed emulsion polymerization, taking butyl acrylate, methyl methacrylate, hydroxy-ethyl acrylate and acrylic acid as monomers, synchronously adding mixed emulsifying agent formed by anionic emulsifying agent and nonionic emulsifying agent as well as mixed liquid formed by initiating agent and ammonium persulphate, and having polymerization reaction in subacid deionized water. The pressure-sensitive adhesive has no emission of noxious and harmful substances when in production and use, so as to purify the environment. Meanwhile, the protective film and base material produced by the pressure-sensitive adhesive has better combination, do not damage the surface of the protected object, and can be torn off from the surface of the protected object so as to leave no residual trace.

Description

Technical field [0001] The invention belongs to the technical field of chemical industry, and is an environment-friendly pressure-sensitive adhesive with high solid content, which is suitable for the manufacture of surface protective films of building materials, electronic and electrical products, metal profiles, machinery, furniture and the like. Background technique [0002] For a long time, most glues used in the manufacture of protective films are solvent-based pressure-sensitive adhesives. Because most of the commonly used solvents are toxic and harmful organic compounds, the existing solvent-based pressure-sensitive adhesives pollute the environment and cause harm to the human body. high. Although there are a few environmentally friendly pressure-sensitive adhesives in the market, their solid content is far lower than 60%, which is not conducive to low-cost production. Some have high viscosity and poor leveling, and some are compatible with certain substrates Poor cap...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C08F220/18C08F2/24
Inventor 陈格德谯雅文钟安永吴利英孟文清
Owner 成都航天明江科技实业有限公司
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