Optical polyester film with multilayer structure and preparation method thereof
A technology of optical polyester film and multi-layer structure, which is applied in the field of polyester film, can solve the problems of affecting the thermal performance of optical film, not conducive to improving thermal performance, affecting the optical performance of film, etc., achieving excellent optical performance and processing performance, improving Apparent flatness, effect of improving surface inertia
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Embodiment 1
[0048] Mix the polyethylene terephthalate polyester chips with intrinsic viscosity of 0.65dl / g and the masterbatch chips containing nano-silica additives evenly, so that the final nano-silica content is 300ppm, and mix well The chips were crystallized and dried at 170°C, and then the crystallized material was fed into a single-screw basic machine for melt extrusion at 280°C.
[0049] Mix polyethylene terephthalate polyester chips with an intrinsic viscosity of 0.60dl / g and polyester masterbatch chips containing nano-scale titanium dioxide and micron-scale cross-linked polystyrene composite additives evenly, nano-titanium dioxide and micron polystyrene The weight ratio of styrene is 4:1, so that the final additive content is 600ppm. The mixed material is crystallized and dried at 170°C, and then sent to a twin-screw extruder for melt extrusion at 282°C.
[0050] The above two molten materials are passed through a co-extrusion die, and the melt is cast onto a rotating cooling dr...
Embodiment 2
[0054] The polyethylene terephthalate polyester chip that intrinsic viscosity is 0.80dl / g is mixed with the polyester masterbatch chip of nanometer aluminum oxide additive, makes the content of final nanometer aluminum oxide be 800ppm, will The mixed material is crystallized and dried at 170°C, and then the crystallized material is fed into a single-screw basic machine for melt extrusion at 270°C.
[0055] Mix polyethylene terephthalate polyester chips with an intrinsic viscosity of 0.55dl / g and polyester masterbatch chips containing nano-scale silicon dioxide and micron-scale cross-linked polymethacrylate composite additives evenly. The weight ratio of silicon dioxide and micron polymethacrylate is 12:1, so that the content of the final additive is 1000ppm, the mixed material is crystallized and dried at 170°C, and then sent into a twin-screw extruder at 275°C under melt extrusion.
[0056] The above two molten materials are passed through a co-extrusion die, and the melt is...
Embodiment 3
[0060] Polyethylene terephthalate polyester chips with an intrinsic viscosity of 0.55dl / g are crystallized and dried at 170°C, and then the crystallized material is fed into a single-screw basic machine for melt extrusion at 290°C.
[0061] Mix polyethylene terephthalate polyester chips with an intrinsic viscosity of 0.80dl / g and polyester masterbatch chips of nano-calcium carbonate and micro-silica composite additives evenly, and the nano-calcium carbonate and micro-silica The weight ratio is 20:1, and the final additive content of the uniformly mixed polyester chips is 10 ppm. The mixed material is fed into a twin-screw extruder, and melted and extruded at 290°C.
[0062] The above two molten materials pass through a co-extrusion die, and the melt is cast onto a rotating cooling drum to form an amorphous A / B / A three-layer cast thick film.
[0063] The cast slab film was preheated to about 80° C., then longitudinally stretched at a longitudinal stretch ratio of 2.5:1, and the...
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