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Compound dephosphorization agent with converter slag as raw material and preparing method thereof

A technology of compound dephosphorization agent and converter slag, applied in lime production and other directions, can solve the problems of complex processing of pre-melting dephosphorization agent, long time for dephosphorization of dephosphorization agent, unstable performance of dephosphorization agent, etc., so as to reduce slag production. volume, shorten the processing time, and the effect of good fluidity

Inactive Publication Date: 2009-10-21
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, some metallurgists have studied the dephosphorization of molten iron with lime-based dephosphorization agent combined with converter slag, but most of them only add powdery or massive converter slag to solid synthetic slag, so there are inevitable shortcomings : (1) Converter slag has high basicity and high melting point, and the dephosphorization agent takes a long time to dissolve slag after adding it, and the dephosphorization rate is low, which increases the time and temperature drop; (2) The solid synthetic dephosphorization agent containing converter slag is formulated A large amount of active lime is added, which is easy to absorb moisture and is not conducive to storage and transportation; (3) Due to the large difference in particle size and density, component segregation is easy to occur, resulting in unstable performance of the dephosphorization agent and sometimes causing phosphorus reversion
[0005] The premelted dephosphorization agent containing converter slag has not been widely used because of complicated processing and high cost.

Method used

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  • Compound dephosphorization agent with converter slag as raw material and preparing method thereof
  • Compound dephosphorization agent with converter slag as raw material and preparing method thereof

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specific Embodiment approach

[0033] A composite dephosphorization agent for molten iron pretreatment using converter slag as raw material, which is composed of the following raw materials and their weight percentages: 45-55% of converter slag, 3-5% of quartz sand, 22-34% of rolled steel skin, and 3% of bauxite ~6%, soda 10~14%, fluorite 0~5%. Raw materials that meet the composition requirements are crushed and mixed uniformly according to the above ratio, and after ball milling, sieving, pelletizing and drying, they are made into finished products with a diameter of 20-50mm. During the pretreatment of molten iron, the total amount of compound dephosphorization agent added is 15-25Kg per ton of steel. When in use, put it into the scrap steel trough, and add it together with the scrap steel at one time. Then, according to the conditions in the furnace, lime and slag-reducing agents are added in time to control the final composition of the slag within the target range. Converter slag is metallurgical slag ...

Embodiment 1

[0043] In this embodiment, the composition and weight percentage of the composite dephosphorization agent are: 54% converter slag, 24% rolled steel sheet, 3% quartz sand, 6% bauxite, and 13% soda. Since a certain amount of soda contained in this embodiment can improve the fluidity of slag, based on the purpose of environmental protection and reducing lining erosion, no fluorite is added in this embodiment. After the finished product is made according to the aforementioned method, according to the actual measurement results, the binary alkalinity of the dephosphorization agent is about 1.85, and the hemispherical point temperature is 1241°C, which meets the temperature requirements of molten iron under normal circumstances. The test adopts the double slag method, that is, the low-temperature dephosphorization operation is carried out first, and part of the converter slag is poured out when pouring, and then the slagging agent is added for decarbonization blowing. This embodimen...

Embodiment 2

[0049] In this embodiment, the composition and weight percentage of the composite dephosphorization agent are: converter slag: 50%, rolled steel sheet 26%, quartz sand 3%, bauxite 4%, soda 12%, fluorite 5%. After the finished product is made according to the aforementioned method, the binary alkalinity of the dephosphorization agent is about 1.8 and the temperature of the hemispheric point is 1235° C., which meets the temperature requirements of molten iron under normal conditions. Under the simulated dephosphorization condition of 1350℃, the slag is in good condition.

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Abstract

The invention discloses a molten iron pretreatment compound dephosphorization agent with converter slag as the raw material, and the compound dephosphorization agent contains the following raw materials by weight: 45 to 55 percent of converter slag, 3 to 5 percent of quartz sand, 22 to 34 percent of steel-rolling iron sheet, 3 to 6 percent of bauxite, 10 to 14 percent of soda and 0 to 5 percent of fluorite; the raw materials meeting the ingredient demands are evenly mixed according to the proportions after being crushed, and then the product with the diameter being 20 to 50mm is produced after ball-milling, screen separation, palletizing and drying. The compound dephosphorization agent realizes cyclic utilization of the converter slag which accounts for 45 to 55 percent, thus reducing the produced slag amount in the steel-making process and the environmental load; the converter slag contains plenty of CaO and FeO, which can reduce consumption of lime to a certain degree, thus increasing the metal yield rate and reducing the steel-making cost; the compound dephosphorization agent has low melting point, slag can be formed fast, the liquidity is good, thus shortening the treatment time, the dephosphorizing efficiency is high, and the dephosphorized final slag has low alkalinity and low melting point.

Description

technical field [0001] The invention relates to a molten iron pretreatment composite dephosphorization agent used in the field of metallurgy and a preparation method thereof, in particular to a molten iron pretreatment composite dephosphorization agent using steelmaking converter slag as a basic raw material and a preparation method thereof. Background technique [0002] In recent years, my country's iron and steel industry has developed rapidly, and the output of steel has increased year by year. The output of metallurgical slag derived from this has also increased significantly. The annual output of converter slag alone has reached tens of millions of tons. The cumulative stockpiles and newly added converter slag are increasing day by day, which not only causes a serious waste of resources, but also occupies a large area of ​​land and pollutes the surrounding environment. Since the utilization of converter slag still lacks practical and effective ways, its comprehensive ut...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/064
CPCY02P40/40
Inventor 谢兵刁江王雨王谦何生平王永红郭戌李晓军
Owner CHONGQING UNIV
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