Limestone powder mineral admixture special for concrete and preparation method thereof

A technology of mineral admixture and limestone powder, which is applied in the field of concrete admixture and its preparation, can solve the problems of reducing the fluidity of concrete, little improvement in cement and concrete performance, and poor sphericity, so as to improve concrete performance and shorten powder The effect of grinding time and improving workability

Inactive Publication Date: 2011-10-05
武汉混凝土协会
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, my country is in a period of rapid development of infrastructure construction, and the amount of concrete is increasing rapidly. A large amount of limestone is mined every year as concrete coarse aggregate. According to relevant national standards, the particle size of concrete coarse aggregate is required to be above 4.75mm, which will inevitably produce a large amount of 4.75mm The following stone chips and stone powder will occupy a large amount of land if they are piled up for a long time, which is not conducive to the protection of the ecological environment.
The current processing method is mainly to use it as artificial sand for concrete, or as a mixture of cement after grinding. Using these methods to process limestone powder, not only the economic benefits are not obvious, but also the performance of cement and concrete is not greatly improved.
[0003] Using limestone chips as artificial sand to replace part of the river sand has a great impact on the working performance of concrete. Due to the irregular shape and poor sphericity of the stone chips, the fluidity of concrete will be reduced.
Grinding stone chips and mixing them into cement as a mixture can improve the water retention performance of cement and increase the early strength of cement, but the amount is only about 5% of cement, and the amount is very limited. It is difficult to consume a large amount of limestone mines. stone chips

Method used

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  • Limestone powder mineral admixture special for concrete and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Put 5 parts of citric acid, 50 parts of oxalic acid, 500 parts of quartz powder, and 10,000 parts of limestone powder dried at 120°C into the mixer, mix them evenly, then feed them into the ball mill, and grind until the specific surface area is 600m 2 / kg to obtain a special limestone powder mineral admixture for concrete. Adding 20% ​​(mass) of this mineral admixture in P.O42.5, see Table 3 for the impact on cement standard consistency water consumption and setting time.

[0022] Table 3 Effect of a special limestone powder mineral admixture for concrete on the performance of cement slurry

[0023] Performance

[0024] It can be seen from Table 3 that the addition of 20% limestone powder mineral admixture has little effect on the water consumption of cement standard consistency, but the setting time is prolonged by about 40-50 minutes, which has a certain retarding effect.

Embodiment 2

[0026] Put 10 parts of citric acid, 60 parts of oxalic acid, 600 parts of quartz powder, and 10,000 parts of limestone powder (or limestone chips) dried at 100°C into a mixer, mix them evenly, and then feed them into a ball mill and grind them until Surface area 700m 2 / kg to obtain a special limestone powder mineral admixture for concrete. Add 10% (mass) of this mineral admixture in P.O42.5, and the influence on the strength of cement mortar is shown in Table 4.

[0027] Table 4 Effect of a special limestone powder mineral admixture for concrete on the fluidity and strength of cement mortar

[0028]

[0029] It can be seen from Table 4 that the fluidity of cement mortar increases significantly when 10% limestone powder mineral admixture is added. The 3d and 28d flexural strengths both increased, the 3d compressive strength increased significantly, and the 28d compressive strength decreased slightly. The special limestone powder mineral admixture for concrete prov...

Embodiment 3

[0031] Put 10 parts of citric acid, 60 parts of oxalic acid, 600 parts of quartz powder, and 10,000 parts of limestone powder dried at 100°C into the mixer, mix them evenly, then feed them into the ball mill, and grind until the specific surface area is 700m 2 / kg to obtain a special limestone powder mineral admixture for concrete. The concrete test was carried out according to the ratio in Table 5, and the test data are shown in Table 6.

[0032] Table 5 concrete test mix ratio

[0033]

[0034] Table 6 Concrete Properties

[0035] serial number

[0036] It can be seen from Table 5 and Table 6 that when 50kg of limestone powder mineral admixture is used to replace 20kg of cement and 30kg of fly ash, the fluidity of concrete is significantly improved, the slump loss is reduced, the strength of 7d is increased, and the strength of 28d is slightly decreased. The use of the special limestone powder mineral admixture for concrete provided by the invention can...

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Abstract

The invention relates to an admixture for concrete and a preparation method thereof. A limestone powder mineral admixture special for the concrete is characterized in that the admixture is prepared by mixing and grinding limestone powder, citric acid, oxalic acid and quartz powder; the admixture comprises the following raw materials in portion by weight: 10,000 portions of the limestone powder, 3to 10 portions of the citric acid, 40 to 60 portions of the oxalic acid and 400 to 600 portions of the quartz powder; and the content of calcium carbonate in the limestone powder is not lower than 85 percent, and the specific surface area is between 500 and 700 m<2> / kg. The admixture has better early strength function, has small influence on later strength, has good retarding effect, greatly improves the performance of the concrete, and can obtain better economic benefit.

Description

technical field [0001] The invention relates to a concrete admixture and a preparation method thereof. Background technique [0002] At present, my country is in a period of rapid development of infrastructure construction, and the amount of concrete is increasing rapidly. A large amount of limestone is mined every year as concrete coarse aggregate. According to relevant national standards, the particle size of concrete coarse aggregate is required to be above 4.75mm, which will inevitably produce a large amount of 4.75mm Long-term stacking of the following stone chips and stone powder will occupy a large amount of land, which is not conducive to the protection of the ecological environment. The current processing method is mainly to use it as artificial sand for concrete, or as a mixture of cement after grinding. Using these methods to process limestone powder, not only the economic benefits are not obvious, but also the performance of cement and concrete is not greatly impr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B14/06C04B24/04C04B18/12
CPCC04B40/0039C04B2103/14C04B2103/22
Inventor 彭波张晓秋周宇飞刘福生付天全黄修林田焜唐容江王兴盛陈宪清陈森张泳
Owner 武汉混凝土协会
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