Method for preparing 4-vinyl benzyl surface-active macromonomer
A vinylbenzyl-type, surface-active technology, used in chemical instruments and methods, drilling compositions, transportation and packaging, etc. Temperature resistance and thermal stability, improved viscosity and enhanced oil recovery
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Embodiment 1
[0020] Add 20 parts of octylphenol polyoxyethylene ether (the adduct EO of polyoxyethylene ether is 10), 18 parts of solvent acetone, and 0.5 parts of catalyst sodium into a three-necked reaction flask equipped with a reflux condensation device, and stir the reaction at room temperature After 1 hour, the temperature was raised to 45°C, 3 parts of 4-vinylbenzyl chloride were added, and the reaction was continued for 6 hours. The solvent was distilled off from the reaction product under reduced pressure to obtain a crude product, which was then separated by silica gel column chromatography to obtain 4-vinylbenzylalkylphenol polyoxyethylene ether with a yield of 61%.
Embodiment 2
[0022] Add 20 parts of nonylphenol polyoxyethylene ether (the adduct EO of polyoxyethylene ether is 20), 60 parts of solvent N, N-dimethylformamide, and 2.3 parts of catalyst sodium hydride into the three-port port equipped with a reflux condensing device. In the reaction flask, the reaction was stirred at room temperature for 1 h, then the temperature was raised to 60° C., 5.5 parts of 4-vinylbenzyl chloride was added, and the reaction was continued for 24 hours. The solvent was distilled off from the reaction product under reduced pressure to obtain a crude product, which was then separated by silica gel column chromatography to obtain 4-vinylbenzylalkylphenol polyoxyethylene ether with a yield of 74%.
Embodiment 3
[0024] Add 20 parts of dodecylphenol polyoxyethylene ether (the adduct EO of polyoxyethylene ether is 15), 150 parts of solvent tetrahydrofuran, and 5.8 parts of catalyst sodium carbonate into a three-necked reaction flask equipped with a reflux condensation device. The reaction was stirred for 1 h, then the temperature was raised to 60° C., 22 parts of 4-vinylbenzyl chloride were added, and the reaction was continued for 24 hours. The solvent was distilled off from the reaction product under reduced pressure to obtain a crude product, which was then separated by silica gel column chromatography to obtain 4-vinylbenzylalkylphenol polyoxyethylene ether with a yield of 92%.
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