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Environment-friendly lythidathion emulsion and preparation method thereof

A thiazophos emulsion and an environment-friendly technology are applied in the formulation and preparation field of the environment-friendly thiazophos emulsion, which can solve the problems of easy decomposition, influence on the use of thiazophos, unpleasant smell of thiazophos, and the like, and achieve the effect of a simple preparation method.

Active Publication Date: 2009-06-03
山东华阳农药化工集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Since January 1, 2007, my country has completely banned methamidophos and other five highly toxic pesticides. Thiazophos should be one of the important alternatives, but currently the dosage form of thiazophos is only granules (10% thiazophos GR, China People's Republic of Pesticide Registration Certificate No.: LS20020026), far from meeting the needs of the market
[0007] Thiazophos granules are unstable and easy to decompose. Thiazophos has an unpleasant smell, and the smell is long-lasting and difficult to eliminate, thus affecting the use of thiazophos to a certain extent.
[0008] A large amount of toluene, xylene and other solvents are added to traditional emulsifiable concentrates, which on the one hand increases the risk of inflammability and explosion in the production, storage and transportation of pesticides; on the other hand increases the pollution to the environment and seriously affects the survival of human beings. surroundings

Method used

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  • Environment-friendly lythidathion emulsion and preparation method thereof
  • Environment-friendly lythidathion emulsion and preparation method thereof
  • Environment-friendly lythidathion emulsion and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Add 680L of methylated rapeseed oil and 120L of thiazole phosphorous crude oil into a mixing tank with a high-speed stirring device, start stirring to mix evenly, then add lauryl alcohol polyoxyethylene ether phosphate in batches while stirring and heating up 225kg and 900g of defoamer organic silicone; after mixing evenly, add 15kg of hydroxyethyl methylcellulose and 45kg of co-solvent ethylene glycol, stir vigorously and keep warm at 50°C for 2h; after lowering the temperature to room temperature, stir while Add 100g of 1.4-butanediamine and 450g of lemon essence, mix well, and it will become a transparent oily liquid, which is the finished product.

[0026] The cold storage stability was stored at 0°C for 7 days, the thermal stability was stored at 54±2°C for 14 days, and the emulsion stability was measured by diluting 200 times with standard hard water. The results are shown in Table 2.

[0027] Table 2 Sample Stability Test

[0028]

[0029] 62% thiazophos emul...

Embodiment 2

[0036] Add 360L of ethylated castor oil and 400L of thiazole phosphorous crude oil into a mixing tank with a high-speed stirring device, start stirring to mix evenly, then add 120kg of nonylphenol polyoxyethylene ether and Antifoaming agent organosilicone 500g, after mixing evenly, add 90kg of hydroxyethyl methylcellulose and 90kg of cosolvent propylene glycol, stir vigorously and keep warm at 60°C for 1.5h; after lowering the temperature to room temperature, add n-butyl After mixing 10kg of amine and 300g of lemon essence evenly, the finished product will be a transparent oily liquid.

[0037] The cold storage stability was stored at 0°C for 7 days, the thermal stability was stored at 54±2°C for 14 days, and the emulsion stability was measured by diluting 200 times with standard hard water. The results are shown in Table 5.

[0038] Table 5 Sample Stability Test

[0039]

Embodiment 3

[0041] Weigh 80L of palm oil, 590L of thiazole phosphorous crude oil, 20kg of gelatin, 20kg of glycerol, 50kg of sucrose glyceride, 200g of defoamer organic silicone, 3kg of triethylamine, and 100g of lemon flavor, and add them into the premixer for pre-treatment. Mix, and then add colloid mill to mix until uniform, transparent oily liquid is the finished product.

[0042] The cold storage stability of the finished product was stored at 0°C for 7 days, the thermal stability was stored at 54±2°C for 14 days, and the stability of the emulsion was measured by diluting 200 times with standard hard water. The results are shown in Table 6.

[0043] Table 6 Sample Stability Test

[0044]

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Abstract

The invention discloses an environment-friendly lythidathion emulsion and a preparation method thereof. The emulsion is prepared from (wt%) lythidathion 10-80, oil 8-63, surfactant 5-25, assistants 0.5-5, cosolvent 0-5, antifoaming agent 0.05-0.5, stabilizer 0.01-1, and essence 0.01-0.5. The emulsion has the advantages of good stability, lasting drug action, low environmental pollution, simple and reasonable preparation method, and low production cost.

Description

technical field [0001] The invention relates to a formula and a preparation method of an environment-friendly thiazole phosphorus emulsion, belonging to the field of agricultural chemicals. It belongs to the field of pesticide formulation processing. Background technique [0002] Thiazophos is a novel, efficient, broad-spectrum, and safe nematocide and a pesticide for killing underground pests that was registered as a patent (60-104096) by Ishihara Corporation of Japan in June 1985 and put on the market in 1992. It is effective on tobacco, peanuts, It has a very good control effect on nematodes and underground pests of soybeans, citrus and vegetables. At present, it is one of the few nematicides registered on vegetables in my country, especially suitable for the production of pollution-free vegetables. Thiazophos is a new type of high-efficiency and low-toxicity nematicide with contact killing and systemic conduction properties, which can effectively prevent nematodes from...

Claims

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Application Information

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IPC IPC(8): A01N57/32A01N25/04A01P7/00
Inventor 刘自友刘玉法闫新华陈永平张瑞生赵林东宋东升齐慧芹
Owner 山东华阳农药化工集团有限公司
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