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Yb-containing deformation magnesium alloy and dynamic precipitation strengthening-toughening preparation thereof

A deformed magnesium alloy, strengthening and toughening technology, applied in the field of metal material strengthening and processing, can solve the problems of insignificant strengthening effect, difficulty in obtaining precipitation strengthening effect, single strengthening and toughening effect, etc.

Inactive Publication Date: 2009-04-15
SOUTHWEST UNIVERSITY
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  • Description
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Problems solved by technology

The alloying method is mainly to use various rare earth elements and Sn, Cu, Ag, etc. to alloy magnesium or to modify the existing Mg-Al and Mg-Zn series magnesium alloys, although many elements have been found to be effective on magnesium and magnesium. Alloys have a certain strengthening effect, but the strengthening effect is not significant, especially the plastic deformation ability of magnesium alloys cannot be significantly improved or even deteriorated. Therefore, special processing technologies for magnesium alloys have received extensive attention, such as ECAE and other large plastic deformation technologies. , semi-solid extrusion, reciprocating extrusion, hydrostatic extrusion, low temperature extrusion and rapid solidification-powder metallurgy-hot extrusion, etc. These methods can indeed obtain high mechanical properties and superplastic deformation capabilities, but they are all due to It is difficult to put into application due to their special manufacturing, efficiency and cost issues
[0005] The essence of the above problems is that these technical methods have the problem of single strengthening and toughening effects. For example, the alloying method pursues the second phase strengthening effect, but because no satisfactory dispersed precipitate has been found, especially after deformation processing, the fine particles are retained. The recrystallized grains are not suitable for effective subsequent heat treatment, making it difficult to fully exert the alloying effect
However, special processing technologies are mostly purely highlighting the effect of grain refinement, and it is difficult to obtain effective precipitation strengthening effects.
[0006] In fact, some scholars have recognized the significance of composite strengthening of magnesium alloys, proposed various methods to obtain composite strengthening effects through deformation heat treatment, and carried out technical attempts and principle analysis, such as liquid solution aging and solution deformation aging, etc., but none of them got rid of the limitation of the traditional deformation heat treatment technology requiring subsequent low temperature aging treatment
Then, can supersaturated alloys be used to dynamically precipitate effective dispersion strengthening phases during deformation processing, thereby completely retaining the processed state structure and simplifying the preparation technology? Scholars in the United Kingdom and Norway have tested this method in 6-series aluminum alloys in recent years, but it is realized under complex ECAE processing conditions, so it lacks practicability, and there is no similar test report on magnesium alloys so far.

Method used

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  • Yb-containing deformation magnesium alloy and dynamic precipitation strengthening-toughening preparation thereof
  • Yb-containing deformation magnesium alloy and dynamic precipitation strengthening-toughening preparation thereof

Examples

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Embodiment 1

[0032] Embodiment 1: Melt the magnesium ingot with a resistance heating furnace, then add a Mg-Zr alloy containing 1.5% of the total mass of the material added in this step at 770 ° C, and stir for 6 minutes under solvent protection conditions, and then in Add the Mg-Yb alloy containing 2.0% of the total mass of materials added in this step at 750° C., stir for 4 minutes to help melting, and finally add zinc ingots with 6.0% of the total mass of materials added in this step at 730° C., stir for 1 minute to help melt, After standing at 730°C for 15 minutes, remove the slag and pour the ingot. Place the ingot in a heat treatment furnace with resistance heating and temperature control, and pass through SO 2 After the gas is kept at 380°C for 20 hours, the temperature is then raised to 420°C, held for 6 hours, and then it is taken out of the furnace and cooled naturally outside the furnace; the homogenized ingot is removed by a machine tool to remove 2mm of the skin, and then put ...

Embodiment 2

[0033] Embodiment 2: Melt the magnesium ingot with a resistance heating furnace, then add a Mg-Zr alloy containing 2.0% of the total mass of the material added in this step at 780 ° C, and stir for 5 min under solvent protection conditions, and then in Add the Mg-Yb alloy containing 0.5% of the total mass of materials added in this step at 740° C., stir for 3 minutes to flux, and finally add zinc ingots with 5% of the total mass of materials added in this step at 740° C., stir for 2 minutes to flux, After standing at 740°C for 20 minutes, remove the slag and pour the ingot. Place the ingot in a resistance heating temperature-controlled heat treatment furnace, heat it at 340°C for 16 hours, then raise the temperature to 405°C, hold it for 10 hours, and then put it out of the furnace and put it into a water tank to cool; The outer skin is then placed in an extrusion mold with a temperature control of 320°C to keep warm and preheat for 30 minutes. At this temperature, a hydraulic...

Embodiment 3

[0034]Embodiment 3: the magnesium ingot is melted with a resistance heating furnace, then add a Mg-Zr alloy containing 1.8% of the total mass of the material added in this step at 750 ° C, and stir for 10 min under gas protection conditions, and then in the Add the Mg-Yb alloy containing 0.2% of the total mass of materials added in this step at 760° C., stir for 5 minutes to flux, and finally add zinc ingots with 7% of the total mass of materials added in this step at 750° C., stir for 3 minutes to flux, After standing at 750°C for 10 minutes, remove the slag and pour the ingot. Place the ingot in a resistance heating temperature-controlled heat treatment furnace, heat it at 330°C for 24 hours, then raise the temperature to 400°C, hold it for 4 hours, and then put it out of the furnace and put it into a water tank to cool; The outer skin is then placed in an extrusion die with temperature control at 380°C for heat preservation and preheating for 15 minutes. At this temperature...

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Abstract

The invention discloses deformed magnesium alloy containing Yb and a dynamic separation strengthening and toughening preparation method thereof. A strengthening phase is effectively dispersed and separated out during a deformation process by selecting a special alloy element and utilizing the universal homogenization treatment and thermal squeezing technologies during the production of the deformed magnesium alloy, thereby obtaining the compound strengthening and toughening effects of deformation strengthening, refined crystalline strengthening and precipitation hardening of the deformed magnesium alloy; the obtained high intensity deformed magnesium alloy simultaneously has the characteristics of refined crystalline strengthening, separation strengthening, intercrystalline strengthening and deformed substructure strengthening, thereby obtaining very high mechanical property; the tensile strength is larger than 380MPa; the yield strength is larger than 320MPa; and the percentage of elongation is larger than 5 percent.

Description

technical field [0001] The invention relates to the technical field of metal material strengthening and processing, in particular to a production method of a high-strength deformed magnesium alloy, in particular to a Yb-containing deformed magnesium alloy and a preparation method thereof for dynamic precipitation strengthening and toughening. Background technique [0002] Magnesium alloy is currently a lightweight metal material that is highly valued at home and abroad. It has broad application prospects in the production of automobiles, aerospace, and electromechanical and electronic products. It is an ideal lightweight substitute for steel and aluminum alloy materials. Known as "the green material of the 21st century", it is of great significance to solve or alleviate the energy crisis and environmental crisis that the world is facing now. [0003] However, due to the inherent atomic structure and crystal arrangement characteristics of magnesium alloys, their low strength ...

Claims

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Application Information

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IPC IPC(8): C22C23/04C22C1/02C22F1/06
Inventor 于文斌
Owner SOUTHWEST UNIVERSITY
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