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Emulsifiable paste stamp-pad ink for reticular lamina printing decoration of ceramic brick for wall and ground

A technology of wall and floor tiles and stencils, which is applied in the field of cream printing oil, which can solve the problems of weak body bonding, poor brightness, lubricity, and poor mesh penetration, and achieve smooth and smooth surfaces, clear and bright patterns, and low burning ash Effect

Inactive Publication Date: 2009-04-08
淄博宜龙实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the prior art, the quality of cream printing oil products for screen printing of ceramic wall and floor tiles is not satisfactory, or its specific gravity and density are insufficient, and it is easy to precipitate and layer when placed, resulting in color difference; or poor lubricity and screen penetration; Or the bonding force of the glaze slurry to the green body is weak, and the surface cleanliness of the ceramic wall and floor tiles after firing is poor, with defects such as unevenness, pinholes or patterns that are not clear enough, and poor brightness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Weight ratio:

[0020] 30kg of ethylene glycol, 20kg of glycerol, 45kg of sorbitol, 1kg of carboxymethyl cellulose for cellulose, 8kg of acrylic acid for high molecular polymer, and 0.2kg of sodium persulfate for the activator;

[0021] Ethylene glycol (ethylene glycol), a product of Beijing Yanshan Petrochemical Company, specifications: appearance is colorless transparent viscous liquid, relative density (d 20 / 4) 1.1130 ~ 1.1140, boiling point 197.6 ℃, chloride (as Cl - Total)%≤0.0001, ash%≤0.003.

[0022] Glycerol (glycerol) Qilu Petrochemical product, specifications: appearance is colorless viscous liquid, content ≥ 95%, melting point 17.8 ℃, boiling point 290 ℃, relative density 1.2636 (20 / 20 ℃), flash point 160 ℃, refractive index 1.4746 .

[0023] Sorbitol (D-Sorbitol), product of Shanghai Daily Chemical Factory, specifications: appearance white crystalline powder, content (dry basis) ≥ 91%, total glucose alcohol (dry basis) ≥ 97%, moisture ≤ 1%, Arsenic (calcu...

Embodiment 2

[0031] 25kg of ethylene glycol, 35kg of glycerol, 30kg of sorbitol, 7kg of hydroxyethyl cellulose, 2kg of acrylamide for high molecular polymer, and 1kg of potassium persulfate for activator.

[0032] Hydroxyethyl cellulose (HEC) white or light yellow powder, degree of substitution (D.S) 1.2-2.0; moisture (%) ≤ 7; relative molecular weight ≥ 305; Ph value 6-7; water insoluble ≤ 2%; viscosity ( mpa.s) 2% aqueous solution ≥ 8000, 20 ℃ aqueous solution 5-60000;

[0033] Acrylamide, specifications: appearance white powder, content ≥ 95%, moisture ≤ 0.1%, manufacturer Beijing Chemical Plant.

[0034] Use of activator: Potassium persulfate, appearance white crystalline powder, content ≥ 98%, nitride content (calculated as N) ≤ 0.35%, iron salt (calculated as Fe) ≤ 0.04%, manufacturer Nanjing Zhongchuang Chemical Co., Ltd. .

[0035] Weigh each component according to the proportion, first add ethylene glycol, glycerol, sorbitol and acrylamide, stir evenly, at 60-65°C, evenly add th...

Embodiment 3

[0038] 27kg of ethylene glycol, 25kg of glycerol, 43kg of sorbitol, 3-4kg of hydroxypropyl cellulose, 4kg of polypropylene glycol for polymer, 0.3kg of ammonium persulfate for activator;

[0039] Specifications of hydroxypropyl cellulose: white or yellowish powder, hydroxypropoxy group ≤ 80.5%; moisture (%) ≤ 10; relative molecular weight ≥ 305; Ph value 5-8; arsenic ≤ 3mg / kg; lead ≤ 10mg / kg kg; manufacturer Xi'an Huian Chemical Plant.

[0040] Ammonium persulfate is used as the activator, the appearance is white crystalline powder, iron salt (calculated as Fe)≤0.04%, acidity (calculated as sulfuric acid)≤0.10%, the manufacturer is Nanjing Zhongchuang Chemical Co., Ltd.

[0041] Polypropylene glycol: white powder in appearance, relative molecular weight ≥ 5000; produced by Jiangsu Runan Petrochemical Plant.

[0042] Weigh each component according to the proportion, first add ethylene glycol, glycerol, sorbitol and high molecular polymer polypropylene glycol, stir evenly, at 6...

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Abstract

The invention relates to cream stamp-pad ink for printing patterns on mesh plates of ceramic tiles, which is a mixture consisting of the following compositions by weight: 20 to 35 percent of ethylene glycol, 20 to 35 percent of glycerol, 30 to 45 percent of sorbitol, 1 to 7 percent of cellulose, 2 to 8 percent of a macromolecule polymer, and 0.2 to 1.0 percent of an exciting agent. The appearance of the cream stamp-pad ink is of milk white cream shape without off flavor; the viscosity is between 4,800 and 5,200 MPa.S; the density at 20 DEG C is between 1.040 and 1.050; the pH value is between 6 and 8; the water-soluble residue with 360 meshes is less than or equal to 0.2 percent; and the freezing point is 10 DEG C below zero. The burnt ash content of products is low without residues; the stability and the suspending power are good without layering; the proportion and the viscosity are adjustable; pattern-printing glaze slurry prepared from the cream stamp-pad ink can be used normally on-line after storage without the appearances of color differences and pinholes; and the cream stamp-pad ink is applicable to the pattern-printing requirements for various high-grade, middle grade and low grade ceramic tiles produced by different ceramic building factories. The pattern-printing glaze slurry prepared from the cream has certain fluidity, the performances of moisture, lubrication, mesh brightening and the like, and increases the adhesive force of the pattern-printing glaze slurry on blanks; besides, the surface of a sintered tile finished product is smooth and has no defects of unevenness, pinholes and the like, and the patterns are clear and bright.

Description

technical field [0001] The invention belongs to the category of cream printing oil in the ceramic industry, in particular to a cream printing oil for screen printing of ceramic wall and floor tiles. This cream printing ink has strong applicability and can fully meet the different needs of printing on interior wall tiles and floor tiles of various specifications; it can be applied to high-gloss tiles, calendered tiles, crystal tiles, antique tiles, interior wall tiles, etc. Background technique [0002] In the prior art, the quality of cream printing oil products for screen printing of ceramic wall and floor tiles is not satisfactory, or its specific gravity and density are insufficient, and it is easy to precipitate and layer when placed, resulting in color difference; or poor lubricity and screen penetration; Or the bonding force of the glaze slurry to the green body is weak, and the surface of the ceramic wall and floor tiles after firing is poor in cleanliness, with defec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/83
Inventor 郑良柱王宜亮
Owner 淄博宜龙实业有限公司
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