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A kind of polyester fdy oil agent and preparation method thereof

An oil and polyester technology, applied in the field of polyester FDY oil and its preparation, can solve the problems of prone to corruption, incomplete antistatic properties of oil, uneven oiling, etc., and achieves good storage and use stability, good resistance. Static effect, long-term use effect

Active Publication Date: 2011-11-30
HANGZHOU TRANSFAR CHEM LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the polyester FDY oils in my country rely on imports, but the price is relatively high, causing a certain cost burden on the chemical fiber industry with poor profitability.
Although domestic FDY oils have been successfully developed, compared with imported oils, they have the disadvantages of unstable quality and poor post-processing performance
The current market share of domestic oil agents is less than 20%, and there are some obvious deficiencies in the quality of oil agents
Firstly, the heat resistance of the oil agent is poor. When the medium-coarse denier yarn above 150 denier is processed and the temperature of the second hot roller exceeds 130°C, the oil agent volatilizes seriously, and the smoke in the workshop is large, which seriously affects the working environment and health of workers. Another manifestation of poor heat resistance is that the coking phenomenon of the oil agent is relatively serious. If the continuous use time does not exceed one month, coking will appear on the hot roller, resulting in wool and broken ends
The second disadvantage is that the antistatic property of the oil is not comprehensive. Since domestic oils currently use phosphoric acid esters as antistatic agents, this can only ensure that the oil has good antistatic properties at higher humidity. In the case of antistatic, the antistatic effect is greatly reduced, which leads to the phenomenon of winding and broken ends due to poor antistatic performance in dry seasons or in northern regions.
The third shortcoming is poor stability of the oil agent, which is prone to corruption, which has a great impact on chemical fiber production. The light ones block the pipeline, resulting in uneven oiling, causing wool and broken ends, and severe cases stop production for repairs.
The fourth shortcoming is that the emulsifiers in the FDY oils on the market now contain APEO (alkylphenol polyoxyethylene ether) components, and APEO is an environmental hormone substance, which belongs to the example of Oeko Tex 100 restricted range, which not only It will cause difficulties for the export of products of downstream printing and dyeing enterprises, and will cause environmental pollution and ecological hazards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Each component and weight percentage of oil agent are as follows:

[0019] High temperature resistant smoothing agent 65%, including special polyether 30%, triol ester 25%, refined mineral oil 10%;

[0020] Environmentally friendly emulsifier 20%, of which isomerized alcohol polyoxyethylene ether 10%, polyoxyethylene laurate 6%, polyoxyethylene lauryl alcohol 4%;

[0021] 7% sizing agent, including 5% high molecular weight polyether and 2% oleic acid polyethylene glycol diester;

[0022] 5% composite antistatic agent, including 3% potassium salt of high-carbon alcohol polyoxyethylene ether phosphate, and 2% of β-alkyl sulfonate;

[0023] 3% additives, including 2% modified silicone oil and 1% preservative.

Embodiment 2

[0025] Each component and weight percentage of oil agent are as follows:

[0026] High temperature resistant smoothing agent 60%, including special polyether 35%, triol ester 25%;

[0027] Environmentally friendly emulsifier 20%, including isomeric alcohol polyoxyethylene ether 10%, random polyether 6%, fatty alcohol polyoxyethylene ether 4%;

[0028] 10% sizing agent, including 5% high molecular weight polyether and 5% polyoxyethylene laurate;

[0029] Composite antistatic agent 7%, of which isomerized alcohol polyoxyethylene ether phosphate potassium salt 5%, β-alkyl sulfonate 2%;

[0030] 3% additives, including 1% modified silicone oil, 1% higher alcohol and 1% preservative.

Embodiment 3

[0032] Each component and weight percentage of oil agent are as follows:

[0033] High temperature resistant smoothing agent 58%, including special polyether 25%, triol ester 20%, tetraol ester 13%;

[0034] Environmentally friendly emulsifier 25%, including isomeric alcohol polyoxyethylene ether 10%, random polyether 9%, fatty alcohol polyoxyethylene ether 6%;

[0035] 7% sizing agent, including 5% high molecular weight polyether and 2% polyoxyethylene laurate;

[0036] Composite antistatic agent 8%, including high carbon alcohol polyoxyethylene ether phosphate potassium salt 5%, β-alkyl sulfonate 3%;

[0037] 2% additives, including 1% modified silicone oil and 1% preservative.

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PUM

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Abstract

The invention discloses a polyester FDY oil agent and a preparation method thereof. The existing oil has poor heat resistance, serious volatilization, and heavy smoke in the workshop, which seriously affects the working environment and health of workers; the coking phenomenon of the oil is relatively serious, resulting in wool and broken ends. The components and weight percentages of the present invention are: high temperature resistant smoothing agent 55-65%, environmental protection emulsifier 15-25%, sizing agent 3-10%, composite antistatic agent 5-8%, and the rest are additives, The high temperature resistant smoothing agent contains special polyether. The invention has good heat resistance, is suitable for high-speed spinning process of various specifications including coarse denier polyester fibers, does not emit smoke, and does not coke on hot rollers.

Description

technical field [0001] The invention relates to an auxiliary agent used in polyester filament processing, in particular to a polyester FDY oil agent and a preparation method thereof. Background technique [0002] Spinning oil must be used in polyester production. Polyester FDY oil is a necessary auxiliary in the one-step spinning process of polyester spinning. processing requirements. At present, most of the polyester FDY oils in my country rely on imports, but the price is relatively high, causing a certain cost burden on the chemical fiber industry with poor profitability. Although the domestic FDY oil has been successfully developed, compared with the imported oil, it has the disadvantages of unstable quality and poor post-processing performance. The current market share of domestic oil agents is less than 20%, and there are some obvious deficiencies in the quality of oil agents. Firstly, the heat resistance of the oil agent is poor. When the medium-coarse denier yarn ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M15/53D06M13/165D06M13/224D06M13/256D06M13/295D06M13/352D06M101/32
Inventor 朱春华王胜鹏吴建华傅幼林丁智敏徐峰
Owner HANGZHOU TRANSFAR CHEM LTD
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