Molecular engram material selectively removing TSNA in cigarette flue gas, preparation and application method thereof
A molecularly imprinted, cigarette smoke technology, applied in applications, tobacco, tobacco processing, etc.
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Embodiment 1
[0034] 1. Preparation of Additives
[0035] (1) Activation and silanization of silica gel: reflux with 10% hydrochloric acid by volume fraction for 12 hours, wash with distilled water until ph=7.0, and then vacuum dry for later use; put 5 g of activated silica gel and 50 ml of toluene into a round-bottomed flask, add 2 ml3 - Aminopropyltriethoxysilane, 1ml of triethylamine, heated to reflux for 24 hours, filtered the reacted silica gel, washed with methanol and chloroform, and dried in vacuum.
[0036] (2) Preparation of Silica Surface Imprinted Polymers (MIPs) and Non-Molecularly Imprinted Polymers (NMIPs)
[0037] Take 1mmol of 3-pyridinemethanol (template molecule) and dissolve it in 10mL of methanol and 30mL of chloroform, add 4mmol of functional monomer 4-vinylpyridine, 4g of silanized silica gel, place it in a constant temperature oscillator and vibrate for 3h, so that the template molecule and Mix the functional monomer and silica gel thoroughly, then add 15mmol of cro...
Embodiment 2
[0042] 1. Preparation of Additives
[0043] (1) Activation and silanization of silica gel: reflux with 10% hydrochloric acid by volume fraction for 12 hours, wash with distilled water until ph=7.0, and then vacuum dry for later use; put 10 g of activated silica gel and 100 ml of toluene into a round-bottomed flask, add 3 g3 - Aminopropyltriethoxysilane, 1ml of pyridine, heated to reflux for 24 hours, filtered the reacted silica gel, washed with methanol and chloroform, and dried in vacuum.
[0044] (2) Preparation of Silica Surface Imprinted Polymers (MIPs) and Non-Molecularly Imprinted Polymers (NMIPs)
[0045] Take 0.25mmol of nicotinamide (template molecule) and dissolve it in 60m L of chloroform, add 1.25mmol of functional monomer methacrylic acid (MAA), 4g of silanized silica gel, put it into a constant temperature oscillator and shake for 3h, so that the template molecule and the functional monomer And silica gel is fully mixed, then add 5mmol cross-linking agent ethyle...
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