High-expansion fireproof sealant and preparation thereof
A fire-proof sealant and high-expansion technology, applied in chemical instruments and methods, adhesives, other chemical processes, etc., can solve the problems of easy falling off of the intumescent carbon layer, failure of fire protection, high production cost, etc., and achieve small volume shrinkage and strong adhesion , Good effect of flame retardancy
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preparation example Construction
[0041] The preparation method of the present invention is as follows:
[0042] 1. Add acrylate emulsion (or styrene-acrylic elastic emulsion), polybutene (or polyisobutylene), ethylene glycol, tricresyl phosphate and emulsifier into the reactor according to the mass parts of the formula, and stir Slowly heat to 50℃~80℃, keep for 60min~120min, and cool to obtain the base material;
[0043] 2. Transfer the base material to a colloidal mixer, and gradually add the formula mass parts of ammonium polyphosphate, flame-retardant aluminum hydroxide, flame-retardant zinc borate, calcium carbonate, expanded graphite, iron oxide and glass under stirring conditions Fiber, continue to stir for 1 to 2 hours until the colloid is uniform.
Embodiment 1
[0045] 1. Take 100 parts of acrylate elastic emulsion, 12 parts of tricresyl phosphate, 2 parts of ethylene glycol, 15 parts of polybutene, and 1 part of emulsifier (sodium lauryl sulfate, OP-10) and add them to the reactor In the medium, slowly heat to 50°C under stirring, keep for 60 minutes, and cool to obtain the base material;
[0046] 2. Transfer the base material to a colloidal mixer, and gradually add 30 parts of ammonium polyphosphate, 40 parts of calcium carbonate, 30 parts of flame-retardant aluminum hydroxide, 2 parts of zinc borate, 4 parts of iron oxide red, and expanded graphite under stirring conditions. 16 parts and 4 parts of glass fiber, continue to stir for 1 hour until the colloid is uniform.
Embodiment 2
[0048] 1. Take 100 parts of acrylate elastic emulsion, 8 parts of tricresyl phosphate, 5 parts of ethylene glycol, 5 parts of polybutene, and 3 parts of emulsifier (sodium lauryl sulfate), add them to the reaction kettle, under stirring Slowly heat to 60℃, keep for 80min, and cool to obtain the base material;
[0049] 2. Transfer the base material to a colloidal mixer, and gradually add 40 parts of ammonium polyphosphate, 50 parts of calcium carbonate, 20 parts of flame-retardant aluminum hydroxide, 4 parts of zinc borate, 4 parts of iron oxide red, and expanded graphite under stirring conditions. 12 parts and 6 parts of glass fiber, continue to stir for 1.5 hours until the colloid is uniform.
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