Method for producing liquefied petroleum gas
A technology of liquefied petroleum gas and manufacturing method, which is applied in the petroleum industry, producing hydrocarbons from carbon oxides, gas fuel, etc.
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Embodiment 1
[0208] use figure 1 The LPG manufacturing apparatus shown produces LPG. As a catalyst for olefin-containing gas synthesis, a dry standard 73.5% by weight of H-ZSM-5 having a Si / Al ratio (atomic ratio) of 25.0 and a dry standard 26.5% by weight of alumina viscosity were used. A catalyst prepared by mixing, wet-forming, drying, and calcining a mixture (Catalyzed Chemical Industry Co., Ltd., Kataroide AP). As the catalyst for the hydrogenation of the olefin-containing gas, a 2.0% by weight Pt / C (manufactured by N.E. CHEMCAT (Epi-Tech Co., Ltd.)) was used. Both the catalyst for olefin-containing gas synthesis and the catalyst for olefin-containing gas hydrogenation were extruded molded articles having the same shape as 1 / 32-inch cylinders.
[0209] The raw material gas with the composition of methanol 50% (mol) and hydrogen 50% (mol) was passed through the first catalyst layer in the first stage (50% of the reactor volume) composed of the above-mentioned catalyst for synthesizin...
Embodiment 2
[0212] use figure 2 The LPG manufacturing apparatus shown produces LPG. As the catalyst for synthesizing olefin-containing gas, the same catalyst for synthesizing olefin-containing gas as in Example 1, and the same catalyst for synthesizing olefin-containing gas as in Example 1 were used to support 0.2% by weight of Pt (hereinafter referred to as Catalysts for the isomerization and hydrogenation of olefin-containing gases). In addition, the same catalyst for hydrogenation of olefin-containing gas as in Example 1 was used as the catalyst for hydrogenation of olefin-containing gas. Further, the catalyst for isomerization and hydrogenation of olefin-containing gas is a catalyst for olefin-containing gas synthesis having the function of a catalyst for hydrogenation of olefin-containing gas.
[0213] The raw material gas having the same composition as in Example 1, the part that passes through the reactor inlet by volume 2 / 3 is the above-mentioned catalyst for olefin-containing ...
Embodiment 3
[0217] use image 3 The LPG manufacturing apparatus shown produces LPG. As the catalyst for synthesizing an olefin-containing gas, the same catalyst for synthesizing an olefin-containing gas as in Example 1 was used. As the catalyst for hydrogenation of olefin-containing gas, the same catalyst for hydrogenation of olefin-containing gas as in Example 1, and the same catalyst for isomerization and hydrogenation of olefin-containing gas as in Example 2 were used.
[0218] A raw material gas having a composition of 50 mol% of methanol and 50 mol% of steam was passed through the first catalyst layer composed of the above-mentioned catalyst for synthesizing an olefin-containing gas. The reaction conditions are: the reaction temperature: the control temperature of the reactor inlet is 330°C, the maximum temperature of the catalyst layer is 365°C; the reaction pressure: the partial pressure of methanol is 70kPa, and the space-time velocity of methanol liquid is 40H relative to the ca...
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