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Etching solution composition for metal foil using silver as main composition

A technology of metal thin film and etching solution, which is applied in the direction of surface etching composition, optics, instruments, etc., can solve the problems of heavy environmental load, large amount of water-soluble organic components, etc., and achieve the effect of high-precision etching processing

Inactive Publication Date: 2007-11-07
KANTO CHEM CO INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] Documentation is arranged, as the etchant of silver alloy, because the mixed acid etching rate of phosphoric acid, nitric acid, acetic acid, water is too high, so add 20~40% by weight ethylene glycol or glycerol (patent document 8) in this mixed acid, but , the disadvantage is that the amount of water-soluble organic components is large and the load on the environment is large

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~11

[0059] Prepare a glass substrate with a resist pattern formed on an Ag alloy (Ag-Pd-Cu) film with a film thickness of 1500 Ȧ, and perform immersion etching at a liquid temperature of 30° C. in the etching solution in Table 1 (Examples 1 to 11). 1.2 times the time. Then, the washed and dried substrate was observed with an optical microscope, and the residue after etching and the amount of undercut were evaluated.

[0060] Here, 85% by weight of phosphoric acid, 99% by weight of acetic acid, 70% by weight of nitric acid, and water were used to prepare the etching solution, and the composition was determined from the weight and concentration of the acid.

[0061] The results are shown in Table 1.

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PUM

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Abstract

The liquid composition for etching a metallic thin film consisting essentially of silver is obtained by blending, by weight, 40 to 50% phosphoric acid, 1.5 to 3.5% nitric acid, 25 to 40% acetic acid, and water.

Description

technical field [0001] The present invention relates to an etchant composition for use in the production of metal thin films containing silver as a main component for flat panel displays and the like. Background technique [0002] In the past, aluminum thin films have been used as reflective plates and reflective electrode materials for reflective and transflective liquid crystal display devices. In recent years, metal thin films mainly composed of silver, which have higher reflectance than aluminum and lower resistance characteristics, have attracted attention. (Refer to Patent Documents 1 and 2). [0003] Although silver has disadvantages such as poor microfabrication and easy reaction with chlorides, sulfides, etc., due to its high conductivity and reflectivity, it has been used to form a transparent conductive film on the silver film and achieve low resistance of wiring. currently using. [0004] As an etchant for a silver thin film, (1) dilute nitric acid and (2) ammo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F1/30G02F1/1335C09K13/06G02F1/1343
CPCC23F1/30
Inventor 大城研二清水寿和景山宪二
Owner KANTO CHEM CO INC
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