Composition for polyurethane foaming, polyurethane foam and use thereof
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preparation examples 1-5
[0047]Polyether polyol 1 was a polyether polyol that was prepared by the polymerization of ethylene oxide, propylene oxide and sorbitol, sucrose, trimethylolpropane, wherein the sorbitol, sucrose, trimethylolpropane were used as initiators. The hydroxyl value was 450 mgKOH / g, and the average functionality was 4.5. The specific preparation method was as follows: 109 g sorbitol, 205 g sucrose, 268 g trimethylolpropane and 35 g catalyst were fed into a 2.5 L jacketed reaction vessel, and the temperature was increased gradually to 70° C. Stirring was started, the reaction vessel was evacuated, and excess amount of water of the raw material was removed, then the content inside the reaction vessel was replaced by nitrogen. 1000 g propylene oxide and 200 g ethylene oxide (the molar ratio between them is about 8:2) were slowly fed into the reaction vessel within 2 hours, the pressure was kept below 0.25 MPa, and the temperature was slowly increased to 100° C. until the completion of feeding...
examples 1-5
[0055]The composition of the formula shown in table 1 and PM200 of Wanhua Chemical Company were foamed using a high pressure sprayer Graco A20, the volume ratio of the two components was 1:1 (the weight ratio was 1:1.1). The polyurethane foam prepared was measured in accordance with common industry standard, and its performance is shown in table 2.
[0056]In the following table, the amounts of components are parts by weight, EO is ethylene oxide, PO is propylene oxide.
TABLE 1Formula of the compositionEx-Ex-Ex-Ex-Ex-ampleampleampleampleampleComponent12345Polyether polyol 1: the 12.02217.522polyether polyol prepared by the polymerization of EO, PO, sorbitol, sucrose and trimethylolpropane, wherein the sorbitol, sucrose and trimethylol-propane were usedas initiators, hydroxyl value450 mgKOH / g, averagefunctionality 4.5, the ratiobetween ethylene oxide and propylene oxide was about 8:2 (molar ratio, the same as below)Polyether polyol 2: the poly-15.0ether polyol prepared by thepolymerizati...
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