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Integration of ALD tantalum nitride and alpha-phase tantalum for copper metallization application

a technology of ald tantalum and alpha-phase tantalum, which is applied in the direction of coatings, special surfaces, chemical vapor deposition coatings, etc., can solve the problems of increasing the overall resistance, and reducing the reliability of the overall circui

Inactive Publication Date: 2003-05-01
APPLIED MATERIALS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, copper diffuses more readily into surrounding materials and can alter the electronic device characteristics of the adjacent layers and, for example, form a conductive path between layers, thereby reducing the reliability of the overall circuit and may even result in device failure.
Therefore, the additional amount of the barrier layer on the bottom of the feature not only increases the overall resistance of the feature, but also forms an obstruction between higher and lower metal interconnects of a multi-layered interconnect structure.

Method used

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  • Integration of ALD tantalum nitride and alpha-phase tantalum for copper metallization application
  • Integration of ALD tantalum nitride and alpha-phase tantalum for copper metallization application
  • Integration of ALD tantalum nitride and alpha-phase tantalum for copper metallization application

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Embodiment Construction

[0072] A TaN layer was deposited over a lower level copper layer using cyclical deposition to a thickness of about 20 .ANG.. A copper alloy seed layer was deposited over the TaN layer by physical vapor deposition to a thickness of about 100 .ANG.. The copper alloy seed layer contained aluminum in a concentration of about 2.0 atomic percent, and was deposited by PVD using a copper-aluminum target consisting of aluminum in a concentration of about 2.0 atomic percent. A bulk copper layer was then deposited using ECP to fill the feature. The substrate was then annealed at a temperature of about 380.degree. C. for a time period of about 15 minutes in a nitrogen (N2) and hydrogen (H2) ambient.

[0073] The overall feature resistance was significantly reduced and the upper level copper layer surprisingly exhibited a grain growth similar to that of the lower level copper layer. The barrier performance of the TaN layer exhibited longer TTF compared with 50 .ANG. PVD Ta. Further, the TaN layer s...

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Abstract

A method for forming a metal interconnect on a substrate is provided. The method includes depositing a refractory metal-containing barrier layer having a thickness less than about 20 angstroms on at least a portion of a metal layer by alternately introducing one or more pulses of a metal-containing compound and one or more pulses of a nitrogen-containing compound. The method also includes depositing a seed layer on at least a portion of the barrier layer, and depositing a second metal layer on at least a portion of the seed layer. The barrier layer provides adequate barrier properties and allows the grain growth of the metal layer to continue across the barrier layer into the second metal layer thereby enhancing the electrical performance of the interconnect.

Description

[0001] This application claims benefit of U.S. Provisional Patent Application Serial No. 60 / 346,086, filed on Oct. 26, 2001, and entitled "Method and Apparatus for ALD Deposition", which is incorporated by reference herein. This application also claims benefit of U.S. patent application Ser. No. 09 / 965,370, filed on Sep. 26, 2001, and entitled "Integration of Barrier Layer and Seed Layer", which is incorporated by reference herein. This application also claims benefit of U.S. patent application Ser. No. 09 / 965,373, filed on Sep. 26, 2001, and entitled "Integration of Barrier Layer and Seed Layer", which is incorporated by reference herein. This application also claims benefit of U.S. patent application Ser. No. 09 / 965,369, filed on Sep. 26, 2001, and entitled "Integration of Barrier Layer and Seed Layer", which is incorporated by reference herein.[0002] 1. Field of the Invention[0003] Embodiments of the present invention relate to a method for manufacturing integrated circuit device...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C23C16/34C23C16/44C23C16/455H01L21/285H01L21/768
CPCC23C16/34C23C16/4411C23C16/4412C23C16/45504C23C16/45508C23C16/45512H01L21/76871C23C16/45544C23C16/45563C23C16/45582H01L21/28562H01L21/76843H01L21/76846C23C16/45525H01L21/768
Inventor CHUNG, HUACHEN, LING
Owner APPLIED MATERIALS INC
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