Toner for electrostatic charge image development
A technology for electrostatic charge images and toners, which can be used in developers, electrographics, optics, etc., to solve the problem that the balance between low-temperature fixability and heat-offset resistance may not be good, and achieve good durability and preservation. , the effect of good heat resistance
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Embodiment 1
[0126] 100 parts of a monomer composition consisting of 80.5 parts of styrene and 19.5 parts of n-butyl acrylate, 0.5 parts of polyisoprene-based diacrylate (average molecular weight : 3000, produced by Osaka Organic Chemical Industry Co., Ltd., trade name "BAC-45"), 6 parts of carbon black (manufactured by Mitsubishi Chemical Corporation, trade name "#25"), 1 part of anti-negative resin (product with 2% sulfonic acid functional group) , Fujikura Chemical Co., Ltd., trade name "FCA S748"), 2 parts of tert-dodecyl mercaptan and 0.5 part of polymethacrylate macromonomer (manufactured by Toa Gosei Chemicals, trade name "AA6", Tg =94°C), uniformly disperse by MEDIA type disperser. Next, 10 parts of dipentaerythritol hexamyristate (acid value: 0.5 mgKOH / g, hydroxyl value: 1.2 mgKOH / g) were added, mixed and dissolved to obtain a polymerizable monomer composition (mixed solution). In addition, the preparation of the polymerizable monomer composition was all performed at room tempera...
Embodiment 2
[0133] Except for using a composition consisting of 90 parts of styrene and 10 parts of n-butyl acrylate as the monomer composition, the amount of polyisoprene-based diacrylate was set to 1.5 parts, the amount of t-dodecyl mercaptan was Except that the amount was set to 1 part, it carried out similarly to Example 1, and obtained the toner for electrostatic charge image development. Evaluation of the properties, image, etc. of the obtained toner for developing electrostatic images was carried out in the same manner as in Example 1. The results are shown in Table 1.
Embodiment 3
[0135] In addition to using a composition consisting of 90 parts of styrene and 10 parts of n-butyl acrylate as the monomer composition, 2 parts of bisphenol A propylene oxide adduct diacrylate (manufactured by Kyoei Chemical Industry Co., Ltd., trade name "Laitoacrilato BP-4PA") was used in the same manner as in Example 1, except that the polyisoprene-based diacrylate was replaced with 0.6 part of t-dodecyl mercaptan, to obtain an electrostatic charge image developing device. toner. Evaluation of the properties, image, etc. of the obtained toner for developing electrostatic images was carried out in the same manner as in Example 1. The results are shown in Table 1.
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