Method for producing paper and paper board
A technology for cardboard and paper materials, applied in papermaking, textiles and papermaking, pulp raw material addition process, etc., can solve problems such as the reduction of the effect of anionic groups
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[0025] Hereinafter, preferred embodiments of the method for producing paper and board of the present invention will be described in detail.
[0026] First, the branched / crosslinked amphoteric polymer, the anionic organic high molecular particle, the water-soluble anionic high molecular polymer and the water-soluble cationic high molecular polymer used in the present invention will be described.
[0027] Although there is no particular limitation on the monomer components of the branched / crosslinked amphoteric polymer used in the present invention, specific examples of preferred branched / crosslinked amphoteric polymers include amphoteric polymers having 0.5-90 mol % of cationic monomer units represented by the following general formula (1), 0.2-90 mole % of anionic monomer units selected from (meth)acrylic acid, itaconic acid, acrylamide-2-methylpropanesulfonate One or more anionic monomer units of acids and salts thereof, and 1-99.3 mol% of acrylamide units, and have the follo...
Embodiment 1-6、 comparative Embodiment 1、2
[0074] [Example 1-6, comparative example 1, 2: the embodiment of acid high-quality paper]
[0075] A pulp sample of 100% LBKP (hardwood bleached kraft pulp) and 450 cc freeness was adjusted such that the consistency of the mixed pulp sample became 0.8% by weight, based on the dry weight of the paper material.
[0076] The paper material (A) thus prepared was put into a yield tester "DFS", and 2.0% by weight (relative to dry pulp) of aluminum sulfate, 1.0% by weight (relative to dry pulp) of cationized starch ( "Cato-3212", available from NSC Corporation), 10% by weight (relative to dry pulp) of talc ("Talc 86-C", available from Nippon Talk Co. Ltd.) and the first yield-enhancing agent, A second yield-enhancing reagent was then added, thereby preparing filtrate "B". As for the setting conditions of DFS, the method recommended by μ-tec Co., Ltd. was used. Each yield enhancing reagent was added at 20 second intervals. Shear is applied by the tester by stirring under standard c...
Embodiment 7-12、 comparative Embodiment 3、4
[0086] Examples 7-12, Comparative Examples 3 and 4: Examples of neutralizing high-quality paper
[0087] A pulp sample of 100% LBKP (hardwood bleached kraft pulp) and 450 cc freeness was adjusted such that the consistency of the mixed pulp sample became 0.8% by weight, based on the dry weight of the paper material.
[0088] The paper material (A) thus prepared was put into a yield tester "DFS", and 2.0% by weight (relative to dry pulp) of aluminum sulfate, 1.0% by weight (relative to dry pulp) of cationized starch ( "Cato-3212", available from NSC Corporation), 10% by weight (relative to dry pulp) of calcium carbonate ("TP-12L", available from Okutama Kogyo Co. Ltd.) and the first yield-enhancing agent, Filtrate "B" was then prepared by adding a second yield enhancing reagent after 20 seconds. As for the setting conditions of DFS, the method recommended by μ-tec Co., Ltd. was used. Shear is applied by the tester by stirring under standard conditions. The evaluation was perf...
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