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Scale and corrosion inhibiting method for industrial boiler

An industrial boiler and anti-scale technology, which is applied in chemical instruments and methods, descaling and water softening, water/sludge/sewage treatment, etc., can solve the problem that there are no green anti-scaling and preservative-friendly anti-corrosion and anti-scaling methods, etc. problems, to achieve the effect of high-efficiency anti-corrosion and scale inhibition, and strong adaptability

Inactive Publication Date: 2005-04-27
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

U.S. Patent US 5,866,011 (1999, February, 2) provides a method of antiscaling by using PESA to prevent scaling of salt concentration and evaporation systems. In the above patents, PESA works at normal pressure, low temperature, low alkalinity, low Under the condition of pH value and water quality with sufficient oxygen supply, while the boiler system is under the condition of high pressure, high temperature, high alkalinity, high pH value and anoxic or anaerobic water quality conditions, general polymers will fail under these conditions, such as PESA Whether green polymers can effectively prevent fouling of boiler heat transfer surfaces under these conditions, and whether there is a synergistic effect between it and oxygen scavengers, has not been reported in the literature so far
Therefore, there is currently no environmentally friendly anti-corrosion and anti-scaling method suitable for the combination of green anti-scaling and preservatives for boiler systems.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0011] Example 1: Sodium sulfite and IV C Mix evenly according to the mass ratio of 100:3 to make IV C Stabilized sodium sulfite. Add relative PESA 5mg / L with a molecular mass of 400-1000, then add IV C Stabilize sodium sulfite so that the sodium sulfite content in the pot water is kept at about 5mg / L. After 4 months of operation, no scale and corrosion were found on the heat transfer surface of the boiler, the original scale layer was obviously thinner, and part of the surface was cleaned. The scale inhibition rate of the standard 20g steel test piece was 100%, and the corrosion inhibition rate was 99.56% %.

example 2

[0012] Example 2: Sodium sulfite and IV C Mix evenly according to the mass ratio of 100:1 to make IV C Stabilized sodium sulfite. Add relative PESA 5mg / L with a molecular mass of 400-1000, then add IV C Stabilize sodium sulfite so that the sodium sulfite content in the pot water is kept at about 5mg / L. After 4 months of operation, no scale and corrosion were found on the heat transfer surface of the boiler, the original scale layer was obviously thinner, and part of the surface was cleaned. The scale inhibition rate of the standard 20g steel test piece was 100%, and the corrosion inhibition rate was 99.12% %.

example 3

[0013] Example 3: Sodium sulfite and IV C Mix evenly according to the mass ratio of 100:5 to make IV C Stabilized sodium sulfite. Add relative PESA 5mg / L with a molecular mass of 400-1000, then add IV C Stabilize sodium sulfite so that the sodium sulfite content in the pot water is kept at about 5mg / L. After 4 months of operation, no scale and corrosion were found on the heat transfer surface of the boiler, the original scale layer was obviously thinner, and some surfaces have been cleaned. The scale inhibition rate of the standard 20g steel test piece is 100%, and the corrosion inhibition rate is 99.89% %.

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Abstract

The scale and corrosion inhibiting method for industrial boiler includes preparing stable sodium sulfite with sodium sulfite and isoascorbic acid, adding polyepoxy succinic acid into the boiler system, adding stable sodium sulfite and maintaining the amount inside the boiler system in 2-10 mg / L to make these two kinds of green scale inhibitor and deoxidant take synergistic effect, so as to provide environment friendly, high efficiency scale and corrosion inhibiting method for industrial boiler.

Description

technical field [0001] The invention relates to an anti-corrosion and scale-inhibiting method for industrial boilers, in particular to an anti-corrosion and scale-inhibiting method using an anti-scale and oxygen scavenger. Background technique [0002] For low-pressure boilers, the commonly used antiscaling methods are softening-scaling agent method and antiscaling agent method, and the commonly used anti-corrosion methods are deaerator-oxidizing agent method and oxygen scavenging method. The scale inhibitors currently used mainly include phosphate, polyphosphate, organic polyphosphonic acid, polyacrylic acid, styrene sulfonic acid and maleic acid copolymer, etc. These scale inhibitors have good scale inhibition effect, but Can cause environmental problems, so its discharge has been restricted. The more important oxygen scavengers include sulfite, hydrazine, diethylhydroxylamine, carbohydrazide, hydroquinone, aminoguanidine, methyl ethyl ketone oxime, etc. Among them, sulfi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10
Inventor 魏刚蔡世杰熊蓉春
Owner BEIJING UNIV OF CHEM TECH
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