Organic compound containing triazine structure and application thereof
A technology of organic compounds and compounds, applied in organic chemistry, chemical instruments and methods, luminescent materials, etc., can solve problems such as electron tolerance defects, insufficient heat resistance stability, material phase separation or decomposition, etc., and achieve good electronic properties. Mobility, enhancement of optoelectronic performance and device lifetime, effect of high glass transition temperature
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[0092] Embodiment 1: the synthesis of compound 1:
[0093]
[0094] In the three-necked flask, nitrogen was introduced, 0.025mol of intermediate A1, 100ml of DMF, 0.03mol of intermediate B1, 0.0002mol of palladium acetate were added, stirred, and then 0.03mol of K 3 PO 4 Aqueous solution, heating and reflux reaction for 12 hours, sampling point plate, the reaction is complete. Cool naturally, pour the reaction solution into a 500ml beaker, add 200ml distilled water, and carry out mechanical stirring for 10min, then the mixed solution is suction filtered, the filter cake is rinsed once with 100ml distilled water, and then rinsed with 100ml ethanol to obtain Pale yellow solid powder. Finally, the light yellow solid powder was purified by silica gel column with the eluent of dichloromethane:petroleum ether=1:3 to obtain compound 3 with HPLC purity of 99.11% and yield of 75.89%; elemental analysis structure (C 48 h 30 N 6 O) Theoretical: C, 81.57; H, 4.28; N, 11.89; Found:...
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