White slag recovery treatment method

A technology for recycling and processing white slag, which is applied in the field of iron and steel metallurgy, can solve problems such as ineffective treatment and application of white slag, inability to use building materials, and environmental pollution, so as to achieve processing and recycling applications, promote wide application, and avoid environmental pollution. pollution effect

Active Publication Date: 2022-04-22
SHANDONG SHIHENG SPECIAL STEEL GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Since the white slag is pulverized into fine powder, it is easy to cause environmental pollution and has no adhesion, so it cannot be applied to building materials, resulting in no effective treatment and application of white slag.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1 provides a method for recovering white slag, mixing liquid converter slag and liquid white slag, controlling the basicity of the mixed slag obtained after mixing to 2.98, and the content of calcium oxide (CaO) in the mixed slag is 47.11wt%, then the liquid mixed slag is solidified and cooled;

[0032] The white slag is the remaining white slag after continuous casting;

[0033] The converter slag includes the following components in mass percentage: 44.79% of CaO, 16.81% of SiO 2 , 7.83% MgO, 1.88% A1 2 o 3 , 12.06% FeO, 3.12% P 2 o 5 ;

[0034] The white slag comprises the following components in mass percentage: 58% CaO, 11.2% SiO 2 , 5.8% MgO, 2.2% A1 2 o 3 , 0.46% FeO;

[0035] The quality of liquid converter slag: the quality=7500kg of liquid white slag: 1600kg;

[0036] The temperature of liquid converter slag is 1452°C; the temperature of liquid white slag is 1409°C.

Embodiment 2

[0038] Example 2 provides a method for recovering white slag, mixing liquid converter slag and liquid white slag, controlling the basicity of the mixed slag obtained after mixing to 2.94, and the content of calcium oxide (CaO) in the mixed slag is 48.65wt%, then the liquid mixed slag is solidified and cooled;

[0039] The white slag is the remaining white slag after continuous casting;

[0040] The converter slag includes the following components in mass percentage: 45.32% CaO, 17.68% SiO 2 , 8.23% MgO, 1.97% A1 2 o 3 , 13.56% FeO, 2.86% P 2 o 5 ;

[0041]The white slag comprises the following components in mass percentage: 63% of CaO, 11.77% of SiO 2 , 7.8% MgO, 3.5% A1 2 o 3 , 0.48% FeO;

[0042] The quality of liquid converter slag: the quality=8200kg of liquid white slag: 1900kg;

[0043] The temperature of liquid converter slag is 1468°C; the temperature of liquid white slag is 1416°C;

[0044] Adjust the slag dumping process of the converter, control the appro...

Embodiment 3

[0047] Embodiment 3 provides a recovery treatment method of white slag, mixing liquid converter slag and liquid white slag, controlling the basicity of the mixed slag obtained after mixing to 3.0, and the content of calcium oxide (CaO) in the mixed slag is 43.53wt%, then the liquid mixed slag is solidified and cooled;

[0048] The white slag is the remaining white slag after continuous casting;

[0049] The converter slag includes the following components in mass percentage: 41.05% CaO, 14.86% SiO 2 , 5.79% MgO, 1.42% A1 2 o 3 , 13.16% FeO, 3.35% P 2 o 5 ;

[0050] The white slag comprises the following components in mass percentage: 59.6% CaO, 13.1% SiO 2 , 7.1% MgO, 3.2% A1 2 o 3 , 0.4% FeO;

[0051] The quality of liquid converter slag: the quality=8500kg of liquid white slag: 1500kg;

[0052] The temperature of liquid converter slag is 1450°C; the temperature of liquid white slag is 1410°C;

[0053] Adjust the slag dumping process of the converter, control the a...

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PUM

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Abstract

The invention provides a white slag recovery treatment method which comprises the following steps: mixing liquid converter slag and liquid white slag, controlling the alkalinity of mixed slag obtained after mixing to be 2.5-4.5, controlling the content of calcium oxide in the mixed slag to be 40-55 wt%, and then solidifying and cooling the liquid mixed slag; the components of the white slag are adjusted through the slag mixing process, so that the alkalinity of the mixed slag is small, the content of free calcium oxide in the mixed slag is small, the content of iron oxide in the mixed slag is increased, and the problems of automatic pulverization and over-serious pulverization of the white slag in the cooling process are solved; the method has the advantages that the defect that fine powder formed after the white slag is pulverized is easy to pollute the environment is overcome, the cooled mixed slag has high adhesiveness, the cooled mixed slag can be used as a building material, wide application of the white slag is obviously promoted, and treatment and recycling application of the white slag are achieved.

Description

technical field [0001] The invention relates to the technical field of iron and steel metallurgy, in particular to a method for recycling and treating white slag. Background technique [0002] After the converter is tapped, the molten steel is refined outside the furnace and then sent to the continuous casting machine. After pouring, the remaining steel slag becomes basic slag. The basicity of the basic slag is between 3 and 7, and FeO in the slag After cooling, it turns into white powder, which is white slag. The reason why the white slag becomes powder is because the orthosilicate (2CaO·SiO 2 ) when cooled to 850°C, allotropic transformation occurs, from α lattice to γ ​​lattice, and the volume increases, resulting in automatic bursting and pulverization. [0003] Since the white slag is pulverized into a fine powder, it is very easy to cause environmental pollution and has no adhesiveness, so it cannot be applied to building materials, resulting in no effective method f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B18/14C21B3/06
CPCC04B40/0039C21B3/06C04B18/141C04B18/142Y02P10/20Y02W30/50Y02W30/91
Inventor 曾四宝程洪波赵滨孟凡玉
Owner SHANDONG SHIHENG SPECIAL STEEL GROUP
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