Printing ink, and preparation method and application thereof
A technology of ink and mass, applied in the field of ink to achieve the effect of reducing damage, good working performance, and improving viscosity on the high side
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preparation example 1
[0043] This preparation example discloses a preparation method of a microcapsule phase change material (MCPCM), including:
[0044] S01, get n-tetradecane 200kg and methyl methacrylate 100kg and mix both; Add styrene maleic anhydride copolymer 12.5kg to the mixture of n-tetradecane and methyl methacrylate and mix evenly; Under ultrasonic vibration (frequency 60kHz), add 600 kg of water to the mixture of the above three (n-tetradecane, methyl methacrylate and styrene maleic anhydride copolymer), and control the addition time for 30 minutes; after that, ultrasonic vibration 2h, water is mixed with n-tetradecane, methyl methacrylate and styrene maleic anhydride copolymer to obtain an emulsion;
[0045] Among them, n-tetradecane is a low-temperature solid-liquid phase change material, and is used as a core material of the microcapsule; methyl methacrylate is a wall material monomer of the microcapsule; and styrene-maleic anhydride copolymer is used as an emulsifier.
[0046] It s...
preparation example 2
[0051] This preparation example discloses a preparation method of a microcapsule phase change material (MCPCM), including:
[0052] S01, get n-tetradecane 250kg and methyl methacrylate 100kg and both mix homogeneously; Add styrene maleic anhydride copolymer 15kg and mix homogeneously in the mixture of n-tetradecane and methyl methacrylate; Under ultrasonic vibration (frequency 60kHz), add 700kg of water to the mixture of the above three, and control the addition time to 40min; then ultrasonically vibrate for 2.5h to make water and n-tetradecane, methyl methacrylate and styrene maleic acid The anhydride copolymers are mixed to obtain an emulsion.
[0053] S02. Add 30kg of allyl methacrylate (AMA) and 8kg of azobisisobutyronitrile (ABIN) to the emulsion; under nitrogen protection, stir the above emulsion at 55°C for 30min, and control the stirring speed to 1000rpm; then the temperature was raised to 87°C, and stirred at a stirring speed of 400rpm for 2h.
[0054] S03. Vacuum s...
preparation example 3
[0056] This preparation example discloses a preparation method of a microcapsule phase change material (MCPCM), including:
[0057] S01, get n-tetradecane 150kg and methyl methacrylate 100kg and both mix homogeneously; Add styrene maleic anhydride copolymer 10kg and mix homogeneously in the mixture of n-tetradecane and methyl methacrylate; Under ultrasonic vibration (frequency 60kHz), add 500 kg of water to the mixture of the above three, and control the addition time to 25 minutes; after that, ultrasonic vibration for 2 hours to make water and n-tetradecane, methyl methacrylate and styrene maleic anhydride The copolymers are mixed to obtain an emulsion.
[0058] S02. Add 20kg of allyl methacrylate (AMA) and 7kg of azobisisobutyronitrile (ABIN) to the emulsion; under nitrogen protection, stir the above emulsion at 60°C for 20min, and control the stirring speed to 1200rpm; then the temperature was raised to 90°C, and stirred at a stirring speed of 300rpm for 4h.
[0059] S03....
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