A kind of high foam-stabilizing, low-sensitivity concrete air-entraining agent and preparation method thereof
A low-sensitivity, concrete technology, applied in the field of low-sensitivity concrete air-entraining agent and preparation, high foam stability, can solve the problem of hard water in alpine areas, without considering the needs of air-entraining and foam stabilization, concrete air-entraining agent research Less problems, such as low CMC value, improved strength and viscoelasticity, and simple preparation method
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Embodiment 1
[0031] A high foam-stabilizing, low-sensitivity concrete air-entraining agent is prepared from the following components in terms of mass percentage: 20% of a gemini surfactant, 2% of a viscosity modifier, 2% of a foam stabilizer, and 1% of a synergist, water 75%;
[0032] The viscosity modifier is prepared from xanthan gum, guar gum and bone glue in a mass ratio of 1:0.2:1, and the synergist is sodium nitrite;
[0033] The preparation method of the high foam-stabilizing, low-sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0034] Step 1: Preparation of Gemini Surfactant
[0035] (1) in the reactor, add the lauroyl chloride with dichloromethane as solvent, drip the pyridine of solution quality 1%, slowly add N,N-diethylethanolamine under ice bath and stirring condition, lauroyl chloride and N, The molar ratio of N-diethylethanolamine is 1:1.2, then the temperature is raised to 20°C, and the reaction is carried out for 3h to obtain the inter...
Embodiment 2
[0047] A highly foam-stabilizing, low-sensitivity concrete air-entraining agent is prepared from the following components in terms of mass percentage: 40% of a gemini surfactant, 3% of a viscosity modifier, 5% of a foam stabilizer, and 2% of a synergist, water 50%;
[0048] The viscosity modifier is prepared from xanthan gum, guar gum and bone glue in a mass ratio of 1:0.2:1.2, and the synergist is sodium nitrite;
[0049] The preparation method of the high foam-stabilizing, low-sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0050] Step 1: Preparation of Gemini Surfactant
[0051] (1) in the reactor, add the lauroyl chloride with dichloromethane as solvent, drip the pyridine of solution quality 1%, slowly add N,N-diethylethanolamine under ice bath and stirring condition, lauroyl chloride and N, The molar ratio of N-diethylethanolamine is 1:1.4, then the temperature is raised to 25°C, and the reaction is carried out for 2h to obtain the int...
Embodiment 3
[0063] A highly foam-stabilizing, low-sensitivity concrete air-entraining agent is prepared from the following components in terms of mass percentage: 30% of a gemini surfactant, 3% of a viscosity modifier, 5% of a foam stabilizer, and 2% of a synergist, water 60%;
[0064] The viscosity modifier is prepared from xanthan gum, guar gum and bone glue in a mass ratio of 1:0.2:1.5, and the synergist is sodium nitrite;
[0065] The preparation method of the high foam-stabilizing, low-sensitivity concrete air-entraining agent of the present embodiment is as follows:
[0066] Step 1: Preparation of Gemini Surfactant
[0067] (1) in the reactor, add the lauroyl chloride with dichloromethane as solvent, drip the pyridine of solution quality 1.5%, slowly add N,N-diethylethanolamine under ice bath and stirring condition, lauroyl chloride and N, The molar ratio of N-diethylethanolamine is 1:1.2, then the temperature is raised to 25°C, and the reaction is carried out for 2h to obtain int...
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