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Preparation method of environment-friendly modified sesame albumen glue mucilage

A protein glue and modification technology, which is applied in the field of plant protein modification, can solve the problems of speed up, anti-corrosion performance improvement, reduction of adhesive water resistance and bonding strength, etc., to improve bonding strength and water resistance, and enhance dryness. Strength and wet strength, the effect of maintaining natural properties

Pending Publication Date: 2021-12-07
南京尚阳机电科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The production and consumption of sesame in our country ranks first in the world. Most of the sesame is used to make oil. As a by-product of sesame oil, sesame cake is mostly used for animal feed and crop fertilizer. The meal is rich in a large amount of protein, and these sesame proteins are not fully utilized, which makes the economic value of sesame protein small and the additional output value low, resulting in a waste of sesame protein resources
The patent CN109825247A provides a compound modified sesame protein adhesive and its preparation method, using urea and metal oxides to carry out compound modification on sesame protein to obtain a green adhesive with good adhesive performance and waterproof performance. The application of sesame protein in wood adhesives has been broadened. However, this research has not improved its antiseptic performance, and its service life is short. In addition, the secondary structure of sesame protein will be destroyed if the concentration of urea is too high, and water molecules will interact with excess Urea forms hydrogen bonds, which accelerates the penetration rate of water molecules into the sesame protein, but reduces the water resistance and bonding strength of the adhesive.

Method used

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  • Preparation method of environment-friendly modified sesame albumen glue mucilage
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  • Preparation method of environment-friendly modified sesame albumen glue mucilage

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of preparation method of environment-friendly modified sesame protein glue, is prepared by the following steps:

[0026] (1) Mix 100g of sesame cake meal with 2L of distilled water, adjust the pH value to 9 with sodium hydroxide solution at 45°C, stir for 2.5 hours, centrifuge, take the supernatant, then adjust the pH value to 4.0 with hydrochloric acid solution, and stir 5min, refrigerated at 4°C for 20min, centrifuged, the obtained precipitate was washed twice with distilled water, centrifuged, then adjusted to neutrality with sodium hydroxide solution, freeze-dried, finally pulverized with a ball mill, passed through a 100-mesh sieve, and obtained sesame residue protein. spare;

[0027] (2) Mince 10 g of fresh citrus peel, add it to 300 mL of methanol, conduct ultrasonic extraction at 50° C. for 25 minutes, cool to room temperature, filter to obtain a filtrate, then concentrate the filtrate to obtain a peel polyphenol extract, and set aside;

[0028] (3) Mix ...

Embodiment 2

[0033] A kind of preparation method of environment-friendly modified sesame protein glue, is prepared by the following steps:

[0034](1) Mix 110g of sesame cake meal with 2.2L of distilled water, adjust the pH value to 10 with sodium hydroxide solution at 50°C, stir for 3.0 hours, centrifuge, take the supernatant, and then adjust the pH value to 4.2 with hydrochloric acid solution, Stir for 8 minutes, refrigerate at 5°C for 25 minutes, centrifuge, wash the obtained precipitate twice with distilled water, centrifuge, adjust to neutrality with sodium hydroxide solution, freeze-dry, and finally crush with a ball mill, pass through a 100-mesh sieve to obtain sesame residue protein ,spare;

[0035] (2) Mince 15 g of fresh citrus fruit peel, then add it to 350 mL of methanol, conduct ultrasonic extraction at 55° C. for 30 minutes, cool to room temperature, filter to obtain a filtrate, then concentrate the filtrate to obtain a peel polyphenol extract, and set aside;

[0036] (3) Mi...

Embodiment 3

[0041] A kind of preparation method of environment-friendly modified sesame protein glue, is prepared by the following steps:

[0042] (1) Mix 120g of sesame cake meal with 2.5L of distilled water, adjust the pH value to 11 with sodium hydroxide solution at 55°C, stir for 3.5 hours, centrifuge, take the supernatant, and then adjust the pH value to 4.5 with hydrochloric acid solution, Stir for 10 minutes, refrigerate at 6°C for 30 minutes, centrifuge, wash the obtained precipitate twice with distilled water, centrifuge, adjust to neutrality with sodium hydroxide solution, freeze-dry, finally crush with a ball mill, and pass through a 100-mesh sieve to obtain sesame residue protein ,spare;

[0043] (2) Mince 20 g of fresh citrus peel, add it to 400 mL of methanol, conduct ultrasonic extraction at 60° C. for 35 minutes, cool to room temperature, filter to obtain the filtrate, then concentrate the filtrate to obtain the polyphenol extract of the peel, and set aside;

[0044] (3) ...

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Abstract

The invention discloses a preparation method of environment-friendly modified sesame albumen glue mucilage, which comprises the steps of firstly, dissolving sesame cake meal with a sodium hydroxide solution, centrifuging, precipitating with a hydrochloric acid solution, adjusting to be neutral, freeze-drying, crushing and sieving to obtain sesame residue albumen, chopping fresh citrus plant peel, performing ultrasonic extraction to obtain peel polyphenol extract, then obtaining a sesame residue albumen modified solution by using montmorillonite, sodium dodecyl benzene sulfonate, Ca (OH) 2, NaOH and modified sesame residue albumen, finally dropwise adding the peel polyphenol extract into the sesame residue albumen modified solution, and stirring to obtain environment-friendly modified sesame albumen glue mucilage. According to the prepared environment-friendly modified sesame residue albumen glue mucilage, the peel polyphenol extract is used for improving the bonding strength and water resistance of the sesame residue albumen glue mucilage, meanwhile, the corrosion resistance of the sesame residue albumen glue mucilage is enhanced, no chemical preservative is added, environmental protection and safety are achieved, the economic value of sesame cake meal by-products is improved, and the application range of the sesame cake meal by-products is widened.

Description

technical field [0001] The invention relates to the field of plant protein modification, in particular to a preparation method of an environmentally friendly modified sesame protein glue. Background technique [0002] In 2019, the output of wood-based panel products in my country has reached 325 million m 3 , Adhesives are essential in the wood-based panel industry. Today, wood adhesives are divided into aldehyde-based adhesives and environmentally friendly adhesives. Among them, "formaldehyde-based adhesives" (such as urea-formaldehyde resins, phenolic resins, and melamine-formaldehyde resins) are relatively low in cost and proficiency in production processes. There are advantages, but this type of adhesive mainly uses non-renewable petrochemical resources as raw materials. During production, transportation and application, harmful substances such as free aldehydes and free phenols will be produced. When these harmful substances reach a certain concentration, they will har...

Claims

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Application Information

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IPC IPC(8): C09J189/00C09J11/04C09J11/06C09J11/08
CPCC09J189/00C09J11/04C09J11/06C09J11/08C08K2003/2206C08L101/06C08K3/22C08K5/42C08K3/346C08K13/02
Inventor 董玲
Owner 南京尚阳机电科技有限公司
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