Alkane composition, 100 # lead-free aviation gasoline composition containing alkane composition and production method of 100 # lead-free aviation gasoline composition

A technology of aviation gasoline and composition, which is applied in the petroleum industry, liquid carbon-containing fuel, fuel and other directions, can solve the problems of environmental pollution, nitrogen oxide emission easily forming acid rain, unable to meet green environmental protection and other problems

Active Publication Date: 2021-12-03
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The emission of nitrogen oxides is easy to form acid rain and pollute the environment
[0005] To sum up, the existing unleaded aviation gasoline generally contains methyl tert-butyl ether, aromatic amine compounds and other oxygen-containing / nitrogen-containing compounds that pollute the environment , still unable to meet the requirements of green environmental protection

Method used

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  • Alkane composition, 100 # lead-free aviation gasoline composition containing alkane composition and production method of 100 # lead-free aviation gasoline composition
  • Alkane composition, 100 # lead-free aviation gasoline composition containing alkane composition and production method of 100 # lead-free aviation gasoline composition
  • Alkane composition, 100 # lead-free aviation gasoline composition containing alkane composition and production method of 100 # lead-free aviation gasoline composition

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Experimental program
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preparation example Construction

[0080] The preparation method of the aviation gasoline composition of the present invention may also include distilling the alkylation reaction product of C4 olefins and isobutane to obtain a fraction with an initial boiling point of 21-45°C and a final boiling point of 140-153°C as Procedure for blending component A. Preferably, the components obtained have an initial boiling point of 40-45°C. Preferably, the fractions obtained have an end boiling point of 145-153°C. The composition and distillation range of the components obtained by the above method meet the requirements of blending component A described above. The alkylation reaction is carried out in the presence of a catalyst. The catalyst for the alkylation reaction may be an acid, such as one or more selected from sulfonic acid, hydrofluoric acid, and concentrated sulfuric acid. The molar ratio of catalyst to C4 olefin (acid-olefin ratio) can be 1-1.2:1. The temperature of the alkylation reaction can be 4-10°C, the...

Embodiment 1

[0100] 60% by mass of the fractionation tower side draw oil of the alkylation unit (see Table 1-1 for its properties), 15% by mass of light naphtha of the hydrocracking unit (see Table 1-2 for its properties), 15% by mass of The aromatics blending component of the aromatics extraction unit (see Table 1-3 for its properties) is mixed with 10% by mass of mesitylene (see Table 1-4 for its properties), and 160 mg / L methylcyclopentadiene manganese tricarbonyl is added , and then add other various additives according to Table 1-5, after reconciling evenly, obtain aviation gasoline, the property of this aviation gasoline is as shown in Table 1-6.

[0101] Table 1-1

[0102]

[0103] Table 1-2

[0104]

[0105] Table 1-3

[0106]

[0107] Table 1-4

[0108]

[0109]

[0110] Table 1-5

[0111] additive 2,6-di-tert-butyl-4-methylphenol Diethylene glycol monomethyl ether Stadis 450 DCI-4A Amount added 10mg / L 0.12% by volume 2mg / L 20mg / m 3...

Embodiment 2

[0115] 65% by mass of the fractionation tower side draw oil of the alkylation unit (see Table 2-1 for its properties), 15% by mass of light naphtha of the hydrocracking unit (see Table 2-2 for its properties), 10% by mass of The aromatics blending component of the aromatics extraction unit (see Table 2-3 for its properties) is mixed with 10% by mass m-xylene (see Table 2-4 for its properties), and 180 mg / L methylcyclopentadiene manganese tricarbonyl is added , and then add other various additives according to Table 1-5, after reconciling evenly, obtain aviation gasoline, the property of this aviation gasoline is as shown in Table 2-5.

[0116] table 2-1

[0117]

[0118] Table 2-2

[0119]

[0120] Table 2-3

[0121]

[0122] Table 2-4

[0123]

[0124] Table 2-5

[0125]

[0126]

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Abstract

The invention provides an alkane composition, a 100 # lead-free aviation gasoline composition containing the alkane composition and a production method of the 100 # lead-free aviation gasoline composition, the alkane composition contains C4 alkane, C5 alkane, C6 alkane, C7 alkane, C8 alkane and C9 alkane, and the aviation gasoline composition contains base oil and an additive, the base oil comprises the alkane composition as a blending component A, a blending component B, a blending component C and a blending component D, and the additive comprises methylcyclopentadienyl manganese tricarbonyl. The aviation gasoline composition disclosed by the invention does not contain tetraethyl lead while meeting various index requirements of anti-knock property, evaporability, stability and the like, can reduce pollution generated during combustion, is environment-friendly, and can meet the requirement of people on environmental protection. The octane number of the aviation gasoline composition is 99.6-103, the vapor pressure and the distillation range meet the requirements, the cost is low, the raw materials are simple and easy to obtain, and the preparation method is simple.

Description

technical field [0001] The invention belongs to the technical field of aviation fuel, and in particular relates to an alkane composition, No. 100 unleaded aviation gasoline composition containing the alkane composition and a production method thereof. Background technique [0002] Aviation gasoline is a high-octane fuel used in aircraft and is an important part of aviation fuel. The octane number is an indicator of the knock resistance of the fuel used in vehicles. Due to the gradual increase in the compression ratio of aviation engines, the requirements for the octane number of the fuel used by the engines continue to increase. In order to ensure that the engine obtains the maximum power under the condition of no knocking and consumes less fuel, it is necessary to add additives that can improve the anti-knocking performance of the fuel into aviation gasoline. Tetraethyl lead is a commonly used antiknock agent that increases the octane rating of the fuel and prevents knock...

Claims

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Application Information

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IPC IPC(8): C10L1/04
CPCC10L1/04
Inventor 杜文莉隆建钱锋钟伟民杨明磊
Owner EAST CHINA UNIV OF SCI & TECH
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