Lubricating oil composition and lubricating oil defoaming method, and defoaming agent composition
A lubricating oil composition, lubricating oil base oil technology, applied in the direction of lubricating composition, chemical instruments and methods, separation methods, etc., can solve the problems of aggravated lubricating oil deterioration, lubricating performance, cooling efficiency reduction, metal surface wear, etc. Achieve the effect of suppressing the reduction of defoaming performance, suppressing separation and sedimentation
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[0543] Hereinafter, based on an Example and a comparative example, this invention is demonstrated more concretely. It should be noted that the purpose of the following examples is to illustrate the present invention and not to limit the present invention.
manufacture example
[0545] (Determination of molecular weight and molecular weight distribution)
[0546] In the following production examples and examples, the molecular weight and molecular weight distribution were obtained by using a GPC device (Tosoh Corporation) connected in series with three columns (TSK gel Super MultiPore HZ-M manufactured by Tosoh Corporation; inner diameter 4.6mm×15cm). HLC-8220), using tetrahydrofuran as the mobile phase, using a differential refractometer (RI) as the detector, under the conditions of measurement temperature 40°C, flow rate 0.35mL / min, sample concentration 1% by mass, and sample injection volume 5μL , measured using polystyrene as a standard substance.
manufacture example 1
[0548] The first antifoaming agent A-1 was produced according to the following operation steps.
[0549]Methyl isobutyl ketone (polymerization solvent) was introduced into a 500 mL four-necked flask equipped with a stirring paddle made of polytetrafluoroethylene (with a vacuum seal), a serpentine condenser, a three-way cock for nitrogen introduction, and a sample introduction port. ) 200 parts by mass, polysiloxane macromer represented by the following general formula (28) (manufactured by Shin-Etsu Chemical Co., Ltd.; weight average molecular weight 43,000; polydispersity index (Mw / Mn) 1.50) 5 parts by mass and formazan 95 parts by mass of lauryl acrylate, and after stirring to form a homogeneous mixture, the reaction system was vacuumed and purged with nitrogen 5 times using a diaphragm pump. Under nitrogen flow, as a free radical initiator, import MAIB (dimethyl 2,2'-azobisisobutyrate, 2,2'-azobisisobutyrate dimethyl from the sample introduction port: an azo radical polymer...
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