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Water-soaking-resistant flame-retardant single-component silane modified polyether sealant and preparation method thereof

A silane-modified polyether and sealant technology, which is applied in the field of sealants, can solve the problems of slow curing speed at low temperature, low strength, and environmental pollution, and achieve improved water resistance and bonding performance, high-efficiency flame-retardant effects, and avoid The effect of too much additive

Pending Publication Date: 2021-10-19
FOSHAN KESHUN BUILDING MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Prefabricated buildings are one of the main directions of future architectural development. With the development of prefabrication, large-scale, high-rise, underground, diversification and longevity of modern prefabricated buildings, the performance and quality of sealants for construction are greatly affected. Higher requirements are put forward, especially the construction industry has higher and higher requirements for waterproof and fireproof grades, so the requirements for the waterproof performance and flame retardant performance of the building sealants used are also higher and higher; the current wide application The polysulfide sealant, silicone sealant and polyurethane sealant used in the construction industry all have some disadvantages. For example, polysulfide sealant has slow curing speed at low temperature, easy aging and hardening, lack of durability, and strong stimulation when curing. Strong odor, which will pollute the environment and endanger health; polyurethane building sealant is cheap, has excellent adhesion, and has excellent deformation adaptability, but its structure contains a large number of carbamate bonds, which are serious in terms of UV resistance. Insufficient; silicone rubber is excellent in acid and alkali resistance and weather resistance, but it is easy to contaminate adjacent parts, and the surface decoration is poor, etc.
However, the traditional modified silane polyether sealant has poor water resistance and low strength compared to epoxy adhesives, polyurethane adhesives, acrylic adhesives, etc., which greatly limits its application fields. Combustible, excellent sealants are of great significance

Method used

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  • Water-soaking-resistant flame-retardant single-component silane modified polyether sealant and preparation method thereof
  • Water-soaking-resistant flame-retardant single-component silane modified polyether sealant and preparation method thereof
  • Water-soaking-resistant flame-retardant single-component silane modified polyether sealant and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0040] The preparation methods used in the following examples are conventional methods unless otherwise specified.

[0041] The materials and reagents used in the following examples can be obtained from commercial sources unless otherwise specified.

[0042] Among them, the silyl-terminated polyether is a silyl-terminated polyether S303H purchased from Japan Kaneka, which is dimethoxysilyl-terminated and has a viscosity of 13 Pa·S;

[0043] The plasticizer is an alkyl sulfonate purchased from Germany Lanxess Mesamoll;

[0044] The pigment and filler are nano-calcium carbonate purchased from Guangxi Warner New Material Technology Co., Ltd.;

[0045] Thixotropic agent is the polyamide wax purchased from Huanqi Chemical Industry;

[0046] The ultraviolet absorber is UV-327 purchased from Dongguan Zhisheng Chemical Co., Ltd.;

[0047] The UV stabilizer is Tinuvin770 purchased from Dongguan Zhisheng Chemical Co., Ltd.;

[0048] The crosslinking agent is methyltrimethoxysilane p...

Embodiment 1

[0053] This embodiment provides a water immersion-resistant flame-retardant one-component silane-modified polyether sealant, which consists of the following components calculated in parts by weight:

[0054]

[0055] Wherein, the organosilicon-modified epoxy resin synthesized by the reaction of the self-made organosilicon oligomer of monomethyltriethoxysilane and epoxy resin E51, the modification catalyst is tetrabutyl orthotitanate, and the The solvent is xylene; 35:65:80:0.02.

[0056] The self-made tackifier is prepared by the following method:

[0057] S1 After mixing the organosilicon oligomer and the solvent according to the proportion, the temperature of the mixture is raised to 50°C while stirring, and then keep it warm, then add hydrochloric acid with a mass fraction of 38% to it according to the proportion to react, and wait for 2.5 hours to react After that, carry out normal pressure distillation and vacuum distillation successively, steam the ethanol and part o...

Embodiment 2

[0067] This example provides a water immersion-resistant flame-retardant one-component silane-modified polyether sealant. Basically the same as Example 1, the difference between this example and Example 1 is that it consists of the following components calculated in parts by weight:

[0068]

[0069]

[0070] Wherein, the self-made tackifier is a silicone-modified epoxy resin synthesized by the reaction of a silicone oligomer of monomethyltriethoxysilane and epoxy resin E51. The catalyst is tetrabutyl orthotitanate, and the solvent is xylene; the weight ratio of the organosilicon oligomer, epoxy resin, solvent and modification catalyst is 35:65:80:0.02.

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PUM

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Abstract

The invention discloses a water-soaking-resistant flame-retardant single-component silane modified polyether sealant which comprises the following components in parts by weight: 100 parts of silane-terminated modified polyether, 8-15 parts of a plasticizer, 18-40 parts of a pigment and filler, 12-36 parts of a flame retardant, 1-6 parts of a thixotropic agent, 0.02-1 part of an ultraviolet light absorber, 0.02-1 part of an ultraviolet stabilizer, 2-6 parts of a cross-linking agent, 0.2-2 parts of a dewatering agent, 1-4 parts of a self-made tackifier, and 0.1-0.8 part of a catalyst. The self-made tackifier is organic silicon modified epoxy resin synthesized by reacting an organic silicon oligomer with at least two hydrolysable alkoxy silane at one end with epoxy resin, wherein alkoxy is methoxy, ethyoxyl or propyl. The invention also discloses a preparation method of the sealant. According to the invention, the water soaking resistance, flame retardance and adhesive property of the single-component modified silane polyether sealant are improved, so that the double requirements of buildings on water resistance and flame retardance of the sealant are met at the same time.

Description

technical field [0001] The invention relates to the field of sealants, more specifically, to a water-resistant and flame-retardant one-component silane-modified polyether sealant and a preparation method thereof. Background technique [0002] Prefabricated buildings are one of the main directions of future architectural development. With the development of prefabrication, large-scale, high-rise, underground, diversification and longevity of modern prefabricated buildings, the performance and quality of sealants for construction are greatly affected. Higher requirements are put forward, especially the construction industry has higher and higher requirements for waterproof and fireproof grades, so the requirements for the waterproof performance and flame retardant performance of the building sealants used are also higher and higher; the current wide application The polysulfide sealant, silicone sealant and polyurethane sealant used in the construction industry all have some di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J171/00C09J11/04C09J11/06C09J11/08
CPCC09J171/00C09J11/04C09J11/06C09J11/08C08L2201/02C08K2003/323C08K2201/011C08K2003/265C08L63/00C08K3/346C08K3/32C08K3/26C08K5/42
Inventor 何宏林陈立义
Owner FOSHAN KESHUN BUILDING MATERIAL CO LTD
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