BB cream containing nonionic silicon-containing modified waterborne polyurethane dispersion
A water-based polyurethane and non-ionic technology, applied in the field of personal care, can solve problems such as concealer, moisturizing, long-lasting makeup, skin feel, easy to remove makeup, difficulty in adjusting formula, clogged pores, etc., to reduce skin redness and softness to the touch Smooth and prevent clogged pores
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Embodiment 1
[0116] Example 1: Nonionic silicon-containing modified aqueous polyurethane dispersion
[0117] Add 48 grams of PPG1000, 9 grams of CHDM, 67 grams of N120, and 32 grams of KF6001 into a four-necked flask with a condenser and a stirrer, then add 80 grams of HMDI, 0.05 grams of organic bismuth 8108, and 26.6 grams of acetone at 75 ℃ for 1.5 hours, the NCO value is 3.59%;
[0118] After cooling down to 20°C, add 266 grams of acetone and 80 grams of DX1704;
[0119] Add 726 grams of water under high-speed (1400 rpm) shear dispersion, and stir for 5 minutes to obtain a coarse emulsion; then add a mixed solution of 3.2 grams of EDA and 13 grams of deionized water, stir and react for 10 minutes, and the reaction temperature is 35 ° C;
[0120] Afterwards, the solvent acetone was removed from the crude emulsion at 45° C. and 0.01 MPa vacuum to obtain a water-based polyurethane emulsion with a particle size (average particle size) d=40 nm and a solid content of 30 wt%, which was designa...
Embodiment 2
[0121] Embodiment 2: nonionic silicon-containing modified aqueous polyurethane dispersion
[0122] 58 grams of PPG2000, 45 grams of CHDM, 159 grams of N120, and 138 grams of KF6002 were added to a four-necked flask with a condenser and a stirrer, then 167 grams of IPDI, 0.07 grams of organic bismuth 8108, and 38.6 grams of acetone were added at 75 ℃ for 1.5 hours, the NCO value is 2.95%;
[0123] After cooling down to 20°C, add 243 grams of acetone and 115 grams of DX1708;
[0124] Add 1536 grams of water under high-speed (1500 rpm) shear dispersion, stir for 5 minutes to obtain a coarse emulsion, then add a mixed solution of 8 grams of EDA and 40 grams of deionized water, continue stirring for 10 minutes, and the reaction temperature is 40 ° C;
[0125] The coarse emulsion was desolventized with acetone at 45° C. and 0.01 MPa vacuum to obtain a water-based polyurethane emulsion with a particle size (average particle size) d=60 nm and a solid content of 30 wt%, silicon-modifi...
Embodiment 3
[0126] Embodiment 3: nonionic silicon-containing modified aqueous polyurethane dispersion
[0127] Add 1 gram of PPG1000, 39.1 grams of CHDM, 2 grams of 1,4-butanedithiol, 109 grams of N120, and 90 grams of KF6001 into a four-necked flask with a condenser and a stirrer, and then add 141 grams of IPDI, 0.07 gram of organic bismuth 8108, 38.6 grams of acetone, reacted at 75°C for 1.5 hours, and the NCO value was 3.79%;
[0128] After cooling down to 20°C, add 386 grams of acetone and 140 grams of sicare 2422;
[0129] Add 1186 grams of water under shear dispersion at 1500 rpm, stir for 5 minutes to obtain a coarse emulsion, then add a mixed solution of 8 grams of EDA and 40 grams of deionized water, continue stirring for 10 minutes, and the reaction temperature is 40 ° C;
[0130] The crude emulsion was desolventized with acetone at 45° C. and 0.01 MPa vacuum conditions to obtain an aqueous polyurethane emulsion with an average particle diameter of d=60 nm and a solid content o...
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