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Phenolic resin composite board and preparation method thereof

A technology of phenolic resin and composite board, applied in the field of phenolic resin materials, can solve problems such as short service life, influence on popularization and application, and potential safety hazards

Pending Publication Date: 2021-09-14
HUBEI UNIV OF AUTOMOTIVE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Phenolic foam has the advantages of heat resistance, corrosion resistance, flame retardant, low smoke and low toxicity, good heat insulation performance, wide use temperature, flame penetration resistance, aging resistance, etc., but its brittleness, impact strength, compressive strength, bending strength and tensile strength The tensile strength is low, which greatly affects its popularization and application
[0003] At present, the partition walls and exterior wall insulation boards widely used in the market are mainly phenolic foam boards. When this board is used in practice, its structure is fragile, easy to break, easy to damage, and short service life, which brings great harm to people's use. inconvenient
The flame retardant ability of the sound-absorbing panels currently used in the market is not enough, which brings great safety hazards to places where sound-absorbing panels are widely used
At present, the method of pasting glass fiber cloth and aluminum foil on both sides of the phenolic foam board has been invented. Although the strength of the foam is improved, this inhomogeneity also leads to a decline in processing performance.
The method of using honeycomb materials to strengthen phenolic foam boards has been invented at present. Although the strength of phenolic foamed plastics has been greatly improved, the preparation of honeycomb materials is not easy and the price is high, which limits the application of this foamed plastics.

Method used

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  • Phenolic resin composite board and preparation method thereof
  • Phenolic resin composite board and preparation method thereof
  • Phenolic resin composite board and preparation method thereof

Examples

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preparation example Construction

[0039] Based on the same inventive concept, an embodiment of the present application further provides a method for preparing the phenol resin of the composite sheet, comprising the steps of:

[0040] S1, formulated expandable phenolic resin material;

[0041] S2, providing a mold, the foamable phenolic resin material plated in a mold, and then placed on the corrugated plate can be made of phenolic resin materials, can be made and then added to the phenolic resin material corrugated board surface, and then be Add the hair phenolic resin corrugated board material, and then added to the surface of the corrugated plate can be made of phenol resin materials, followed by cycle;

[0042] S3, after the mold is closed, foaming phenol resin to obtain the composite sheet.

[0043] Incidentally, the phenol resin prepared in Example of the present application embodiment of the composite sheet, first formulated expandable phenolic resin material, and then the prepared expandable phenolic resin ...

Embodiment 1

[0059] The present application example provides a method of preparing a phenolic resin composite sheet, comprising the steps of:

[0060] S1, a weight of 100 parts of a thermosetting phenolic resin liquid, 12 parts of surfactant Tween 80, 15 parts of a foam nanopentane, 8 parts of nitric nitric acid stirred at room temperature for 5 min, resulting in hairability Phenolic resin;

[0061] S2, a mold is provided, tabulated in the mold in the mold, and then places the corrugated phenolic resin, and then add a privylene phenol resin surface on the surface of the corrugated plate;

[0062] S3, after the mold is molded, foamed at 80 ° C for 3 h, that is, the phenolic resin foam composite sheet;

[0063] Among them, the corrugated plate is a composite material with a phenolic resin as a substrate, a composite material of a glass fiber cloth, which is prepared by placing two-layer glass fibers together, wetting the phenolic resin, on the hot press on 120 Heating at ° C, after 15 min, the p...

Embodiment 2

[0068] The present application provides a method of preparing a phenolic resin composite sheet, in the same embodiment, and different in that step S2 is specifically: providing a mold, laying the hairdable phenolic resin is tangled in the mold, and then the corrugation plate is placed The proconsive phenol resin is added to the surface of the zigzags and then placed on the surface of the corrugated plate, and a layer of corrugated plate is added thereto, and the viscular phenolic resin is added to the surface of the corrugated plate. In this embodiment, two layers of corrugated plates, the ridge direction of the corrugated plate is parallel to each other, specifically, the stacking method is specifically figure 1 As shown, the corrugated sheet is made of the corrugated plate prepared in Example 1 in the present application embodiment.

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Abstract

The invention provides a phenolic resin composite board and a preparation method thereof. The phenolic resin composite board comprises: a phenolic resin foam board; and at least one corrugated plate, which is embedded in the phenolic resin foam plate from top to bottom. According to the composite board, multiple corrugated boards are embedded in the phenolic resin foam board, and the corrugated boards serve as a framework, so the strength of the phenolic resin foam board is greatly improved, a flame retardant property is not changed, and meanwhile, the low-density characteristic of the phenolic resin foam board is reserved; the strength of the composite board enables the composite board to be applicable to usage scenes such as insulation boards and acoustic boards, the problems of breakage, and falling and the like of traditional phenolic foam materials are solved; and the preparation method is simple in process, low in cost and suitable for being popularized and used in the civil field.

Description

Technical field [0001] Technical Field The present invention relates to a phenolic resin material, phenolic resin, particularly to a composite panel and its preparation method. Background technique [0002] Phenolic foam having heat resistance, corrosion resistance, flame retardancy and low smoke toxicity, heat insulation performance, over a wide temperature, anti-flame penetration, aging resistance, but its large brittleness, impact strength, compressive strength, flexural strength and tensile low tensile strength, greatly affect its application. [0003] Currently on the market used widely in walls, exterior insulation board mainly phenolic foam board, this plate when the specific use of the fragile structure, easily broken, fragile, life is short, to bring great people inconvenient. Currently not enough fire-retardant capability of using sound-absorbing panels on the market, which has brought great security risk for the extensive use of sound-absorbing panels in place. In the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/10C08K7/14C08J9/14C08J5/04C08J5/18
CPCC08J9/141C08J9/0061C08J9/0085C08J5/043C08J5/18C08J2203/14C08J2361/10C08J2461/10C08K7/14
Inventor 赵钦
Owner HUBEI UNIV OF AUTOMOTIVE TECH
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