Normal-temperature self-crosslinking type core-shell structure acrylate emulsion as well as preparation and application thereof
An acrylate and self-crosslinking technology, which is applied in the field of normal temperature self-crosslinking core-shell structure acrylate emulsion and its preparation and application, can solve the problems of high difficulty in process control and high production cost, and achieve small steric hindrance, High degree of copolymerization reaction and good compatibility
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Embodiment 1
[0032] The preparation method of a normal temperature self-crosslinking type core-shell structure acrylate emulsion of the present embodiment comprises the following preparation steps:
[0033] (1) Preparation of modified macromonomer: Add vinyl polyether monomer APEG-350 with a molar ratio of 1:3 and hydrogen-containing silane coupling agent trimethoxysilane into N,N dimethylformamide Stir and mix evenly, then add the organic tin catalyst DBTDL, heat up to 75-80°C and carry out dehydrogenation condensation reaction for 4 hours under the condition of slight negative pressure. Sexual macromonomer, the calculated yield was 62%. The resulting modified macromonomer structural formula can be expressed as CH 2 =CHCH 2 O(CH 2 CH 2 O) n-1 CH 2 CH 2 OSi(OCH 3 ) 3 .
[0034] (2) Preparation of the core layer monomer emulsion: by weight, add 20 parts of styrene (St), 60 parts of methyl methacrylate, 20 parts of methyl acrylate and 4 parts of the total monomer mass of the emulsi...
Embodiment 2
[0039] The preparation method of a normal temperature self-crosslinking type core-shell structure acrylate emulsion of the present embodiment comprises the following preparation steps:
[0040] (1) Preparation of modified macromonomer: Add vinyl polyether monomer APEG-500 with a molar ratio of 1:4 and hydrogen-containing silane coupling agent triethoxysilane to N,N dimethylformamide Stir and mix evenly in medium, then add organotin catalyst DBTDA, heat up to 75-80°C and carry out dehydrogenation condensation reaction for 4 hours under slight negative pressure conditions, after the reaction is completed, the solvent is removed in vacuum and the low boiling point raw materials are recovered to obtain a light yellow transparent liquid The modified macromonomer has a yield of 71% through detection and calculation.
[0041] (2) Preparation of core layer monomer emulsion: by weight, add 25 parts of styrene (St), 50 parts of ethyl methacrylate, 25 parts of ethyl acrylate and 4 parts ...
Embodiment 3
[0046] The preparation method of a normal temperature self-crosslinking type core-shell structure acrylate emulsion of the present embodiment comprises the following preparation steps:
[0047] (1) Preparation of modified macromonomer: Add vinyl polyether monomer APEG-2400 with a molar ratio of 1:2 and hydrogen-containing silane coupling agent trimethoxysilane into N,N dimethylformamide Stir and dissolve evenly, then add the organotin catalyst DBTDA, heat up to 75-80°C and carry out dehydrogenation condensation reaction for 4 hours under the condition of slight negative pressure. The macromonomer has a calculated yield of 53%.
[0048] (2) Preparation of core layer monomer emulsion: by weight, 25 parts of styrene (St), 50 parts of butyl methacrylate, 25 parts of butyl acrylate and emulsifier APEO of 4 parts of total monomer mass were added Stir and emulsify in 150 parts of deionized water to obtain the core layer monomer emulsion;
[0049] (3) Preparation of the shell layer ...
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