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Preparation methods of chemical micro-corroded coral aggregate and geopolymer-based ultrahigh-strength coral concrete

A micro-corrosion and concrete technology, applied in the field of concrete, can solve the problems of adverse effects on the durability of concrete, increase the corrosion of structural concrete steel bars, etc., and achieve the effects of delaying the setting and hardening process, low porosity, and prolonging the setting time.

Active Publication Date: 2021-08-03
ANHUI UNIVERSITY OF ARCHITECTURE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, people often use strong acids such as HCl and H 2 SO 4 Technical methods such as immersion treatment of aggregates are used to solve and remove a large amount of salt and sediment on the surface of coral reef coarse aggregates and in the pores, but such treatment methods will introduce corrosive ions such as sulfate and chloride ions, which will be detrimental to the durability of concrete. influences
For example, the Chinese invention patent application number CN201610079268.8 announced "a method of using coral reefs to prepare coarse aggregates and concrete", which uses dilute hydrochloric acid to soak coral aggregates. The main problem faced by this method is that Cl - The presence of may increase the risk of steel corrosion in structural concrete

Method used

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  • Preparation methods of chemical micro-corroded coral aggregate and geopolymer-based ultrahigh-strength coral concrete
  • Preparation methods of chemical micro-corroded coral aggregate and geopolymer-based ultrahigh-strength coral concrete
  • Preparation methods of chemical micro-corroded coral aggregate and geopolymer-based ultrahigh-strength coral concrete

Examples

Experimental program
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preparation example Construction

[0052] The invention provides a method for preparing chemically slightly corroded coral aggregate, wherein the chemically slightly corroded coral aggregate is chemically slightly corroded coral coarse aggregate or chemically slightly corroded coral sand;

[0053] Wherein, the preparation method of the chemically slightly corroded coral coarse aggregate comprises: soaking the coral coarse aggregate in a phosphoric acid solution, taking out the chemically slightly corroded coral coarse aggregate without washing and directly drying;

[0054] The preparation method of chemical microcorrosion coral sand includes: soaking coral coarse aggregate in phosphoric acid solution, taking out the chemical microcorrosion coral coarse aggregate without washing and directly drying, and then ball milling and sieving, divided into the following different particle sizes Coral fine aggregate: 0.075~0.15mm, 0.15~0.3mm, 0.3~0.6mm, 0.6~1.18mm, 1.18~2.36mm, 2.36~4.75mm, 4.75~9.5mm; the method of directi...

Embodiment 1

[0089] figure 1 It is the preparation flowchart of the chemical microcorrosion coral aggregate of the present embodiment;

[0090] Step 1: Soak coral coarse aggregate in 0.68mol / L phosphoric acid solution for 60 minutes (volume ratio of coral aggregate to phosphoric acid aqueous solution is about 1:2);

[0091] Step 2: After soaking, filter and dry, remove, and dry at 50°C for 24 hours without washing to obtain chemically corroded coral coarse aggregate;

[0092] Step 3: Ball-mill the chemically micro-corroded coral coarse aggregate and sieve it into the following chemically micro-corroded coral fine aggregates of different particle sizes: 0.075-0.15mm, 0.15-0.3mm, 0.3-0.6mm, 0.6-1.18mm , 1.18~2.36mm, 2.36~4.75mm, 4.75~9.5mm;

[0093] Step 4: Composite chemically micro-corroded coral fine aggregates of different particle sizes according to directional gradation to obtain the required gradation of chemically micro-corroded coral sand. The mass fraction is calculated. For spec...

Embodiment 2

[0097] The chemical micro-corrosion coral coarse aggregate prepared in Example 1 is used as aggregate to prepare concrete, and the concrete steps are as follows:

[0098] Raw materials: 9 parts of active powder (a mixture of slag and fly ash with a mass ratio of 3:1), 4 parts of alkali activator (sodium hydroxide modified water glass, modulus of 1.2), 7 parts of aggregate; The active powder and the alkali activator are stirred to prepare the geopolymer slurry, and then the aggregate is stirred to prepare the concrete. Then carry out the fresh mix performance test, and shape 40×40×160mm 3 Prismatic specimens are used for compressive strength tests.

[0099] The initial and final setting times were tested to be 56min and 100min respectively; the 3-day compressive strength was tested to be 34.2MPa.

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Abstract

The invention discloses preparation methods of chemical micro-corroded coral aggregate and geopolymer-based ultrahigh-strength coral concrete, and relates to the technical field of concrete. The preparation method of the aggregate specifically comprises the steps that coral coarse aggregate is placed and soaked in a phosphoric acid solution, taken out and directly dried to obtain chemical micro-corroded coral coarse aggregate; and after ball milling and sieving, compounding is performed by adopting a directional grading compounding method to obtain chemical micro-corroded coral sand. The coral coarse aggregate is subjected to micro-corrosion by using phosphoric acid, so that phosphate grows on the surface of the coral aggregate and in communicated pores in situ, and the porosity of the coral coarse aggregate is reduced. The chemical micro-corroded coral coarse aggregate is subjected to ball milling and screening to obtain chemical micro-corroded coral fine aggregate, and then the coral aggregate is compounded in a directional grading compounding mode to obtain coral sand with low void ratio and high close packing density. The concrete is prepared by taking the substance as aggregate and an alkali-activated active powder material as a cementing material, so that the effects of delaying the setting time of the geopolymer-based coral aggregate concrete, optimizing a concrete interface transition region and improving the mechanical property of the concrete can be achieved.

Description

technical field [0001] The invention relates to the technical field of concrete, in particular to a method for preparing chemically micro-corroded coral aggregate and geopolymer-based ultra-high-strength coral concrete. Background technique [0002] In recent years, the development of islands in my country has gradually increased, and the engineering construction as the basis for development has also encountered certain challenges. The reserves of building aggregate gravel and river sand in inland areas are decreasing day by day, and the cost of inland shipping sand and gravel for ocean construction is high, which is not conducive to project cost control. At the same time, there is a huge stock of coral reefs and reef sand around the islands, which are potential building materials. However, the particularity of the growth environment of undisturbed coral reefs leads to their own porous structure, different shapes, low strength and a large amount of sediment. From the persp...

Claims

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Application Information

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IPC IPC(8): C04B20/02C04B28/00C04B14/28C04B20/00
CPCC04B20/023C04B14/28C04B28/006C04B2201/52C04B2201/50C04B22/062C04B12/04C04B18/08C04B18/141C04B14/48C04B20/0076Y02P40/10
Inventor 王爱国王星尧孙道胜刘开伟马瑞徐海燕管艳梅曹菊芳董伟伟赵俊
Owner ANHUI UNIVERSITY OF ARCHITECTURE
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