Preparation method of high-quality scandium-doped aluminum nitride film template

A high-quality technology of aluminum nitride, applied in the direction of gaseous chemical plating, ion implantation plating, coating, etc., can solve the problems of low phase velocity of SAW devices, reduce the piezoelectric performance of the film, increase the acoustic loss, etc., and achieve high Acoustic phase velocity, improvement of crystallization quality, and good crystallization performance

Pending Publication Date: 2021-07-27
ULTRATREND TECH INC
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  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0004] Although SAW / BAW devices based on scandium-doped aluminum nitride thin films have very bright application prospects, there are great difficulties and challenges in the preparation of scandium-doped thin films, and it is difficult to achieve high-quality and mass production
Currently, based on the low aluminum phase (La 3 Ga 5.5 Ta 14 o 14 , LGT), silicate (La 3 Ga 5.5 Ta 0.5 o 14 , LGT) or aluminosilicate (La 3 Ga 5.5 Nb 0.5 o 14 , LGN) commercially available SAW devices have low phase velocity (eg LGS: 2700m / s) and high acoustic propagation loss, with the increase of temperature and frequency, the acoustic loss will increase greatly
In addition, since the layered wurtzite structure is not the most stable phase, as the doping concentration of scandium increases, the coating process parameter window will narrow, and the orientation of the film will easily deteriorate or even form a polycrystalline film, resulting in a decrease in the pressure of the film. Electrical performance, which brings deterioration of the electromechanical coupling coefficient and quality factor Q value to the device

Method used

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  • Preparation method of high-quality scandium-doped aluminum nitride film template
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  • Preparation method of high-quality scandium-doped aluminum nitride film template

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Embodiment 1

[0036] Reference attached figure 1 And attached figure 2 , in this illustrated embodiment, a method for preparing a high-quality scandium-doped aluminum nitride thin film template, including:

[0037] S1. Provide a single crystal sapphire substrate.

[0038] In this embodiment, the sapphire substrate 10 with a positive C-direction surface is provided as an example.

[0039] S2. Depositing a layer of AlN transition layer 21 on the single crystal sapphire substrate 10 by coating technology;

[0040] S3. Using high-temperature face-to-face heat treatment technology to perform high-temperature heat treatment on the AlN transition layer 21 under pure nitrogen to form a high-quality AlN buffer layer 22;

[0041] S4. Deposit scandium-doped AlN thin film 30 on AlN buffer layer 22 by DC reactive magnetron sputtering deposition method.

[0042] Steps S2 and S3 are combined with each other. Among the many coating technologies of the AlN transition layer 21, the magnetron sputtering ...

Embodiment 2

[0053] Reference attached figure 1 And attached figure 2 , in this illustrated embodiment, a method for preparing a high-quality scandium-doped aluminum nitride thin film template, including:

[0054] S1. Provide a single crystal silicon substrate. In this embodiment, the (100) crystal plane silicon substrate 40 is taken as an example.

[0055] S2. On the silicon substrate 40, first deposit a layer of SiO with a film thickness of 100 nm by using magnetron sputtering technology 2 Thin film layer 51 (process S2-1), again in SiO 2 Deposit a layer of AlN thin film layer 61 with a film thickness of 100-500 nm on the thin film layer 51 (process S2-2), and the above two layers form the transition layer 71;

[0056] S3. Using high-temperature face-to-face heat treatment technology to perform high-temperature heat treatment on the transition layer 71 under pure nitrogen to form a high-quality buffer layer 72;

[0057] S4. Depositing the scandium-doped AlN thin film 30 on the buff...

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Abstract

The invention provides a preparation method of a high-quality scandium-doped aluminum nitride film template. The preparation method includes the following steps of: S1, preparing a substrate; S2, depositing a film transition layer on the substrate by adopting a coating technology; S3, thermally treating the film transition layer at a high temperature in a pure nitrogen atmosphere by adopting a high-temperature face-to-face heat treatment technology to form a high-quality buffer layer; and S4, depositing a scandium-doped aluminum nitride film on the buffer layer by adopting a reactive magnetron sputtering deposition method. The preparation method provided by the invention can be used for preparing a scandium-doped aluminum nitride thin film with a high crystallization property, solves the problem that the orientation of the aluminum nitride thin film is seriously deteriorated due to doping of a high Sc concentration, and achieve results of far exceeding the level of the prior art under different film thicknesses, and lays a solid foundation for application of SAW / BAW devices with a higher frequency, enhanced piezoelectric response, a higher electromechanical coupling coefficient and a higher Q value.

Description

technical field [0001] The invention relates to the technical field of semiconductor material preparation, in particular to a method for preparing a high-quality scandium-doped aluminum nitride film template. Background technique [0002] Aluminum nitride (AlN) is a hexagonal wurtzite structure III-V nitride widely used in the field of acoustic wave electronic devices. Compatible and has high thermal conductivity. In addition, due to its own characteristics such as high surface acoustic wave (SAW) phase velocity and low material temperature coefficient (TCD), aluminum nitride thin films have achieved rapid development in the past 30 years. However, due to the relatively small lateral effective electromechanical coupling coefficient (≈0.5%) of AlN thin film, its application is limited. In order to improve its electromechanical coupling coefficient while retaining other excellent properties, an effective method is to dope it to produce a new ternary nitride, and use other Gr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/35C23C14/58C23C14/06C23C14/10C23C14/14C23C16/34C23C16/40C23C16/06C23C16/56
CPCC23C14/352C23C14/5806C23C14/10C23C14/14C23C14/0641C23C16/34C23C16/402C23C16/06C23C16/56
Inventor 吴亮王琦琨付丹扬龚建超刘欢
Owner ULTRATREND TECH INC
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