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Sound absorption black body foam material and preparation method thereof

A foam material and foam technology, applied in the field of sound-absorbing black body foam material and its preparation, can solve the problems of high cost of graphene, sheet slip, loss of ultra-thin vibration characteristics of graphene, etc.

Active Publication Date: 2021-06-08
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still two major problems with graphene drums as acoustic absorbing materials.
First of all, it is difficult to assemble ultra-thin graphene drums into macroscopic materials for daily use; although aerogels can assemble nanometer-thick graphene in three-dimensional porous materials, due to the weak bonding between sheets , not fixed to form a nano-graphene drum structure, so it is easy to produce sheet slip during vibration, which affects its sound absorption ability; and due to the high cost of graphene, it is still more expensive to use graphene alone for large-scale applications. insufficient
Secondly, inside the polymer foam where graphene sheets are directly fixed, graphene tends to pile up layers, which seriously loses the ultra-thin vibration characteristics of graphene.
Therefore, there are still huge challenges in how to prepare new high-performance sound-absorbing materials.

Method used

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  • Sound absorption black body foam material and preparation method thereof
  • Sound absorption black body foam material and preparation method thereof
  • Sound absorption black body foam material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Melamine foam (pore size 50-200um) with a thickness of 20mm was immersed in 10mg / ml aqueous graphene oxide (purchased from Hangzhou Gaoxi Technology Co., Ltd., with an average size of 20um) for 2 hours, and then the dried foam was hydrated to 30% Hydrazine was foamed for 2 hours, and after natural drying, a high-performance multi-stage foam sound-absorbing black body material was obtained, such as image 3 As shown, the wall thickness of graphene in the secondary foam structure is 20nm, the average sound absorption coefficient at 100-10000Hz is 0.78, and the average sound absorption coefficient at 200-6000Hz is 0.86.

Embodiment 2

[0028] With embodiment 1, wherein the pore diameter of melamine foam is 50-200um, and thickness is 30mm, the obtained high-performance multistage foam sound-absorbing blackbody material, wherein the wall thickness of graphene in the secondary foam structure is 20nm, at 100-10000Hz The average sound absorption coefficient is 0.8, and the average sound absorption coefficient at 200-6000Hz is 0.89.

Embodiment 3

[0030] With embodiment 2, wherein the polyurethane foam that melamine foam is replaced by pore diameter is 10-100um, the obtained high-performance multistage foam sound-absorbing black body material, wherein the wall thickness of graphene in the secondary foam structure is 15nm, in 100-100um The average sound absorption coefficient at 10000Hz is 0.75, and the average sound absorption coefficient at 200-6000Hz is 0.83.

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Abstract

The invention provides a multi-stage foam sound absorption black body material for the first time, graphene aerogel is introduced into a commercialized polymer foam skeleton by using a solvent plasticizing foaming technology, so that ultrathin graphene drums are embedded into the foam skeleton, and when sound waves enter the foam black body, a large number of graphene drums generate a violent resonance effect, so that attenuation of the sound waves is rapidly achieved, and in combination with friction loss of a porous structure of the polymer foam to the sound waves, the sound absorption black body foam material has excellent sound absorption performance in a broadband range. The scheme is based on a commercial foam material, the method is simple, the cost is low, and the potential of wide industrial application is achieved.

Description

technical field [0001] The invention belongs to the technical field of functional materials, and in particular relates to a sound-absorbing black body foam material and a preparation method thereof. Background technique [0002] Sound-absorbing materials have a wide range of applications, and play an indispensable role in various fields from personal protection, electrical protection to architectural design. At present, about 1 / 5 people in the world are suffering from hearing loss, and this number is constantly increasing rapidly. Therefore, it is particularly important to explore high-performance acoustic absorbing materials. As a traditional sound-absorbing material, polymer foam has been widely used in various fields due to its highly porous structure. The basic principle of its sound-absorbing performance mainly relies on the friction of sound waves in the porous cavity to generate loss. At present, there have been many studies on the pore size and pore structure of po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B38/10C04B30/00C04B111/40C04B111/52
CPCC04B30/00C04B2111/40C04B2111/52C04B14/024C04B24/129C04B38/106C08J9/40C08J2375/04C08J2361/28C08J2205/044C08J2201/038C04B16/08C04B38/02C04B32/02C04B38/08C08J9/35C08J2379/02
Inventor 许震刘晓婷高超庞凯
Owner ZHEJIANG UNIV
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