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Quartz sand filter material with excellent oleophylic and hydrophobic properties and preparation method thereof

A quartz sand, hydrophobic technology, applied in the field of quartz sand, can solve the problems of difficult oily wastewater and discharge up to standard

Inactive Publication Date: 2021-05-18
徐州康纳高新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, due to the limitations of economic conditions and technical factors, it is difficult to completely discharge oily wastewater up to the standard

Method used

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  • Quartz sand filter material with excellent oleophylic and hydrophobic properties and preparation method thereof
  • Quartz sand filter material with excellent oleophylic and hydrophobic properties and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] (1) Pretreatment of quartz sand: Use a 20-30 mesh stainless steel sieve to screen out quartz sand with a particle size of 0.55-0.83mm, wash it repeatedly with deionized water until it is no longer turbid, and then put it in a vacuum drying oven at 110°C Dry for 12 hours; after cooling, soak the quartz sand in 1mol / L nitric acid solution for 20 hours, then soak it in absolute ethanol for 30 minutes, and finally wash and dry it for use; (2) surface modification: according to the formula, the The surface modification liquid, in parts by mass, mainly consists of the following components: 395 parts of absolute ethanol, 25 parts of tris(hydroxymethyl)aminomethane, 1.58 parts of nano-zinc oxide, 0.0025 parts of dopamine hydrochloride; Methyl) aminomethane is dissolved in dehydrated alcohol, obtains the ethanol solution of tris (hydroxymethyl) aminomethane, then nanometer zinc oxide, dopamine hydrochloride are added in the ethanol solution of above-mentioned tris (hydroxymethyl)...

Embodiment 2

[0042] (1) Pretreatment of quartz sand: Use a 20-30 mesh stainless steel sieve to screen out quartz sand with a particle size of 0.55-0.83mm, wash it repeatedly with deionized water until it is no longer turbid, and then put it in a vacuum drying oven at 100°C Dry for 10 hours; after cooling, soak the quartz sand in 1mol / L nitric acid solution for 20 hours, then soak in absolute ethanol for 30 minutes, and finally wash and dry for use;

[0043] (2) Surface modification: According to the formula, the surface modification liquid is mainly composed of the following components in parts by mass: 395 parts of absolute ethanol, 28 parts of tris(hydroxymethyl)aminomethane, nano 1.59 parts of zinc oxide, 0.003 part of dopamine hydrochloride; tris(hydroxymethyl)aminomethane is dissolved in absolute ethanol to obtain an ethanol solution of tris(hydroxymethyl)aminomethane, and then nanometer zinc oxide and dopamine hydrochloride are added to the three (Hydroxymethyl) aminomethane is disso...

Embodiment 3

[0047] (1) Pretreatment of quartz sand: Use a 20-30 mesh stainless steel sieve to screen out quartz sand with a particle size of 0.55-0.83mm, wash it repeatedly with deionized water until it is no longer turbid, and then put it in a vacuum drying oven at 100°C Dry for 12 hours; after cooling, soak the quartz sand in 1mol / L nitric acid solution for 22 hours, then soak in absolute ethanol for 30 minutes, and finally wash and dry for use;

[0048] (2) Surface modification: According to the formula, the surface modification liquid is mainly composed of the following components in parts by mass: 395 parts of absolute ethanol, 25 parts of tris(hydroxymethyl)aminomethane, nano 1.54 parts of zinc oxide, 0.0028 parts of dopamine hydrochloride; tris(hydroxymethyl)aminomethane is dissolved in absolute ethanol to obtain an ethanol solution of tris(hydroxymethyl)aminomethane, and then nanometer zinc oxide and dopamine hydrochloride are added to the three (Hydroxymethyl) aminomethane is dis...

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Abstract

The invention relates to a quartz sand filter material with excellent oleophylic and hydrophobic properties and a preparation method thereof. The quartz sand filter material is obtained by performing surface modification on quartz sand through a surface modification liquid, then performing self-assembly of a molecular film through a self-assembly liquid, and finally performing composite modification through an iron-copper modification liquid. The surface modification liquid is mainly prepared from the following components by mass: 390-400 parts of anhydrous ethanol, 25-28 parts of tris(hydroxymethyl)aminomethane, 1.5-1.6 parts of nano zinc oxide and 0.002-0.003 part of dopamine hydrochloride; the self-assembly liquid is mainly prepared from the following components by mass: 5-20 parts of a coupling agent and 80-100 parts of a solvent. According to the quartz sand filter material with excellent oleophylic and hydrophobic properties and the preparation method thereof, the formula is reasonable, the quartz sand filter material which is high in surface roughness, has a super-hydrophobic surface, is excellent in lipophilicity and high in oil removal efficiency and has the capacity of removing micro-pollutants in water is prepared, the preparation process is simple, large-scale production is easy, and the application prospect is wide.

Description

technical field [0001] The invention belongs to the technical field of quartz sand, and in particular relates to a quartz sand filter material with excellent lipophilic and hydrophobic properties and a preparation method thereof. Background technique [0002] As a kind of inorganic particles that widely exist in nature, quartz sand filter material has high surface hardness, strong mechanical stability, good pollution interception performance, low price and easy purchase. It is a commonly used natural filter material for sewage treatment. With the continuous development of my country's industrial technology, oily substances and organic solvents are used more and more frequently in daily life and industrial production, and the production scale of waste oil is increasing day by day, but limited by the lagging behind in the development of industrial production technology , Insufficient management level of the production discharge process and other reasons cause a large amount of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/06B01J20/10B01J20/28B01J20/30C02F1/28C02F1/40
CPCB01D39/06B01J20/103B01J20/28011C02F1/40C02F1/281
Inventor 王永江陈辉
Owner 徐州康纳高新材料科技有限公司
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