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Mildew-proof wear-resistant environment-friendly PVC artificial leather and preparation method thereof

A kind of artificial leather, environmental protection technology, applied in the field of leather processing, can solve the problems of bad smell, shorten the service life of the product, aging, etc., achieve outstanding adsorption and anti-corrosion and anti-bacterial properties, improve strength and abrasion resistance, improve flame retardancy and anti-aging effect

Pending Publication Date: 2021-04-30
嘉兴市博尔新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, for PVC artificial leather products, there are mainly the following problems: First, due to the need to use some volatile processing aids (such as plasticizers) in the processing process, the final PVC artificial leather products often have certain The unpleasant smell not only affects the normal use of the product, but also causes potential harm to human health; second, most of the existing PVC artificial leather products have poor wear resistance, poor aging resistance, and poor water resistance. Obvious aging, wear, peeling, mildew and other phenomena will not only seriously affect the aesthetics of leather products, but also greatly shorten the service life of the products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] The anti-mildew and wear-resistant environmentally friendly PVC artificial leather of this embodiment comprises a base cloth layer and a PVC surface layer attached to the base cloth layer, wherein the PVC surface layer is prepared from raw materials comprising the following components and their weight parts content: PVC resin 100 parts, 20 parts of functional elastomer, 50 parts of plasticizer, 12 parts of coconut shell powder modified vermiculite powder, 4 parts of crosslinking agent, 1 part of heat stabilizer, 1 part of antibacterial agent and 0.2 part of foaming agent.

[0039] The functional elastomer used in this embodiment is a thermoplastic polyurethane elastomer modified by graphene oxide. Based on the mass of thermoplastic polyurethane elastomer, the amount of graphene oxide added is 5wt%. The specific preparation method is: first prepare the content of 2 wt% graphene oxide aqueous suspension, and then adding isocyanate modifier and thermoplastic polyurethane elas...

Embodiment 2

[0048] The anti-mildew and wear-resistant environmentally friendly PVC artificial leather of this embodiment comprises a base cloth layer and a PVC surface layer attached to the base cloth layer, wherein the PVC surface layer is prepared from raw materials comprising the following components and their weight parts content: PVC resin 100 parts, 23 parts of functional elastomer, 57 parts of plasticizer, 15 parts of coconut shell powder modified vermiculite powder, 6 parts of crosslinking agent, 2 parts of heat stabilizer, 1 part of antibacterial agent and 1 part of foaming agent.

[0049] The functional elastomer used in this example is a graphene oxide modified thermoplastic polyurethane elastomer. Based on the mass of the thermoplastic polyurethane elastomer, the amount of graphene oxide added is 7 wt%. The specific preparation method is: first prepare the content 4 wt% graphene oxide aqueous suspension, and then adding isocyanate modifier and thermoplastic polyurethane elastom...

Embodiment 3

[0058] The anti-mildew and wear-resistant environmentally friendly PVC artificial leather of this embodiment comprises a base cloth layer and a PVC surface layer attached to the base cloth layer, wherein the PVC surface layer is prepared from raw materials comprising the following components and their weight parts content: PVC resin 100 parts, 26 parts of functional elastomer, 60 parts of plasticizer, 18 parts of coconut shell powder modified vermiculite powder, 10 parts of crosslinking agent, 4 parts of heat stabilizer, 2 parts of antibacterial agent and 3 parts of foaming agent.

[0059] The functional elastomer used in this example is a graphene oxide modified thermoplastic polyurethane elastomer. Based on the mass of the thermoplastic polyurethane elastomer, the amount of graphene oxide added is 10 wt%. The specific preparation method is: first prepare the content 5 wt% graphene oxide water suspension, and then add isocyanate modifier and thermoplastic polyurethane elastome...

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PUM

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Abstract

The invention relates to mildew-proof wear-resistant environment-friendly PVC artificial leather and a preparation method thereof. The PVC artificial leather comprises a base cloth layer and a PVC surface layer attached to the base cloth layer. The PVC surface layer is prepared from the following raw materials in parts by weight: 100 parts of PVC resin, 20-30 parts of a functional elastomer, 50-70 parts of a plasticizer, 12-20 parts of coconut shell powder modified vermiculite powder, 4-12 parts of a cross-linking agent, 1-5 parts of a heat stabilizer, 1-3 parts of an antibacterial agent and 0.2-4 parts of a foaming agent. Compared with the prior art, the PVC artificial leather disclosed by the invention does not contain any volatile solvent, is good in environmental protection property, smooth in hand feeling, strong in stereoscopic impression and high in glossiness quality, has excellent mould-proof, antibacterial and wear-resistant scratching properties, is plump in hand feeling like real leather, has physical properties reaching test standards, and is long in service life; the problems that existing PVC leather is prone to aging, mildewing, peeling and the like can be effectively solved, and high economic practicability is achieved.

Description

technical field [0001] The invention belongs to the technical field of leather processing, and relates to a mildew-proof, wear-resistant and environment-friendly PVC artificial leather and a preparation method thereof. Background technique [0002] Artificial leather is also called imitation leather or rubber, which is a plastic product that looks and feels like leather and can be used instead of it. Artificial leather is usually made of different formulations of PVC or PU foamed or coated on a woven or non-woven fabric base. It has the characteristics of a wide variety of designs and colors, good waterproof performance, neat edges, high utilization rate and relatively cheap price compared with real leather. [0003] At present, for PVC artificial leather products, there are mainly the following problems: First, due to the need to use some volatile processing aids (such as plasticizers) in the processing process, the final PVC artificial leather products often have certai...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/06B32B27/30B32B33/00C08L27/06C08L75/04C08K9/04C08K3/34C08K3/04C08K9/02C08K9/06C08K13/06C08J9/10C08J5/18B29B7/28B29C44/60B29C59/02B29D7/01
CPCB32B5/18B32B33/00C08J9/103C08J9/0095C08J9/009C08J9/0066C08J9/0061C08J5/18B29D7/01B29B7/28B29C44/60B29C59/02B32B2266/0235C08J2203/04C08J2327/06C08J2475/04C08K9/04C08K3/34C08K3/042C08K9/02C08K9/06C08K13/06
Inventor 张惠良
Owner 嘉兴市博尔新材料股份有限公司
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