Method for improving dye-uptake of direct dyes on cotton fabrics

A direct technology for cotton fabrics, which is applied in the field of improving the dyeing rate of direct dyes on cotton fabrics, can solve the problems of external water environment pollution, strong toxicity, health threats to operators, etc., and achieves improved K/S value, low cost, and reduced Effects of Environmental Pollution and Harm on Human Body

Pending Publication Date: 2020-10-30
WUHAN TEXTILE UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although this technology can greatly increase the dyeing rate of direct dyes, it poses a health threat to operators due to the extremely strong pungent odor and strong toxicity of common cationic modifiers
At the same time, if the wastewater produced by this process is not strictly treated, it is very likely to cause serious pollution to the external water environment after discharge.

Method used

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  • Method for improving dye-uptake of direct dyes on cotton fabrics
  • Method for improving dye-uptake of direct dyes on cotton fabrics
  • Method for improving dye-uptake of direct dyes on cotton fabrics

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] (1) The cotton fabric after bleaching and scouring is completely submerged in a citric acid solution with a solvent of 40g / L and a chitosan solution with a concentration of 12g / L, and then the excess solution is removed to control the amount of liquid carried on the cotton fabric 100% by weight, pre-baking at a temperature of 70°C for 2 minutes, and then heating and curing at a temperature of 180°C for 60s;

[0054] (2) Washing the solidified cotton fabric in step (1) in a sodium citrate solution with a concentration of 35g / L, followed by drying;

[0055] (3) After placing the treated cotton fabric obtained in step (2) in a dye solution of sodium copper chlorophyllin (sodium copper chlorophyllin consumption is 1% o.w.f., and the pH value of the solution is 6.4) and stirred for 15 min, the mixture was stirred at a temperature of 5° C. / min. The heating rate is raised from room temperature to 95°C, and the temperature is kept at a constant temperature for 1 hour, and the t...

Embodiment 2

[0058] Implement according to the method described in Example 1, the difference is that in step (1), the concentration of the chitosan solution is 11g / L, to obtain dyed cotton fabric sample A2.

Embodiment 3

[0060] Carried out according to the method described in Example 1, the difference is that in step (1), the liquid carrying amount of the cotton fabric was controlled to be 105% by weight to obtain dyed cotton fabric sample A3.

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Abstract

The invention relates to the field of textile printing and dyeing, and discloses a method for improving the dye-uptake of direct dyes on cotton fabrics. The method comprises the following steps that (1) the cotton fabrics are treated by a chitosan solution, specifically, the pretreated cotton fabrics are completely immersed in the chitosan solution, then an excess solution is rolled out, pre-roasting is conducted, heating and solidifying are conducted, then washing is conducted in a weakly acidic solution, and then drying is conducted; and (2) dyeing is conducted, specifically, the treated cotton fabrics obtained in step (1) are placed in a direction dye solution for stirring, then heating and heat preservation are conducted, and the cotton fabrics are soaped and dried; wherein in the step(1), the preparation method of the chitosan solution comprises the steps that chitosan is dissolved in a citric acid solution with the concentration of 40-50 g/L; and the concentration of the chitosan solution is 10-15 g/L. According to the method, citric acid is used as a crosslinking agent, the chitosan is crosslinked on the cotton fabrics, and the dye-uptake of the direct dyes on the cotton fabrics is improved.

Description

technical field [0001] The invention relates to the field of textile printing and dyeing, in particular to a method for improving the dyeing rate of direct dyes on cotton fabrics. Background technique [0002] Due to the poor affinity of direct dyes to cellulose, it is difficult to obtain a high dye uptake rate in the dyeing of cotton fabrics, resulting in a low apparent color depth (K / S) of the dyed fabrics, which is difficult to obtain. Dye dark. [0003] Cationic modified cotton fabrics are a solution that can alleviate this problem. This technology uses cationic modifiers on the surface of cotton fibers, such as 3-chloro-2-hydroxypropyltrimethylammonium chloride (CHPTAC), and dyes the grafted cotton fabrics at a specific pH. The amine group in the neutralizing agent is protonated to be positively charged under acidic conditions, and forms an electrostatic attraction with the negatively charged sulfonate and carboxylate groups in the direct dye, thereby improving the de...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P3/62D06P1/48D06P1/653
CPCD06P3/62D06P1/48D06P1/6533D06P5/002
Inventor 吴济宏赵仲林经纬张新斌高秀红朱三童
Owner WUHAN TEXTILE UNIV
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