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Low-smoke halogen-free and flame-retardant polyolefin cable material with high cracking resistance

A polyolefin cable material, high-density polyethylene technology, used in circuits, electrical components, plastic/resin/wax insulators, etc. The effect of improving flame retardant performance, improving cracking resistance and improving mechanical properties

Inactive Publication Date: 2020-09-08
上海方之德新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Cable material refers to the plastic used for wire and cable insulation and sheathing. As people become more and more aware of fire prevention, people pay more and more attention to the flame retardant performance of cable materials. However, adding halogen-containing plastics to cable materials Flame retardants, when there is a fire, will produce toxic smoke, causing greater casualties, so now low-smoke halogen-free flame-retardant cable materials are more and more widely used
[0003] In order to make the cable material have low-smoke, halogen-free flame-retardant properties, it is necessary to fill it with more flame retardants. More flame retardants tend to be unevenly distributed in the cable material, which reduces the mechanical properties of the cable material. When the cable When the cable is coiled, the cable material may crack at the bending position, which cannot protect the cable, and there is still room for improvement in the smoke suppression and flame retardant performance of the existing cable material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A high-cracking-resistant low-smoke halogen-free flame-retardant polyolefin cable material is prepared by the following method: 65g of ethylene-vinyl acetate copolymer, 35g of high-density polyethylene, 10g of magnesium hydroxide, 40g of aluminum hydroxide, and 0.05g of melamine Urate, 11g red phosphorus, 4.375g acrylic acid, 5.625g propenyl alcohol, 5g 4,4'-thiobis-(2-methyl-6-tert-butylphenol), 15g silica with a diameter of 30nm, Mix 15g of methyl silicone resin, 5g of zinc hydroxystannate with a diameter of 50nm, 1.75g ​​of sorbitol, and 0.5g of sodium alginate evenly, and banbury at 130°C for 10 minutes, and then at 115°C, use A twin-screw extruder is used for extrusion and granulation to obtain a high-crack-resistant, low-smoke, halogen-free, flame-retardant polyolefin cable material.

Embodiment 2

[0055] A high-cracking-resistant, low-smoke, halogen-free, flame-retardant polyolefin cable material is prepared by the following method: 75g of ethylene-vinyl acetate copolymer, 25g of high-density polyethylene, 18g of magnesium hydroxide, 20g of aluminum hydroxide, and 0.25g of melamine Urate, 5g red phosphorus, 8.75g acrylic acid, 11.25g propenyl alcohol, 2g 4,4'-thiobis-(2-methyl-6-tert-butylphenol), 21g silica with a diameter of 30nm, Mix 9g of methyl silicone resin, 11g of zinc hydroxystannate with a diameter of 50nm, 1.25g of sorbitol, and 1.5g of sodium alginate evenly, and banbury at 130°C for 10min, and then at 115°C, use A twin-screw extruder is used for extrusion and granulation to obtain a high-crack-resistant, low-smoke, halogen-free, flame-retardant polyolefin cable material.

Embodiment 3

[0057] A high-cracking-resistant low-smoke halogen-free flame-retardant polyolefin cable material is prepared by the following method: 70g of ethylene-vinyl acetate copolymer, 30g of high-density polyethylene, 14g of magnesium hydroxide, 30g of aluminum hydroxide, and 0.15g of melamine Urate, 8g red phosphorus, 6.75g acrylic acid, 8.25g propenyl alcohol, 3.5g 4,4'-thiobis-(2-methyl-6-tert-butylphenol), 18g carbon dioxide with a diameter of 32.5nm Silicone, 12g of methylphenyl silicone resin, 8g of zinc hydroxystannate with a diameter of 50nm, 1.5g of sorbitol, and 1g of sodium alginate were mixed evenly, and banburyed at a temperature of 135°C for 12.5min, and then mixed at a temperature of 127.5°C Under the temperature, the twin-screw extruder is used for extruding and granulating to obtain the high-cracking-resistant, low-smoke, halogen-free and flame-retardant polyolefin cable compound.

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Abstract

The invention discloses a low-smoke halogen-free and flame-retardant polyolefin cable material with high cracking resistance. The invention belongs to the technical field of cable materials, and solves the problem that when a cable wire is subjected to coiling, the cable material possibly cracks at a bent position. The cable material is prepared by the following method of: firstly, mixing 65-75 parts by weight of an ethylene-vinyl acetate copolymer, 25-35 parts of high density polyethylene, 10-18 parts of magnesium hydroxide, 20-40 parts of aluminum hydroxide, 0.05-0.25 part of melamine urate,5-11 parts of red phosphorus, 10-20 parts of a hyperdispersant, 2-5 parts of an antioxidant, 15-21 parts of silicon dioxide, 9-15 parts of silicon resin, 5-11 parts of zinc hydroxystannate, 1.25-1.75parts of sorbitol, and 0.5-1.5 parts of sodium alginate evenly, conducting internal mixing at 130-140DEG C for 10-15min, and carrying out extrusion granulation at 115-140DEG C, thereby achieving theeffects of enabling the cable material to have favorable smoke suppression and flame retardancy and high mechanical properties.

Description

technical field [0001] The invention relates to the field of cable materials, in particular to a highly crack-resistant, low-smoke, halogen-free, flame-retardant polyolefin cable material. Background technique [0002] Cable material refers to the plastic used for wire and cable insulation and sheathing. As people become more and more aware of fire prevention, people pay more and more attention to the flame retardant performance of cable materials. However, adding halogen-containing plastics to cable materials Flame retardants, when a fire occurs, will produce toxic fumes, causing greater casualties, so now low-smoke, halogen-free, flame-retardant cable materials are more and more widely used. [0003] In order to make the cable material have low-smoke, halogen-free flame-retardant properties, it is necessary to fill it with more flame retardants. More flame retardants tend to be unevenly distributed in the cable material, which reduces the mechanical properties of the cable...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L5/04C08L83/04C08K13/06C08K9/04C08K3/22C08K5/3492C08K3/02C08K3/36C08K13/02H01B3/44
CPCC08L23/0853H01B3/441C08L2201/02C08L2201/22C08L2203/202C08L2205/035C08L2207/062C08K2003/2227C08K2003/2224C08K2003/026C08K2003/2231C08K2201/003C08L23/06C08L5/04C08L83/04C08K13/02C08K3/22C08K5/34928C08K3/02C08K3/36C08K13/06C08K9/04
Inventor 董建东何亚丽李俊龙
Owner 上海方之德新材料有限公司
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