Self-repairing polymer waterproof coiled material and preparation method thereof
A technology for polymer waterproofing and waterproofing membranes, applied in the field of building waterproofing materials, can solve the problems of insufficient self-repairing ability of waterproofing membranes, and achieve the effects of good adaptability, reduced damage, and high chemical bond energy.
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Embodiment 1
[0041]Take 100 parts of 107 silicone rubber, 1 part of tetraethyl orthosilicate, 1 part of hydroxy silicone oil, 0.1 part of dibutyltin dilaurate (DBTDL), 0.1 part of amino functional silane (KH550), and 0.1% root inhibitor for initial mixing, Stirring speed is 80r / min, so that all components are mixed evenly, then add 10 parts of microcapsules into the above system, stir at a speed of 10r / min to obtain silicone prepolymer, and then coat it on the modified polymer layer The surface is vacuum defoamed, impregnated with glass fiber, and then coated with a layer of the above-mentioned silicone prepolymer, vacuum defoamed, left to stand at room temperature to cure, and the coil is wound, delivered, and packaged by winding rollers. Among them, the polymer layer adopts a polypropylene film with a thickness of 100 μm, which is treated with corona and grafted with glycidyl methacrylate, and the grafting rate is 5%.
Embodiment 2
[0043] Get 100 parts of 107 silicone rubber, 5 parts of ethyl orthosilicate, 5 parts of hydroxy silicone oil, 0.2 part of dibutyltin dilaurate (DBTDL), 0.5 part of amino functional silane (KH550), and 1% root inhibitor for initial mixing, Stirring speed is 120r / min to mix all components evenly, then add 30 parts of microcapsules to the above system, stir at a speed of 30r / min to obtain silicone prepolymer, and then coat it on the modified polymer layer The surface is vacuum defoamed, impregnated with glass fiber, and then coated with a layer of the above-mentioned silicone prepolymer, vacuum defoamed, left to stand at room temperature to cure, and the coil is wound, delivered, and packaged by winding rollers. Among them, the polymer layer adopts a polypropylene film with a thickness of 100 μm, which is corona treated and grafted with glycidyl methacrylate, and the grafting rate is 15%.
Embodiment 3
[0045] Get 100 parts of 107 silicone rubber, 3 parts of tetraethyl orthosilicate, 3 parts of hydroxy silicone oil, 0.15 part of dibutyltin dilaurate (DBTDL), 0.3 part of amino functional group silane (KH550), 0.5% root inhibitor for initial mixing, The stirring speed is 100r / min to mix all the components evenly, then add 20 parts of microcapsules to the above system, stir at a speed of 20r / min to obtain a silicone prepolymer, and then coat it on the modified polymer layer The surface is vacuum defoamed, impregnated with glass fiber, and then coated with a layer of the above-mentioned silicone prepolymer, vacuum defoamed, left to stand at room temperature to cure, and the coil is wound, delivered, and packaged by winding rollers. Wherein the polymer layer is a polypropylene film with a thickness of 100 μm, which is subjected to corona treatment and grafted with glycidyl methacrylate, and the grafting rate is 10%.
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