Novel electron transport layer perovskite solar cell and preparation method thereof
A technology of electron transport layer and solar cell, which is applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of high defect density, poor stability, and low electron mobility of the electron transport layer, so as to reduce the recombination rate and improve stability , Improve the effect of photoelectric conversion efficiency
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Embodiment 1
[0030] A novel GaN electron transport layer perovskite solar cell and a preparation method thereof, the preparation method comprising the following steps:
[0031] (1) After cleaning the fluorine-doped tin oxide (FTO) conductive glass, process it with a plasma cleaning machine to obtain a pretreated conductive glass substrate at last;
[0032] (2) Put GaN powder with a particle size of 100 μm, deionized water and ball milling medium into the ball mill tank at a ratio of 20:1:1, use a high-energy ball mill to mill at an ultra-high speed of 800 r / min for 25 hours, take it out and put it in 80 Dry in an oven at ℃ to obtain GaN nanomaterials with a particle size of 100nm, disperse the GaN materials in absolute ethanol at a mass ratio of 0.2, and ultrasonicate for 1h to obtain a GaN dispersion; spin-coat the GaN dispersion on an FTO conductive glass substrate, The spin coating speed is 4000r / min, and then transferred to a heating table with a temperature of 150°C, and kept for 30mi...
Embodiment 2
[0037] (1) After cleaning the indium tin oxide (ITO) conductive glass, process it with a plasma cleaning machine, and finally obtain a pretreated conductive glass substrate;
[0038] (2) Put GaN powder with a particle size of 150 μm, deionized water and ball milling medium into the ball milling tank at a ratio of 30:1:1, use a high-energy ball mill to mill at an ultra-high speed of 1100r / min for 30 hours, take it out and put it in 80 Dry in an oven at ℃ to obtain GaN nanomaterials with a particle size of 110 nm. GaN materials are dispersed in absolute ethanol at a mass ratio of 0.25, and ultrasonicated for 2 hours to obtain a GaN dispersion. Spin-coat the GaN dispersion on the ITO conductive glass substrate at a spin-coating speed of 5000r / min, then transfer to a heating table at a temperature of 200°C and keep it warm for 40min to prepare the GaN electron transport layer;
[0039] (3) The spin coating component on the prepared GaN electron transport layer is FA 0.83 MA 0.17...
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